• Title/Summary/Keyword: polyacetylene

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Chemical Constituents of the Halophyte Glehnia littoralis (염생식물 갯방풍의 화학적 성분연구)

  • Um, Young-Ran;Lee, Jung-Im;Lee, Jin-Hyeok;Kim, Hae-Jin;Yea, Sung-Su;Seo, Young-Wan
    • Journal of the Korean Chemical Society
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    • v.54 no.6
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    • pp.701-706
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    • 2010
  • Two polyacetylenes (1 and 2), four coumarins (3-6), and one sesquiterpene (7) were isolated from the halophyte Glehnia littoralis. Particularly, compound 6 and 7 were isolated for the first time from Glehnia littoralis. Their chemical structures have been determined by extensive 2-D NMR experiments such as $^1H$, COSY, HMQC and HMBC and by comparison with the reported data in the literature.

Synthesis and Electric Conductivity of Poly(thiophene-co-pyrrolyl undecanoic acid) (Poly(thiophene-co-pyrrolyl undecanoic acid)의 합성 및 전기전도도)

  • 장지임;박연흠;김건형;조원호
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.305-306
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    • 2003
  • 전기전도성 고분자는 금속과 유사한 전도성을 가진 공액이중결합의 고분자로서, 전기적, 전기 화학적, 광학적 성질 둥을 가지고 있어 그 연구 범위가 넓으며, 지금까지 많은 연구 논문들이 보고 되어왔으며 최근에는 전도성(Conducting) 유기물질들과 반도체(Semiconducting) 유기물질들이 electrolumine- scent diodes, membranes, 재충전 batteries와 같은 장치에 응용되고 있다[1]. 대표적인 전기전도성 고분자로는 polyacetylene, poly(p-phenylene), polyaniline, polypyrrole, polythiophene 등이 있고 특히 그 중에서 전도성과 stability가 우수한 polypyrrole과 polythiophene에 관한 많은 연구가 진행되어 왔다[2]. (중략)

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A study on the functional application of conducting polymer (도전성 고분자의 기능성 응용에 관한 연구)

  • 김종욱;김현철;정인성;김현관;구할본;김태성
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.520-526
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    • 1994
  • A rectifying heterojunction consisting of polyparaphenylene(PPP) and polypyrrole(PPY) films was prepared by the electrochemical method. The photoresponse in the heterojunction of PPY and PPP is similar to the absorption spectrum of undoped PPP. This fact suggests that photoresponse depends strongly upon polyparaphenylene of semiconductor. The fill-factor was calculated from the photo current-voltage curve to be 0.19, which is relatively small compared to polyacetylene-polythiophene heterojunctions.

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폴리피롤/공중합폴리에스테르 전도성 복합필름의 전기전도성에 미치는 고분자 구조의 효과

  • 이성모;김길래;백두현
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.121-125
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    • 1998
  • 1977년 polyacetylene(PA)이 할로겐 도핑에 의해 금속에 필적하는 도전성을 나타낸다는 것이 발견된 이래 전도성 고분자는 전기 전도도 및 전자 상태를 자유롭게 제어 할 수 있다는 특징 때문에 2차 전지 및 연료 전지, 가스분리막, 우주 항공용 경량 도전재료, 대전방지제등의 넓은 응용분야를 가지며 현재에도 기초 연구 및 응용 연구의 양면에서 활기를 띠고 있다.(중략)

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Studies on the Constituents of Acanthopanax koreanum

  • Chung, Bo-Sup;Kim, Young-Ho
    • Korean Journal of Pharmacognosy
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    • v.17 no.1
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    • pp.62-66
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    • 1986
  • Acanthopanax koreanum Nakai (Araliaceae) is a indigenous medicinal plant growing throughout Jeju-Do in Korea. The plant extract is used in rheumatism, tonic, paralysis and sedative agent. From the roots of A. koreanum, lignan compounds, a diterpenoid, and a polyacetylene compound were isolated and their structures were elucidated by using IR, PMR, CMR and MS spectral data.

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Polyacetylenes from the Rhizome of Korean Red Ginseng (홍삼 뇌두로부터 수종의 폴리아세칠렌 화합물의 분리)

  • 백남인;김동선
    • Journal of Ginseng Research
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    • v.20 no.1
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    • pp.30-35
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    • 1996
  • Some polyacetylenes were Isolated from the rhizome of Korean red ginseng through re - pealed column chromatogrphy, and identified as 3-hydroxy-1, 9-heptadecadiene-4, 6-diyne (panaxynol), 9, 10-epoxy-3-hydroxy-1-heptadecene-4, 6-diane(panaxydol), 3, 9, 10-trihydroxy-1-heptadecene-4, 6-diyne(panaxytriol), 9, 10-epoxy-3-hydroxy-1, 16-heptadecadiene-4, 6-diyne(ginsenoyne A) and 10-ch1oro-3, 9-dihydroxy-1-heptadecene-4, 6-diane(panaxydol chlorohydrine) by several spectral and chemical methods.

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Phytochemical Studies on the Barks of Acanthopanax senticosus forma intermis (좀가시 오갈피나무의 성분연구)

  • 육창수;김선창;김창종;한덕룡
    • YAKHAK HOEJI
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    • v.35 no.3
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    • pp.147-153
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    • 1991
  • Chemical constituents of fruits, leaves and barks of Acanthopanax senticosus forma inermis were studied. Their fruits have higher contents of crude ash, crude protein, crude fat, fructose and glucose than those of other Acanthopanax species, and contained larger amount of glutamic acid and malic acid among amino acid and organic acid, respectively. The compounds identified from their barks and leaves, were $\beta$-sitosterol and stigmasterol, sesamin, savinin, syringaresinol diglucoside, oleanolic acid, chiisanoside and polyacetytene ($C_9H_{10}O_2$, mp. 62~63).

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