• Archives of Pharmacal Research
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• v.18 no.3
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• pp.183-188
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• 1995

Polymeric reinforcement and coatings of alginate beads were carried out to control the release rate of drug from alginate beads. A poorly water-soluble ibuprofen (IPF) was selected as a model drug. A commercially available $Eudragit^{\circledR}$ RS100 was also used as a polymer. Effects of polymeric contents, the presence of plasticizers and amount of drug loading on the release rate of drug were investigated. The release rate of drug from alginate beads in the simulated gastric fluid did not occur within 2 h but released immediately when dissolution media were switched to the simulated intestinal fluid. No significant difference of release rate from polymer-reinforced alginate bead without plasticizers was observed when compared to plain (simple) beads. However, the release rate of drug from polymer-reinforced alginate beads was further sustained and retarded when aluminium tristearate (AT) as a plasticizer was added to polymer. However, polyethylene glycol 400 (PEG400) did not change the release rate of drug from alginate beads although PEG400 was used to improve dispersion of polymer and sodium alginate, and plasticize $Eudragit^{\circledR}$ RS100 polymer. The presence of plasticizer was crucial to reinforce alginate gel matrices using a polymer. As the amount of drug loading increased, the release rate of drug increased as a result of decreasing effects of polymer contents in matrices. The significantly sustained release of drug from polymer-coated alginate beads occurred as the amount of polymer increased because the thickness of coated membrane increased so that cracks and pores of the outer surface of alginate beads could be reduced. The sustained and retarded action of polymer-reinforced and coated beads may result from the disturbance of swelling and erosion (disintegration) of alginate beads. From these findings, polymeric-reinforcement and coatings of alginate gel beads can provide an advanced delivery system by retarding the release rate of various drugs.

• Journal of Radiation Protection and Research
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• v.3 no.1
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• pp.23-28
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• 1978

In order to investigate corelation between contents of dioctylphthalate in polyvinylchloride blent dibutyl tin dilaulate with dibutyl tin maleate as stabilizer and the behaviors of radiation resistance as well as electrical conductivity on irradiated specimens, several observations were carried out. A characteristic peak observed in the range of $1,540-1,640cm^{-1}$ on infrared spectra shows such a sensitive response to radiation as the intensity decreases with increasing doses and that this tendency strongly depressed in the presence of plasticizer. It is seemingly attributed for origin of the peak to the existence of RCOO- ion resulting from dissociation of stabilizere, further the depressive effect of decreasing peak intensity influenced by radiation seems to be caused by resonance absorption in benzen ring being a consistituent of plasticizer. It is also suggestive to be use the peak behavior influenced by radiation as a criterion for the evaluation of radiation resistance of PVC. Further the results obtained from electrical conductivity measurement also exhibit reasonable characteristics explainable with views used for the interpretation of the peak behavior mentioned previousely.

• Composites Research
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• v.35 no.4
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• pp.232-241
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• 2022

Plasticizers are chemical additives added to polymers to have a desirable effect on mechanical properties such as processability and ductility. In this paper, we explore the use and market of eco-friendly plasticizers that can replace phthalate-based plasticizers that have been traditionally used in the plastics market. Bio plasticizers are derived primarily from biomass sources, including agricultural products, by-products and wastes. Regardless of the source of biomass, an ideal eco-friendly plasticizer should be non-toxic, have high resistance to volatilization, extraction, and migration, have good compatibility and compatibility, and be economical. The global bio plasticizer market is expected to reach USD 2.1 billion by 2030 from USD 1.3 billion in 2020, growing at a CAGR of 5.31% from 2021 to 2030.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.16-24
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• 2018

In this study, an experiment was conducted to analyze mortar based rheology for 3D printing method application. The tendency of rheological properties due to the change of W/B, binder type, replacement ratio, and super plasticizer which have a great influence on the flow characteristics of concrete was experimentally analyzed. Experiments were carried out by dividing into paste and mortar. In the paste experiment, rheology was analyzed by setting W/B, binder type, replacement ratio, and super plasticizer dosage as main variables. In the mortar experiment, the rheological properties of W/B and sand ratio were analyzed. As a result, as the W/B was increased, the viscosity decreased and the FA ratio to replace FA increased and the viscosity increased. In order to increase the fluidity, substitution of only 5% of SF reduces the shear stress and the viscosity is reduced by about 83%. Mortar rheological evaluation shows that there is a critical section where a large change occurs in the W/B 30 to 40% section. Also, in the same W/B, it is analyzed that there is a critical section where the shear stress increases more than twice in the sand ratio of 50~60%.

• Journal of Korean Ophthalmic Optics Society
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• v.16 no.1
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• pp.13-19
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• 2011

Purpose: The purpose of this study was to assess characterize overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established for appropriate glasses frame. Methods: Overseas company's Cellulose acetate glasses frame sheets (overseas company's CA sheet) were characterized by $^1H$-NMR, GPC, and TGA. Also, the optimum content of plasticizer and melt extrusion condition of industrial CA resin were established. Results: The plasticizer of overseas company's CA sheet measured by $^1H$-NMR was diethyl phthalate, and its content was measured 30 wt% by TGA. Also, industrial CA resin showed enough melting behavior in the range of 190~200$^{\circ}C$. Compared to overseas company's CA sheet's tensile strength value of 2.2~2.8 kgf/$mm^2$, industrial CA resin exhibited sufficient tensile strength value of 2.3 kgf/$mm^2$ for glasses frame. Conclusions: Industrial CA resin with 30 wt% plasticizer content would be a promising material for glasses frame prepared by melt extrusion to replace China CA sheet.

• Journal of the Korean Electrochemical Society
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• v.10 no.3
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• pp.213-218
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• 2007

In order to find out proper PVdF gel polymer electrolyte for Li/S battery, we investigated PVdF gel polymer electrolytes with various glyme type plasticizer such as polyglyme, tetraglyme, triglyme. The organic solvents as triglyme, tetraglyme, polyglyme (Mn = 250, 500) has different chain length of ethylene oxide(EO) in solvent of glyme system. ionic conductivity decreased as increasing chain length of EO in plasticizers. Ionic conductivity of PVdF gel electrolyte with tetraglyme, triglyme, polyglyme (Mn = 250, 500) at room temperature was $5{\times}10^{-4},\;3{\times}10^{-4},\;6{\times}10^{-5},\;3{\times}10^{-5}\;S/cm$, respectively. Li/S cell with PVdF gel polymer electrolyte using tetraglyme plasticizer had low interfacial resistance and the highest initial discharge capacity of 1232 mAh/g of active sulfur, which was about 70% utilization of theoretical value.

• Journal of the Korean Society of Food Science and Nutrition
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• v.35 no.1
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• pp.121-125
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• 2006

To study the effects of plasticizer concentration and its ratio on the physical properties of silk fibroin films, polyethylene glycol (PEG) was used at 4 different concentrations; 1, 2, 3, $4.5\%$ (w/v). Tensile strength (TS) and water vapor permeability (WVP) increased with the increase of PEG concentration, while opposite trend was observed for percent elongation of silk fibroin films. WVP of silk fibroin films increased from $2.54\;ng{\cdot}m/m^2spa$ for $1\%$ of PEG to $5.41\;ng{\cdot}m/m^2sPa$ for $4.5\%$. In addition, a mixture of PEG and glycerol (Gly) as a plasticizer was used at the ratio of 100:0, 75:25, 50:50, 25:75, and 0:100 (w/w). Percent elongation of the films was improved to $130.95\%$ when the ratio of 75:25 was used. On the contrary, WVP of silk fibroin films increased with the decrease of the ratio of PEG:Gly. Effect of the plasticizer concentration and its ratio on the color of silk fibroin films was negligible. These results suggest that mixture of PEG and Gly as a plasticizer provide more flexible than PEG alone in silk fibroin films, and the best ratio of PEG to Gly was 75:25.

• Proceedings of the Korean Fiber Society Conference
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• 1987.06a
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• pp.51-51
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• 1987

• Proceedings of the Korean Fiber Society Conference
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• 1994.10a
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• pp.133-134
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• 1994

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.271-275
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• 1996

This study was performed to analyze flowing properties with kinds of the super-plasticizer and flowing effects with agitation method of the mixer truck. After that, this study presents the reference data about better flowing method and quality control when flowing concrete is applied in practice.