• Polymer(Korea)
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• v.39 no.2
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• pp.191-199
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• 2015

In order to improve the low impact resistance of polystyrene without harming its transparency the styrene monomer was copolymerized with transparent butyl acrylate (BA), and methylmethacrylate (MMA) to obtained a poly(styrene-co-butylacrylate) P(SM-co-BA) and a terpolymer copolymer P(SM-co-BA-co-MMA). The polymers were then cross-linked with the aid of a cross-linking agent dicumylperoxide (DCP), and their mechanical and optical properties were tested. It was found that the contents of monomers and DCP affect the mechanical, thermal, and optical properties of the polymers. An increase in BA contents in P(SM-co-BA) and P(SM-BA-MMA) improved the mechanical strength, but the optical properties remained the same with some exception for P(SM-co-BA). An increase in the DCP contents improved the mechanical but found losses in the optical properties.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.182-188
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• 1994

Poly(butadiene-g-MMA) was synthesized by grafting methyl metharcylate on polybutadiene which is intrinsically incompatible with poly(mothy methacrylate)(PMMA) and this graft copolymer was blended with PMMA. Mechanical properties of PMMA-poly(butadiene-g-MMA) blends and PMMA-polybutadiene blends, such as impact strength, tensile strength and haze were determined. Morphological changes of the blends as a function of graft percentage were observed by scanning electron microscopy. Mechanical properties of PMMA-poly(butadiene-g-MMA) blends were better than PMMA-polybutndiene blends. Especially, mechanical properties of PMMA-poly(butadiene-g-MMA) blends were improved nth increasing graft percentage of MMA.

• Korean Journal of Materials Research
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• v.10 no.12
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• pp.825-830
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• 2000

The copolymers with various composition of vinylbenzyl chloride (VBC), methyl methacrylate (MMA), and 2-hydroxyethyl methacrylate(HEMA) were synthesized as a humidity sensitive material and quaternized with N, N, N', N'-tetraethylene diamine.. Resistance versus relative humidity decreased with increase in the content of MMA in the copolymer. The introduction of HPMA increased the resistance of the humidity sensor as well as enhanced the adherence to the alumina substrate. In the case of VBC/MMA/HEMA=80/10/10, the hysteresis and temperature dependency coefficient were $\pm$2%RH and -0.46~0.42%RH/$^{\circ}C$. The average resistance at 30%RH, 60%RH and 90%RH were 3.0M$\Omega$ ,200k$\Omega$ and 9k$\Omega$, respectively.

• Analytical Science and Technology
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• v.17 no.2
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• pp.98-107
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• 2004

In this study, $^1H$ NMR spectroscopy and HPLC were used to identify the type and quantity of each component in an acrylic coating materials applied for an automotive part. By the $^1H$ NMR analysis, it was found that this acrylic coating contained about 88.40 wt% of poly methyl methacrylate (PMMA), 7.05 wt% of methyl methacrylate (MMA), and 2.36 wt% of allyl methacrylate. Polymer additives such as a benzotriazole light stabilizer (Hisorb 328), an oxanilide light stabilizer, butylated hydroxy toluene (BHT), and dimethyl phthalate (DMP) were also identified and measured quantitatively from the $^1H$ NMR spectra. However, only two light stabilizers were identified by reverse phase (RP) HPLC analysis using Bondapak C18 column, methanol mobile phase, and a PDA (Photodiode array) detector. The contents of two light stabilizers in the acrylic coating were measured by a quantitative analysis through UV-Vis spectroscopy and compared with the NMR data. The analytical informations from $^1H$ NMR spetra were better than those from HPLC-PDA plot.

• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.214-215
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• 2002

최근 들어 polymer는 여러 분야에 응용되고 있으며 광학적 시스템에도 널리 사용되고 있다. 주로 사용되는 polymer에는 PMMA(Poly methyl methacrylate), PC(Polycarbonate), PS(polystyrene)[1] 등이 있다. Optical Polymer는 제작이 용이하고 크기에 제한을 받지 않아 그 수요가 크게 확대되고 있다. 광학적인 시스템에 사용되기 위해서는 높은 순도가 요구되면서 또한 재질의 균일성이 확보되어야 한다. 본 연구에서는 간섭계를 구성하여 복굴절을 측정하고 이러한 복굴절에 기인하는 비대칭 수차의 평가를 통하여 광학적인 시스템에 미치는 영향을 분석하였다. (중략)

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.10a
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• pp.829-830
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• 2012

• Journal of the Korean Society for Precision Engineering
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• v.23 no.6 s.183
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• pp.37-43
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• 2006

• Proceedings of the Korean Vacuum Society Conference
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• 2009.02a
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• pp.112.2-112.2
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• 2009

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2010.03a
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• pp.107-107
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• 2010

• Bulletin of the Korean Chemical Society
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• v.16 no.2
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• pp.96-101
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• 1995

The optical properties of individual 3-to 14-micron diameter CdS crystalline spheres embedded in poly(methyl methacrylate) were studied using elastic scattering. The presence of well defined sharp peaks in the 550 to 600 nm elastic scattering spectra confirmed that each microcrystal acts as an optical cavity with cavity quality factors exceeding 104. Such natural resonator microcrystals should lead to greatly enhanced local field effects near the surface of CdS, quantum electrodynamic modification of optical transition rates of nearby species and altered photochemistry. Absorptive heating following high intensity laser irradiation was found to induce a transient washout of the high Q modes.