• 제목/요약/키워드: polyester

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저융점 폴리에스테르 복합사의 저온 염색성 (Dyeability of Low-melting Hybrid Polyester at Low Temperature)

  • 황지현;김창남;마진숙;오해선;윤남식
    • 한국염색가공학회지
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    • 제24권2호
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    • pp.113-120
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    • 2012
  • Jacquard floor covering could be prepared from low-melting/regular sheath-core hybrid polyester, where the fiber is dyed in yarn state. With regard that the expected high shrinkage of the hybrid polyester in water makes problems in yarn dyeing, low-temperature dyeing properties of the hybrid polyester were studied. The rate of shrinkage of low-melting hybrid polyester exceeds 9% in hot water above $90^{\circ}C$, at such condition, cheese yarn dyeing is very difficult. Although disperse dyes exhaust in a relatively high speed on low-melting hybrid polyester, diffusion of these dyes to the core regular polyester was extremely slow under $90^{\circ}C$. Foron Blue E-BL 150, an anthraquinone E-type disperse dye, showed appreciable diffusion after 48hrs dyeing at $90^{\circ}C$. The fastness to rubbing and drycleaning were improved by one grade after reduction cleaning.

이산화티타늄 광촉매를 처리한 Polyester 섬유의 기능성 연구 (A study on the Functional Properties of Polyester Fiber Treated Titanium Dioxide Photocatalyst)

  • 최세영
    • Elastomers and Composites
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    • 제49권4호
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    • pp.336-340
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    • 2014
  • 본 연구에서는 광촉매 작용을 하는 이산화티타늄 광촉매를 polyester 섬유에 코팅하여 탈취, 항균 및 자외선 차폐에 대한 기능을 부여하고 그 특성을 알아보았다. 그 결과 탈취성능은 세탁 전과 반복 20회 세탁 후에도 97%이상 저감되는 것으로 나타났으며, 항균성은 균수가 99.9%이상 감소되는 것으로 나타났다. 그리고 Polyester 섬유를 20회 반복 세탁을 행하여도 이산화티타늄 광촉매의 이탈 없이 표면에 견고하게 부착되어 있음을 확인하였으며, 또한 가스분해성능도 세탁전과 20회 반복 세탁 후에도 유지하는 것으로 나타나 세탁내구성이 우수함을 확인하였다. 자외선 차폐성도 세탁 전과 비교하여 20회 반복 세탁 후에도 83%이상 차단되는 것으로 나타났다.

Ethylene glycol을 사용한 폐지의 전처리공정에서 발생된 폐액으로부터 polyester 제조 (Preparation of Polyester Using Waste Ethylene Glycol Generated from the Wastepaper Pretreatment Process)

  • 이동헌;김창준;김성배
    • KSBB Journal
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    • 제27권1호
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    • pp.51-56
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    • 2012
  • This research was to investigate the polyester preparation using waste ethylene glycol (EG) generated from the wastepaper pretreatment process. Waste EG was obtained from using EG five times repeatedly in the pretreatment of wastepaper. The hydroxyl value of the waste EG was 441 mg KOH/g and its composition was 0.68% cellulose, 6.5% hemicellulose, 6.1% lignin, and 86.7% EG. Maleic acid was used as carboxylic acid. The effect of reaction temperature and time except carboxyl group/hydroxyl group ratio on the crosslinkage of the prepared polyester was marginal. Citric acid, lithium hydroxide and dicumyl peroxide were used as additive or catalyst to enhance the crosslinkage of polyester. Among them, 10% of citric acid was found to be most effective. The crosslinkage was 86% when the polyester was prepared at an optimum condition such as $130^{\circ}C$ and 15 minutes, 1.5 of C/H ratio, and 10% of citric acid, and its insoluble percentage in boiling water for 6 hours was 47%. The weight loss of the prepared polyester was approximately 40% when it was buried in damp soil for 5 months, indicating that it is readily biodegradable. This results can provide some information for future development of wastepaper pretreatment by organic solvent.

알칼리 감량 폴리에스테르 섬유의 기공도와 염색성 (The Porosity and the Dyeability of Polyester Fiber Treated with Sodium Hydroxide Aqueous Solution)

  • 김병인;김태경;임용진;조광호;조규민
    • 한국염색가공학회지
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    • 제12권6호
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    • pp.380-388
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    • 2000
  • The porosity of polyester fibers treated with sodium hydroxide aqueous solution was investigated using a nitrogen porosimeter, and the dyeability of the treated fibers was discussed in terms of the porosity. In pore distribution, the polyester fibers treated with sodium hydroxide aqueous solution were characterized by higher amount of pores below $10\AA$ than those of the untreated fibers, and by shift of the pore size having maximum accumulated volume from $10\AA$ for the untreated fibers to $5~6\AA$. As the weight loss of the polyester fibers treated with sodium hydroxide aqueous solution increased, BET surface area and total pore volume increased linearly, but average pore size, showing some different aspect, increased steeply at earlier stage and then approached the maximum value. The dye uptakes of the polyester fibers treated with sodium hydroxide aqueous solution increased with the BET surface area, the total pore volume and the average pore size. The alkali treatment increased the surface area of polyester fibers, so that the chance of contact between the fiber and dye molecules increased. In addition, the pores created on the surface of polyester fibers by alkali treatment might act as pathways for dye molecules into the polyester fibers.

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식물성 섬유와 폴리에스테르 섬유의 혼합 부직포 제조 및 특성 -어저귀, 칡섬유를 중심으로- (The Properties of Plant Fiber and Polyester Blended Nonwoven Fabrics)

  • 이혜자;김남은;유혜자
    • 한국의류학회지
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    • 제33권11호
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    • pp.1696-1706
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    • 2009
  • Nonwoven fabrics have been widely used in various fields that include household, industrial, agricultural, medical goods, especially in the automobile industry. In this study, eco-friendly fiber materials were developed and investigated as a substitute material for polyester fibers in nonwovens. To make plant fiber bundles, stems of Indian mallow (IM), and Kuzu vine (KV) were retted; in addition, the non-cellulose component was partially removed. Plant fiber bundles and polyester fibers (P) were blended and needle punched to produce nonwovens. Five kinds of nonwovens were manufactured: P100 (Polyester 100%), IM10 (IM 10% and Polyester 90%), IM20 (IM 20% and Polyester 80%), KV10 (KV 10% and Polyester 90%), and KV20 (KV 20% and Polyester 80%). The color values, surface appearance, tensile strength, elongation, tear strength, abrasion strength, flexstiffness, moisture regain, water or oil absorbency, and static electricity of manufactured nonwovens are investigated. As the blended ratios of IM or KV increased, the brightness of nonwovens decreased compared to that of polyester 100%. Tensile strength, tear strength, abrasion strength, and flexstiffness of IM10 as well as KV10 were higher than those of P100, IM20, and KV20, resulting from the influence of the structure and properties of nonwoven fibers. Moisture regain and water or oil absorbency increased, while static electricity decreased in proportion to the amount of plant fibers. IM or KV and polyester blended nonwovens showed improved properties over P100 that could be substituted for P100 as a novel material for textiles.

가교제와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색 - 그에 따른 물성 변화 및 염색견뢰도 - (Dyeing of Cotton/Polyester Blends with Disperse Dyes and Crosslinking Agent - The Changes of Physical Properties and Colorfastness -)

  • 김은아;유효선
    • 한국의류학회지
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    • 제26권10호
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    • pp.1401-1411
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    • 2002
  • To Save energy and cost one bath/one step dyeing and finishing on cotton/polyester blends is carried out with disperse dyes in the presence of crosslinking agent. Cotton 100 %, cotton/polyester 70/30, 50/50, 35/65, polyester 100 % fabrics were used. wrinkle recovery angle, tensile strength retention and tearing strength retention were determined in according to the dyebath composition, and also determined while the concentration of DMDHEU, molecular weight and concentration of PEG were varied. Colorfastness to abrasion, washing and light were tested. For cotton and cotton/polyester blends dyed in the presence of DMDHEU/PEG, wrinkle recovery was improved. Tensile strength retention and tearing strength retention were decreased, in compared with dyed fabrics without DMDHEU. Colorfastness to abrasion was good but colorfastness to washing and to light were poor for the fabrics dyed in the presence of DMDHEU/PEG.

열분해-GC에 의한 면/폴리에스터 혼방 직물의 분석 (Analysis of Cotton/Polyester Fabrics using Pyrolysis Gas Chromatograpy)

  • 조미숙;김명덕;박성우;윤기준;남재도;이종훈;이영관
    • 폴리머
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    • 제27권3호
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    • pp.271-274
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    • 2003
  • 열분해 기체 크로마토그래피 (Py-GC)를 이용하여 섬유의 동일성과 함량을 조사하였다. 면사, 폴리에스터, 면과 폴리에스터 혼방사를 Py-GC를 이용하여 그 성분과 함량을 조사하였다. 면과 폴리에스터 성분은 각각의 특성 피이크를 나타내었으며, 특성 피이크의 면적은 각 성분의 함량이 증가함에 따라 비례적으로 증가함을 알 수 있었다. 또한 폴리에스터의 경우에 열분해로부터 생성되는 화합물의 성분을 질량 분광법을 이용하여 테레프탈산, 벤조산, 비닐 벤조산임을 확인할 수 있었으며, 이를 바탕으로 미지의 시료에 포함되어 있는 면과 폴리에스터의 함량을 정량 분석할 수 있었다.

폴리에스테르 직물의 저온플라즈마 처리에 따른 계면동전위와 심색성 향상에 관한 연구 (Increase in Color Depth and Analysis of the Interfacial Electrokinetic Potential of Poly(Ethylene Terephthalate) Fabric by Plasma Treatment)

  • 전상민;이기풍;구강
    • 한국염색가공학회지
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    • 제15권4호
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    • pp.1-7
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    • 2003
  • We investigated the effect of color depth on polyester fabrics by plasma treatment. In this study, although it have many paper about effects of plasma treatment, we observed interfacial electrokinetic potential of polyester fabrics by plasma treatment and also we investigated relationship between deep coloring agent and plasma treatment to get the effect of color depth on polyester fabrics. The results obtained are as follows, 1. Plasma treatment did not enhanced the effect of color depth of polyester fabrics by plasma treatment independently. 2. In the case of using the deep coloring agent with plasma treatment on polyester fabrics, lightness was more decreased than using the deep coloring agent itself. 3. Plasma treatment could not affect surface shape and tensile strength of treated polyester fabrics.

Diphenyl-2-ethanolamidophosphate의 합성과 폴리에스테르 직물에 대한 방염성에 관한 연구 (Studies on the Synthesis of Diphenyl-2-Ethanolamidophosphate (DPEOAP) and Flame Retardancy Effect of DPEOAP on polyester Fabrics)

  • 이광우;김영만
    • 한국의류산업학회지
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    • 제2권2호
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    • pp.123-131
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    • 2000
  • Diphenyl-2-ethanolamidophosphate (DPEOAP) was synthesized to treat polyester fabrics in order to improve its flame retardancy. The flame retardancy and physical properties of DPEOAP-treated polyester fabrics were investigated. The results were as follows: 1) polyester fabrics can be treated with DPEOAP by means of Pad-Dry-Cure method, because DPEOAP was easily soluble in benzene. 2) The most economic conditions of treatment were determined as 10% of DPEOAP cocentration, $140^{\circ}C$ of curing temperature, and 2 minutes of curing time. 3) Though the washablity of DPEOAP is low in comparison with the other products which are purchasable in a market, it has an excellent flame retardment effect 3 times more than in number of flame contact just with 0.66% add-on. 4) The physical properties of DPEOAP treated polyester fabrics were little changed as compared with non-treated fabric.

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Investigation of Inter Fiber Cohesion in Yarns. II. Influence of Fiber and Process Parameters on the Cohesion in Man Made and Blended Yarns

  • Gokarneshan N.;Ghosh Anindya;Anbumani N.;Subramaniam V.
    • Fibers and Polymers
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    • 제7권1호
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    • pp.70-72
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    • 2006
  • This paper discusses the inter fiber cohesion in man made and blended yarns. The fiber parameters such as fiber length and fineness influence the cohesion. Studies have been focused on polyester and viscose spun yarns. Though polyester and viscose yarns show similar trend in cohesion, viscose yarns exhibit better cohesion clue to their serrated cross section. Studies on the effect of blend proportion of polyester cotton and polyester viscose yarns reveal that increase of polyester and viscose in the respective blends improve the inter fiber cohesion.