• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1998년도 봄 학술발표회 프로그램
• /
• pp.122-124
• /
• 1998

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1999년도 정기총회 및 봄 학술발표회 프로그램 The Korean Environmental Sciences Society
• /
• pp.220-223
• /
• 1999

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1999년도 임시총회 및 가을 학술발표회 초록집 The Korean Environmental Sciences Society
• /
• pp.151-153
• /
• 1999

• 자원환경지질
• /
• 제16권4호
• /
• pp.269-276
• /
• 1983

단순한 사각주형(四角柱型) 물체(物體)에 대한 3차원 표준곡선을 해석하였다. 이들 표준곡선은 쌍극자배치(雙極子配置)에 대하여 적분방정식을(積分方程式) 이용한 수치계산기술(數値計算技術)로 구하였다. 전도성(電導性) 물체에 대한 IP응답(應答)은 물체의 폭과 두께의 비율에 따라서 그 패턴이 달라진다. 주향(走向)길이가 쌍극자간격(雙極子間隔)의 6배 이상이 되면 2차원의 결과와 유사하다. 또한 주향(走向)길이가 길고, 폭이 쌍극자 간격의 4배이상이 되면 층구조(層構造)(1차원) 해석도 가능하게 된다. 한편, 측선(測線)이 주향방향(走向方向)을 따라서 물체의 중심으로부터 멀어지는 효과는 물체의 깊이가 지표로부터 깊어질 때와 비슷하게 나타난다. 물체가 측선하(測線下)에서 측선과 평행(平行)한 방향으로 이동하더라도 IP패턴에는 거의 영향을 미치지 않는다.

• Corrosion Science and Technology
• /
• 제9권6호
• /
• pp.294-299
• /
• 2010

Two types of welding methods were performed on austenitic 304 stainless steel: laser welding and TIG welding. The differences of the corrosion characteristics of the welded zones from the two welding methods were investigated with electrochemical methods, such as measurement of the corrosion potential, polarization curves, cyclic voltammogram, etc. The vickers hardness of all laser-welded zones (WM:Weld Metal, HAZ:Heat Affected Zone, BM:Base Metal) was relatively higher while their corrosion current densities exhibited a comparatively lower value than those which were TIG welded. In particular, the corrosion current density of the TIG-welded HAZ had the highest value among all other welding zones, which suggests that chromium depletion due to the formation of chromium carbide occurs in the HAZ, which is in the sensitization temperature range, thus it can easily be corroded with an active anode. Intergrenular corrosion was also observed at the TIG-welded HAZ and WM zones. Consequently, we can see that corrosion resistance of all austenitic 304 stainless steel welding zones can be improved via the use of laser welding.

• Advances in materials Research
• /
• 제4권2호
• /
• pp.113-132
• /
• 2015

The phenomena of high-voltage polarization and conductivity in oriented vinylidenefluoride and tetrafluoroethylene copolymer films have been investigated. It was shown that under certain electric fields, injection of carriers from the material of electrodes appears The barrier for holes injection in the copolymer was found to be lower than that for electrons. It results in more effective screening of the external field near the anode than near cathode. Electrones, ejected from cathode, creating negative charge by trapping on the surface. It is shown that the electrons injected from cathodes create a negative homocharge on the copolymer surface and then become captured on the surface shallow traps. Their nature has been studied by the x-ray photoelectron spectroscopy. It was shown that these traps may consist of chemical defects in the form of new functional groups formed by reactions of surface macromolecules with sputtered atoms of aluminum. The asymmetric shape of hysteresis curves was explained by the difference in mobility of injected holes and electrons. These factors caused appearance of "non-closed" hysteresis curves for fluorine-containing polymer ferroelectrics. Hysteresis phenomena observed at low electric fields (below coercive ones) are to associate with the behavior of the domains localized in the ordered regions formed during secondary crystallization of copolymers.

• 소성∙가공
• /
• 제30권6호
• /
• pp.301-305
• /
• 2021

The role of Nb addition in the tension and corrosion responses of ferrite-based stainless-steel sheets processed by cold-rolling and annealing treatment at 1173 °K was studied to evaluate the possibility for commercialization. For this purpose, the grain sizes in the samples with and without Nb content were controlled to be reasonably identical by utilizing different heat treatments within the specific range for 60 seconds. The corrosion properties of both samples were evaluated based on the analysis of polarization curves. Room-temperature tension testing showed that the strength of the sample with Nb was much higher than that without Nb whereas the elongation of the sample with Nb was slightly lower than that without Nb. The polarization curves revealed that the addition of Nb contributed to the significant improvement in protective capabilities. We thought that such combinational behavior was mainly due to the formation of niobium carbides found in the ferritic matrix.

• Corrosion Science and Technology
• /
• 제21권3호
• /
• pp.171-183
• /
• 2022

The performance and inhibitory action of the aqueous extract of Cyperus Conglomeratus's leaves against corrosion of XC70 steel in a 1M HCl acid medium are studied by the determination of the weight loss, the potentiodynamic polarization curves analysis, and electrochemical impedance measurements (electrochemical techniques). The corrosion inhibitory efficiency of XC70 steel increases with the increasing concentration of the green inhibitor, however, the corrosion rate of the steel decreases. Weight loss measurements show that the maximum percentage corrosion inhibition efficiency is approximately 61.86%, while the analysis of the mixed character polarization curves shows that the inhibitor could achieve an inhibition efficiency of 86.96%. The electrochemical impedance study confirmed that the value of the charge transfer resistance (R_ct) increases and the value of the double layer capacity (C_dl) decreases with increasing concentration of the aqueous extract of Cyperus Conglomeratus's leaves, thus increasing the inhibition efficiency. The study showed that this aqueous extract acts by adsorption on the metal surface; this adsorption follows the Langmuir isotherm. This research work showed that Cyperus Conglomeratus leaves extract acts as an effective and eco-friendly inhibitor on mild steel in an acid medium.

• 전기화학회지
• /
• 제9권2호
• /
• pp.70-76
• /
• 2006

마이크로 전기화학 실험법인 비접촉식 미세방울셀이 산 용액에 노출된 저 크롬이 함유된 스테인리스강(STS 316)과 같이 젖음성이 높은 전기화학계에 사용되는데 어려움이 있었다. 음압의 인가, 방울의 크기 제어 그리고 소수성의 개스킷의 사용은 높은 젖음성을 지닌 표면에서 비접촉식 미세방울셀의 적용을 가능하게 하였다. 개선된 미세방울셀의 신뢰성을 확인하고자 3종류의 다른 계-산성염화용액과 고 크롬 페라이트 스테인리스강, 산성염화용액과 STS 316 그리고 중성염화용액과 STS 316-에 대하여 개선된 미세방울셀로 국부부식 연구를 수행하였다. 첫째 산성용액에서 고 크롬강의 양극 분극 결과는 $\alpha/\sigma$ 계면 근처에서 국부부식이 크롬 고갈층에 의한 것임을 보여주었다. 둘째 산성용액에서 STS316의 양극 분극실험이 개선된 미세방울셀에서 성공적으로 수행됨을 확인할 수 있었다. 특히, 미세방울셀에서 얻어진 국부 양극 분극곡선을 통해 STS316의 내식성에 미치는 $\delta$-라이트 영향을 밝힐 수 있었다. 마지막으로 중성염화 용액에서 STS316의 양극 분극곡선은 핏팅 저항성이 $\delta$-페라이트보다 개재물에 의존됨을 보여주었다.

• Journal of Advanced Marine Engineering and Technology
• /
• 제29권5호
• /
• pp.519-525
• /
• 2005

An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint(DFT:25um) was carried out for 5 kinds of heavy anticorrosive paints such as high solid epoxy(HE), solvent free epoxy(SE). tar epoxy(TE), phenol epoxy(PE). and ceramic epoxy(CE). Corrosion current densities obtained by Tafel extrapolation method from anodic and cathodic polarization curves didn't correspond with the values obtained by AC impedance measurement, however, the values of polarization resistance obtained from the cyclic voltammogram showed a good tendency corresponding well with the values of AC impedance measurement. Futhermore there was a good correlation against the corrosion resistance evaluation between passivity current density of the anodic polarization curve and diffusion limiting current density of the cathodic polarization curve. And corrosion resistance increased with corrosion potential shifting to noble direction. From the results discussed above. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paints.