• Title/Summary/Keyword: poly(acrylonitrile)

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Evolution of Phase Morphology During Compounding of Ternary Blends in a Twin Screw Extruder (이축 압출기를 이용한 혼련에서 삼성분계 블렌드의 상구조 형성과정)

  • Kim, Hyungsu;Lee, Shi-Choon;D .Y. Yu;C. G. Gogos
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.247-255
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    • 1998
  • The morphological changes during melt compounding of ternary blends containing various combinations of acrylonitrile-butadiene-styrene(ABS), methyl methacrylate-butadiene-ethyl acrylate(MBE), styrene-acrylonitrile(SAM) copolymers, and poly(methyl methacrylate)(PMMA) as dispersed components in a fixed matrix of polycarbonate(PC) have been investigated. Depending on the composition of the blend, MBE particles and PMMA phase appear to locate at the PC-SAN interface under the influence of interfacial tensions and motion induced coalescence. The interfacial viscosity is found to be a critical factor that affects the amount of coalescence.

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Study on the reduction of stick-slip noise in acrylonitrile butadiene styrene-based plastics using non-polar additives to reduce friction (마찰 저감을 위한 비극성 첨가제에 따른 acrylonitrile butadiene styrene계 플라스틱의 stick-slip 이음 저감 연구)

  • Sangjun Yeo;Yewon Jeong;Sunguk Choi;Hyojun Kim;Geonwook Park;Minyoung Shon
    • The Journal of the Acoustical Society of Korea
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    • v.43 no.1
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    • pp.49-59
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    • 2024
  • Recently, the electric vehicle market is gradually growing due to strengthened environmental regulations and high oil prices. also, in internal combustion engine vehicles, the sensitivity of Buzz, Squeak, Rattle (BSR) noise is increasing as engine Noise, Vibration, and Harshness (NVH)-related noise is reduced and technology for shielding noise coming from outside is developed. In this study, the stick-slip noise that occurs in Panoramic Curved Display (PCD) of automobile was analyzed for the correlation between the surface energy of polymer plastic and the polar component. For polar polymer materials, Acrylonitrile Butadiene Styrene (ABS) and PolyCarbonate-Acrylonitrile Butadiene Styrene (PC-ABS), compound materials were fabricated and evaluated. As a result, when the polar component of the polymer plastic was 3.86 mN/m or higher, stick-slip motion occurred, and as the absolute transition slope increased in the friction behavior over time, the possibility of stick-slip noise increased and the value of the friction coefficient The greater the difference, the greater the strength of the stick-slip noise.

Surface Structure of Blend Films of Styrene/Acrylonitrile Copolymer and Poly(methyl methacrylate)(PMMA) or Hydrolyzed PMMA

  • 이원기;K. Tanaka;A. Takahara;T. Kajiyama;하창식
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.958-961
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    • 1997
  • The compatibility and the surface structure of blends of poly(styrene-co-acrylonitrile) (SAN) with either poly(methyl methacrylate) (PMMA) or hydrolyzed PMMA (H-PMMA) were studied in terms of film thickness, interaction, and surface free energy difference on the basis of X-ray photoelectron spectroscopy (XPS), attenuated total reflection Fourier transform IR spectroscopy and atomic force microscopy. The XPS measurement showed that the surface enrichment of (PMMA/SAN) blends with different AN contents of SAN and with different carboxyl acid contents of PMMA was dependent on the molecular interaction, the surface free energy difference between components and the sample preparation history. It was found that the compatibility of H-PMMA and SAN was reduced with increasing carboxyl acid content of PMMA.

The Effects of Blend Composition and Compatibilizer on the Mechanical Properties of the PP/SAN and the PP/ABS Blends (블렌드 조성과 상용화제가 PP/SAN과 PP/ABS 블렌드의 기계적 물성에 미치는 영향)

  • 박정훈;성운모;현재천;김우년;홍병권;홍존희;임양수
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.53-60
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    • 2002
  • Polypropylene(PP : continuous phase)/poly (styrene-co-acrylonitrile)(SAN : dispersed phase) blends, and PP/poly(acrylonitrile-butadiene-styrene) (ABS : dispersed phase)blends, containing various amounts of compatibilizer(PP-SAN graft copolymer), were prepared at various shear rates by using twin-screw extruder. In the PP/SAN blend, the average size of the dispersed particles(SAN) was increased with SAN content, while the flexural strength and tensile strength were decreased with SAN content. When the screw rpm was increased from 10 to 60 rpm, the size of the dispersed phase was decreased while the flexural strength and the tensile strength were increased. Maximum mechanical strength and minimum droplet size were observed when the 5 phr compatibilizer was added to the PP/SAN blends. The mechanical strength of PP/ABS blends such as flexural strength and tensile strength increased by adding compatibilizer was reached maximum when blends contained 5 phr compatibilizer.

Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model (Eyring-Halsey 모델의 유동파라메타로부터 열역학 성질과 자체 확산)

  • Kim, Nam Jeong
    • Journal of the Korean Chemical Society
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    • v.58 no.3
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    • pp.251-257
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    • 2014
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples were carried out in air and distilled water at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The self diffusion, hole volume, viscosities, and thermodynamic parameters of copolymer samples were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusion, hole volume, viscosities, and thermodynamic parameters of flow segments.

Separation of Aqueous Ethanol Solution Using a PAA-PAN Composite Membrane Through Pervaporation (PAA-PAN 복합막을 이용한 에탄올 수용액의 투과증발 분리)

  • 원장묵;하백현;최호상
    • Membrane Journal
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    • v.6 no.3
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    • pp.182-187
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    • 1996
  • Hydrophilic poly(acrylonitrile) [PAN] membrane with good molecular weight cut-off characteristics were prepared by using the phase inversion method. Permeability and molecular weight cut-off of the membranes were measured through the ultrafiltration test. On the surface of the PAN support membranes, poly(acrylic acid) [PAA] was deposited by dip-coating. The water permeability of the PAN support membrane had $0.17~31\textrm{mm}^3/m^{2} \cdot s \cdot Pa$, the molecular weight cut-off 42, 000~150, 000. The transport characteristics of the prepared composite membranes were significantly affected by the variation of the support membrane mophology. The permeability of the composite membrane was decreased with increasing molecular weight cut-off of the support membrane, and the separation factor was slightly changed depending on the feed concentration.

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