• Polymer(Korea)
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• v.38 no.5
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• pp.620-625
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• 2014

The effect of polyvinyl alcohol/polyamide-epichlorohydrin (PVA/PAE) complex strengthening additive on dry and wet strength and surface properties of paper was investigated. The enhancements of dry and wet strength and dimensional stability were found when PVA/PAE was applied as a complex strengthening additive compared with the cases of applying individual PVA or PAE. This was understood as physical crosslinking between PVA and PAE in the PVA/PAE complex strength additive. This complex strengthening additive also lowered surface roughness and increased sizing. As a result, PVA/PAE complex strengthening additive provided the distinctive gain dot in printed papers.

• Polymer(Korea)
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• v.37 no.6
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• pp.730-735
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• 2013

The physical properties of poly(vinyl alcohol) (PVA) with polyamide-epichlorohydrin (PAE) for wet strength additives in paper industry were investigated. Upon introducing PAE to PVA, not only melting and crystallization enthalpy in DSC but also the area of diffraction peaks in XRD decreased, which represented the fact that PAE acted as a crosslinking agent for PVA. However, this crosslinking seemed to be physical crosslinking having relatively less bonding energy compared to chemical crosslinking since the crystallization in PVA was able to take place by thermal annealing. This physical crosslinking and crystallization by thermal annealing enhanced the thermal stability and mechanical strength in PVA and consequently, these improvements are desired in the paper manufacturing process to increase the dry and wet strength in the paper.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.1
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• pp.13-25
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• 1997

To establish the weed control method without herbicide and weeding work, mulch paper was developed from domestic old corrugate container. Basis weight of mulch paper should be above 120 g/$m^2$ to guarantee the mechanical properties. It was concluded that polyamide polyamine epichlorohydrin was desirable to improve the wet strength of mulch paper and the optimum addition level was about 1.5% on the basis of oven dry pulp. The mulch paper was found to be effective in controlling paddy weeds. For the complete weed control the mulch paper should be sustained without decomposition over 45 days. As the paper mulching reduced the soil temperature, the mulch paper was required to improve the penetration of radiant heat.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.2
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• pp.26-32
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• 2003

For the purpose of manufacturing water-resistant corrugated board boxes for agricultural products in the cold chain system, the effects of fiber types, wet strength agents and a moisture-proof chemical on the properties of the base papers were investigated first. PAE(polyamide amine epichlorohydrin) showed better performance than MF(melamine formalde-hyde) over broad stock pH ranges, which was prefered as wet strength agent for the paper grade. When short fibers(AOCC, KOCC) were mixed with long fiber(UKP) in certain ratios, some physical properties of the paper made with mixed fibers were similar to those of the paper made with UKP only. Paper containing AOCC showed the biggest increase in water resistance when PAE was added to the stock. Synergistic effects in moisture-proof and some mechanical properties of paper were appeared when PAR was added internally, together with the coating of a moisture proof chemical on the sheets.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1819-1824
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• 2006

The general objective of the present study was to investigate the potential application of the UV spectroscopic method for determination of the polymeric additives present in papermaking fibrous stock solutions. The study also intended to establish the surface-chemical retention model associated with the adsorption kinetics of additives on fiber surfaces. Polyamide epichlorohydrin (PAE) wet strength resin and imidazolinium quaternary (IZQ) softening agents were selected to evaluate the analytical method. Concentrations of PAE and IZQ in solution were proportional to the UV absorption at 314 and 400 nm, respectively. The time-dependent behavior of polymeric additives obeyed a mono-molecular layer adsorption as characterized in Langmuir-type expression. The kinetic modeling for polymeric adsorption on fiber surfaces was based on a concept that polymeric adsorption on fiber surfaces has two distinguishable stages including initial dynamic adsorption phase and the final near-equilibrium state. The simulation model predicted not only the real-time additive adsorption behavior for polymeric additives at high accuracy once the kinetic parameters were determined, but showed a good agreement with the experimental data. The spectroscopic method examined on the PAE and IZQ adsorption study could potentially be considered as an effective tool for the wet-end retention control as applied to the paper industry.