• Title/Summary/Keyword: polyamide

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Effect of Mechanical and Toughening Characteristics of Epoxy/Carbon Fiber Composite by Polyamide 6 Particles, CTBN Addition Technology (Polyamide 6 입자 및 CTBN 첨가 기술에 따른 에폭시/탄소섬유 복합재의 강인화 효과 및 기계적 특성)

  • Sung-Youl Bae;Kyo-Moon Lee;Sanjay Kumar;Ji-Hun Seok;Jae-Wan Choi;Woo-Hyuk Son;Yun-Hae Kim
    • Composites Research
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    • v.36 no.5
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    • pp.355-360
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    • 2023
  • Epoxy-based carbon fibers reinforced plastic (CFRP) exhibit limitations in their suitability for industrial applications due to high brittleness characteristics. To address this challenge, extensive investigations are underway to enhance their toughness properties. This research focuses on evaluating the toughening mechanisms achieved by Polyamide 6 particles(p-PA6) and Carboxyl-Terminated Butadiene-Acrylonitrile (CTBN) elastomer, with a specific emphasis on utilizing minimal additive quantities. The study explores the impact of varying concentrations of p-PA6 and CTBN additives, namely 0.5, 1, 2.5, and 5 phr, through comprehensive Mode I fracture toughness and tensile strength analyses. The inclusion of p-PA6 demonstrated improvements in toughness when introduced at a relatively low content of 1phr. This improvement manifested as a sustained fracture behavior, contributing to enhanced toughness, while simultaneously maintaining the material's tensile strength. Furthermore, the investigation revealed that the incorporation of p-PA6 affected in particle aggregation, thus influencing the overall toughening mechanism. Incorporation of CTBN, an elastomeric modifier, exhibited a pronounced increase in fracture toughness at higher concentrations of 2.5 phr and beyond. However, this increase in toughness was accompanied by a reduction in tensile strength, resulting in fracture behavior similar to conventional CFRP exhibiting brittleness. The synergy between pPA6, CTBN and CFRP appeared to marginally enhance tensile strength under specific content conditions. As a result of this study, optimized conditions for the application of the p-PA6, CTBN toughening technology have been identified and established.

The Application of Reactive Dyes on Polyamide Fibers and Their Dyeing Properties (반응성염료를 이용한 폴리아마이드 섬유에의 응용 및 거동분석)

  • 홍진표;김태경;배기서;손영아
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.413-414
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    • 2003
  • 폴리아마이드 섬유, 즉 나일론 섬유에 응용될 수 있는 여러 종류의 이온성 염료들 중에서 섬유분자와 염료의 결합특성에 기인하는 산성염료의 사용이 현재 주를 이루고 있지만 결합력에서 기인하는 염료의 탈착으로 말미암아 색상강도의 저하 및 첨부포에의 오염이 문제가 되고 있다. 또한 함금속 염료를 이용한 방법에서는 세탁 및 일광에 대한 견뢰도 향상은 얻을 수 있지만, 원하는 수준의 견뢰도를 얻기 위해서는 후처리의 적용도 고려되어진다. 반응성 염료$^{1.2)}$ 를 이용한 염색은 셀룰로오스 섬유에의 적용이 대부분이며, 양모 및 견에 대한 응용도 발표되고 있다. (중략)

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Study on Spinning Behavior and Structure of Polyester Fibers by the Melt-type Electrospinning Method (용융형 전기방사법에 의한 폴리에스테르섬유의 방사거동과 구조에 관한 연구)

  • Lee, Jin-Ah;Lim, Min-Soo;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.273-276
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    • 2002
  • The fiber formation of conventional melt spinning is extruded by forcing the polymer melt through a spinneret by pumping mechanism usually involving high pressure. This is followed by cooling, solidification and appropriate drawing of the fiber. The spinning process is broadly applicable to polyolefin, polyamide, polyester and indeed the whole range of fibers forming thermoplastic polymers. (omitted)

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Investigation of Surface Morphology for Nylon 4,6 Thin Film by Molecular Layer Deposition

  • Gwon, Deok-Hyeon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.419-419
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    • 2012
  • We fabricated the Polyamide 4,6 (PA46) thin film using Adipoyl chloride and 1,4-butadiamine. PA46 film was grown at $70^{\circ}C$ by Molecular Layer Deposition (MLD) method. MLD is sequential and self-terminating fabrication method for organic thin film. The growth rate of PA46 is $3.5{\acute{\AA}}$ cycle. The thickness of PA46 film was measured by Ellipsometer. Surface morphology of this film was investigated by Atomic Force Microscopy (AFM) and roughness is directly proportional to number of growing cycles.

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Dyeing of Polyamide Fabric with Reactive Dyes (반응성 염료에 의한 폴리아미드 섬유의 염색)

  • 이병선;김성동
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.96-99
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    • 2003
  • 대표적인 합성섬유인 나일론은 강도, 탄성 및 내마모성이 우수하여 상업용으로 개발된 후 현재까지 지속적으로 발전하여 왔다. 또한 염색가공성이 우수하고 내약품성이 큰 장점을 가지고 있어 의류용 및 산업용 분야에서의 수요가 증대되어 1950년대 이후 생산량의 꾸준한 증가를 보이고 있다. 나일론 섬유의 염색에 있어 산성염료, 함금속염료 및 분산염료가 널리 이용되고 있으나 염색공정의 편리성, 색상 및 섬유-염료간의 염착결합력 관점에서 산성염료를 이용하여 나일론 섬유를 염색하는 것이 일반적 염색공정으로 채택되고 있다. (중략)

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The Effect of Thermal Annaling on the Gas Transport Properties of Liquid Crystalline Polymer HIQ-40 (액정 고분자 HIQ-40의 열처리에 의한 기체전달 특성 변화)

  • ;Paul, Donald R.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.22-28
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    • 1995
  • Since the discovery of liquid crystallinity by Reinitzer [1] in 1988 as he studied the melting behavior of cholesteryl benzoate, anisotropic structural ordering in fluid phases has been of considerable interest to chemists, physicists and other scientists. Polymers which exhibit liquid crystallinity either in solution (lyotropic) or in the neat state upon heating (thermotropic) have both theoretical and practical importance [2]. Du Pont's Kevlar, a high modulus polyamide fiber spun from a lyotropic solution, is a prime example of such an application.

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Positron Annihilation Lifetime Spectroscopic Analysis to Demonstrate Flux-Enhancement Mechanism of Aromatic Polyamide Reverse Osmosis Membranes (양전자 소멸시간 분광분석을 통한 방향족 폴리아미드 역삼투 분리막의 수투과 향상 메커니즘 제시)

  • Kim, Sung-Ho;Kwak, Seung-Yeop
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.82-85
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    • 2004
  • Flux-enhancement mechanism of thin-film-composite (TFC) membranes for the reverse comosis (RO) process was newly explained by positron annihilation lifetime spectroscopy (PALS) that has been found to be applied for detecting molecular vacancies or pores having sizes that are equivalent to salt or hydrate ions in RO membrane.(omitted)

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The Major Developments of the Evolving Reverse Osmosis Membranes and Ultrafiltration Membranes

  • Kurihara, Masaru
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.10a
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    • pp.9-16
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    • 1991
  • The current status of reverse osmosis and ultrafiltration membranes are reviewed with the view for the future. In the case of reverse osmosis (RO) membranes, as examples, new crosslinked aromatic polyamide membranes exhibited the superior separation performance with the sufficient water permeability, the high tolerance for oxidizing agents and chemicals. Ultrafiltration (UF) membrane based on poly(phenylene sulfide sulfone) (PPSS) also exibited the superior separation performance with the high solvent, heat and fouling resistance.

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