• 한국염색가공학회지
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• 제2권4호
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• pp.231-236
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• 1990

The diffusion coefficient of C.I. Disperse Red 4 in the dyeing of carrier-pretreated poly (ethylene terephthalate) film was Investigated by Sekido's film-rolled method. From the result it was shown that the diffusion coefficient increases exponentially with the content-ration of carrier in the film, and, for the films containing same concentration of carrier, the carrier effect was enhanced with the molar volume of the carriers. The greater carrier effect was accompanied by the decrease in diffusion activation energy and entropy, which shows that the carrier with larger molar volume plasticizes PET film to more extent.

• 한국염색가공학회지
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• 제2권3호
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• pp.26-35
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• 1990

This study was carried out with the view of fundamental investigating to improve the tactile and the hygroscopicity of Poly(ethylene Terephthalate) (PET)fibers. Mono-sodium ethylene glycolate in ethylene glycol (MSEG-EG) solution was prepared and PET films were treated with it. The following conclusions were obtained. When PET films were decomposed in MSEG-EG solution, decomposition rate constant showed an exponential relationship with treating temperature; activition energy was 23.30 Kcal/mol, activation enthalpy was 22.52~22.60 Kcal/mol and activation entropy was -29.20~ -29.41 e.u. On the basis of the results obtained above and structure identification of decomposition products, it was found that the decomposition reaction proceeded through ester interchange reaction.

• 한국의류산업학회지
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• 제15권2호
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• pp.302-308
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• 2013

This study is a preliminary investigation of the influence of surface characteristics of substrates on detergency of particulate soil. The surface of PET film was modified with NaOH and NaOH+ethylene diamine on different times. The surface morphology of the film was scanned by AFM and surface energies were calculated from measured contact angles between several solutions and film based on the geometric mean and a Lewis acid base method. The surface morphology of PET film treated with NaOH and NaOH+ethylene diamine became more etched, and the surface area, surface roughness and the coefficient of friction of film increased with treatment of NaOH and NaOH+ethylene diamine. The contact angle of film treated with NaOH and NaOH+ethylene diamine decreased in water and surfactant solution; in addition, the surface energy increased was largely attributed to the increased portion on the polar surface energy of film. However, the effect of the diamine addition to the NaOH treatment solution on surface characteristics of PET film was insignificant.

• 한국염색가공학회지
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• 제15권3호
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• pp.185-191
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• 2003

Surface modification of poly(ethylene terephthalate) (PEI) films by treatment with ethoxylated alkylaminoanthraquinoes which was synthesized by the reaction of 1-aminoanthraquinone with poly(ethylene glycol) via a series of methylene spacer were investigated. The synthesized ethoxylated alkylaminoanthraquinones showed definite cloud point as in nonionic surfactants, and the adsorption of the compounds on PET increased near the cloud point. At same temperature the adsorption increased with the length of methylene spacer; hexyl-octyl-, and decyl-. The adsorption was limited to the extreme surface of PET film, which made the surface of PET film hydrophillic by reducing water contact angle.

• 한국염색가공학회지
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• 제2권4호
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• pp.223-230
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• 1990

This study was carried out with the view of fundamental investigating to improve the tactile and the hygroscopicity of Poly (ethylene terephthalate) (PET) fibers. Mono-sodium ethylene glycolate in ethylene glycol (MSEG-EG) solution was prepared and PET films were treated with it. The following conclusions were obtained. 1. The tensile strength decreased with increasing decomposition ratio while density, crystallinity and crystallite size increased with increasing decomposition ratio when PET films were treated with MSEG-EG solution. 2. Number of carboxyl end groups was increased until 10-20% decomposition ratio when PET films were treated with MSEG-EG solution. However, the decomposition ratio became more than 20%, the number of carboxyl end groups had tendency to decreased. 3. The surface tension of PET films increased for treating with MSEC-EG solution. Hydrogen bonding force and poler force among the components of surface tension increased while dispersion force among those decreased. 4. The moisture region of PET films increased with increasing decomposition ratio when PET films were treated with MSEG-EG solution.

• 폴리머
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• 제37권3호
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• pp.316-322
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• 2013

본 연구에서는 고분자 소재 중 하나인 폴리(에틸렌 테레프탈레이트)(poly(ethylene terephthalate), PET) 필름의 표면을 친수성으로 개질하기 위하여 기상 불소화 및 초음파 수세를 실시하였다. 표면 처리된 PET 필름의 표면 특성은 접촉각, 표면 자유에너지, 주사전자 현미경(FE-SEM), 원자간력 현미경(AFM), X선 광전자분석법(XPS)을 통하여 분석하였다. 직접 불소화 및 초음파 수세 처리된 PET 필름의 물 접촉각은 $10.8^{\circ}$으로 미처리된 PET에 비하여 85% 감소하였고, 총 표면 자유에너지는 $42.25mNm^{-1}$으로 미처리된 PET에 비하여 650% 증가하였다. 또한 RMS(root mean square) 거칠기는 1.965 nm로 미처리된 PET 필름에 비하여 348% 증가하였으며, 친수성 관능기인 C-OH 결합의 농도는 약 3배 가까이 증가하였다. 이는 직접 불소화 및 초음파 수세 처리된 PET 필름 표면에 형성된 친수성 관능기와 공동화 현상에 의한 화학적 식각 반응에서 기인한 것으로 생각된다. 이 결과로부터, 기상 불소화 및 초음파 수세 처리법은 PET 필름 표면을 친수성으로 쉽게 개질할 수 있는 효과적인 방법으로 기대된다.

• 전기학회논문지
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• 제59권12호
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• pp.2230-2234
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• 2010

This paper deals with the change of surface potential decay, surface resistivity, contact angle and XPS of ultraviolet-treated PET films. From the experimental results on the surface potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

• 한국안전학회지
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• 제16권3호
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• pp.61-67
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• 2001

In this study the electrical and mechanical characteristics of PET films ore analyzed after plasma surface treatment. After plasma treatment, the surface potential decay, surface potential and dielectric property were evaluated to analyze the electrical insulating property, and the tensile strength was measured as the mechanical characteristic. When plasma treatment was conducted for less than 10 minutes, it was found that the electrical insulating property was improved through evaporation of low molecular weight materials md cleaning of surface. However, for more than 10 minutes, the insulating property of plasma treated PET films was decreased due to excessive discharge energy. The tensile strength was hardly changed by Plasma treatment.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.1587-1589
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• 2000

In this paper the weight loss, surface potential decay, surface resistivity and dielectric constant are measured to investigate the surface properties, insulation characteristic changes of PET film according to the discharge treatment. As a result of the test, up to the 10[min] the surface potential decay and surface resistivity have increased. Also, from the result of dielectric constant has decreased. On the other hand, the insulation characteristic of PET film have decreased after 10[min] in the discharge treatment.

• 한국염색가공학회지
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• 제1권1호
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• pp.7-18
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• 1989

The distinguishing characteristic of the glow discharge is that chemical reaction induced by partially ionized gases are limited only to the substrate surface. Most studies have been done on the plasma etching and polymerization. The graft polymerization in vapour phase by cold plasma has been rarely investigated. In this study the system of tub3ar reaction chamber with capacitively coupled electrode of alternative current of 60 Hz was employed for the graft polymerization. The graft polymerization of Acylic Acid(AA) onto the poly (ethylene terephthalate) (PET) was carried out by treatment of PET film and fabric by cold plasma (glow discharge of argon gas), followed by the supply of AA vapour. The graft yield was about 1 wt%. The surface property was determined by contact angle, the surface tension was evaluated by zisman’s plot and equation of surface tension mesurement. The results were as follows: 1. In order to obtain lower contact angle, it was effective to avoid the vicinity of electrodes for a setting position of substrate. 2. Contact angle affected on the monomer pressure and its duration of exposure to the acid vapour. 3. Polymer radical formation was influenced by the changes of the value of current density and plasma treatment time. 4. Total surface tension of plasma grafted PET film increased. With an increase in the carboxylic acid content, the dispersion force decreased, while, the polar force and hydrogen bonding force increased. 5. The contact angle decreased from $75^\circ$ to around $30^\circ$ by plasma grafting. There was no ageing effect on the contact angle after 4 months.