• Title/Summary/Keyword: pitch treatment

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Fracture Properties of Nuclear Graphite Grade IG-110 (원자로용급 흑연인 IG-110의 파괴특성)

  • Han, Dong-Yun;Kim, Eung-Sun;Chi, Se-Hwan;Lim, Yun-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.439-444
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    • 2006
  • Artificial graphite generally manufactured by carbonization sintering of shape-body of kneaded mixture using granular cokes as filler and pitch as binder, going through pitch impregnation process if necessary and finally applying graphitization heat treatment. Graphite materials are used for core internal structural components of the High-Temperature Gas-cooled Reactors (HTGR) because of their excellent heat resistibility and resistance of crack progress. The HTGR has a core consisting of an array of stacked graphite fuel blocks are machined from IG-110, a high-strength, fine-grained isotropic graphite. In this study, crack stabilization and micro-structures were measured by bend strength and fracture toughness of isotropic graphite grade IG-110. It is important to the reactor designer as they may govern the life of the graphite components and hence the life of the reactor. It was resulted crack propagation, bend strength, compressive strength and micro-structures of IG-110 graphite by scanning electron microscope and universal test machine.

USE OF ENZYMES FOR MODIFICATION OF DISSOLVED AND COLLOIDAL SUBSTANCES IN PROCESS WATERS OF MECHANICAL PULPING

  • Johanna Buchert;Annikka Mustrnata;Peter Spetz;Rainer Ekman;Kari Luukko
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.115-119
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    • 1999
  • During mechanical pulp production and blcaching wood components, such as extractives, carbohydrates and lignin are dissolved and dispersed into the process waters. These components are called dissolved and colloidal substances(DCS). DCS can accumulate during water circulation and can in turn affect paper machine runnability and also the strength and optical properties of the paper. In this work DCS fraction origination from TMP process were treated with enzymes acting on triglycerides. glucomannans, and lignin and the effect of enzymatic treatments on the water composition as well as sheet properies were evaluated. Lipases were found to modify the chemical structure of the extractives resulting in more hydrophilic fibre surface and subsequent improvement in the sheet strength properties. Mannanase treatment, on the other hand, destabilized pitch. As a result, aggregation of pitch to the fibres was observed which in turn resulted in impaired strength properties. Laccase could effectively polymerize lignans and the reaction products seemed to be sorbed onto the fibres.

Electrochemical Characteristics of Surface Modified CTP Anode by H3PO4 Treatment (인산 처리된 표면 개질 음극 석탄계 피치의 전기화학적 특성)

  • Lee, Ho Yong;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.415-420
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    • 2016
  • To enhance electrochemical performances of anode materials, the surface of coal tar pitch (CTP) was modified by incorporating heteroatoms through chemical treatment with phosphoric acid ($H_3PO_4$). The prepared anode materials with modified CTP was analyzed by XRD, FE-SEM and XPS. The electrochemical performances of modified CTP were investigated by constant current charge/discharge test, rate performance, cyclic voltammetry and impedance tests using the electrolyte of $LiPF_6$ dissolved in the mixed organic solvents (ethylene carbonate : dimethyl carbonate = 1 : 1 vol% + vinylene carbonate 3 wt%). The coin cell using modified CTP ($H_3PO_4/CTP$ = 3 : 100 in weight) has better initial capacity and initial efficiency (489 mAh/g, 82%) than those of other composition coin cells. Also, it was found that the capacity retention was 86% after 30 cycles and the rate capability was 87% at 2 C/0.1 C.

Optimization Technology of Thermomechanical Pulp Made from Pinus densiflora (I) - Effect of Temperature and NaOH at Presteaming and Refining - (국내산 소나무로 제조되는 열기계펄프 제조 기술 최적화 연구 (1) - 목재 칩의 전처리와 리파이닝 시 온도와 NaOH 처리의 효과 -)

  • Nam, Hyegeong;Kim, Chul-Hwan;Lee, Ji-Young;Park, Hyunghun;Kwon, Sol;Cho, Hu-Seung;Lee, Gyeong-Sun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.35-44
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    • 2015
  • Thermomechanical pulping process uses large amounts of energy, mostly electricity to run electrical facilities. Thermomechanical pulp (TMP) made from Pinus densiflora also has a big drawback that refining consumes 90 per cent of the total energy used in TMP process. This study explored to draw up a way to save refining energy through different thermal treatment at the stages of presteaming and refining. Presteaming temperature was $80^{\circ}C$, $100^{\circ}C$, and $120^{\circ}C$. After presteaming at each temperature, refining was carried out at $100^{\circ}C$, $120^{\circ}C$, and $140^{\circ}C$ respectively. In a presteaming stage, steaming temperature over $120^{\circ}C$ greatly contributed to the decrease of refining energy leading to earlier attainment of a target freeness, irrespective of refining temperature. In addition, NaOH treatment with presteaming enhanced better development of fiber properties during refining than presteaming without NaOH. High temperature refining at $140^{\circ}C$ produced a high strength paper, and wood chips treated by alkali responded better to refining than at over $120^{\circ}C$. Improved softening effect on wood chips led to the decrease in shives contents but it gave no effect on pitch contents of TMP.

Radiographic Characteristics and the Clinical Results of the Operative Treatment of the Tarsometatarsal Osteoarthritis with Hallux Valgus Deformity (무지 외반증에 동반된 중족 설상 관절염의 방사선학적 특징과 수술적 치료 결과)

  • Choi, Hong-Joon
    • Journal of Korean Foot and Ankle Society
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    • v.17 no.2
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    • pp.121-129
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    • 2013
  • Purpose: To evaluate the radiographic characteristics of the tarsometatarsal osteoarthritis with hallux valgus deformity and report the clinical results of the operative treatment. Materials and Methods: This is a retrospective study of 20 patients, 22 feet who had been operated for non-traumatic tarsometatarsal osteoarthritis with hallux valgus (TMT group) and control group of hallux valgus patients without tarsometatarsal osteoarthritis (26 patients, 28 feet) from April 2004 to July 2011. Radiographic characteristics were compared between the groups, using hallux valgus angle, $1^{st}-2^{nd}$ intermetatarsal angle, metatarsal length ratio, metatarsus adductus angle, talonavicular coverage angle, talus-$1^{st}$ metatarsal angle, calcaneal pitch angle and medial cuneiform height. Pre- and postoperative difference of $1^{st}-2^{nd}$ metatarsal declination angle and distance between the $1^{st}-2^{nd}$ metatarsal head were evaluated. The clinical results were evaluated by American Orthopaedics Foot and Ankle Society (AOFAS) midfoot scale and visual analogue scale (VAS). Results: Metatarsal length ratio was significantly larger in TMT group (p<0.001). Metatarsus adductus angle, talonavicular coverage angle, talus-$1^{st}$ metatarsal angle on lateral radiograph, calcaneal pitch angle and medial cuneiform height were different from control group (p<0.001, p<0.001, p=0.001, p=0.010, p=0.006). Postoperative declination of the $2^{nd}$ metatarsal and distance between the $1^{st}-2^{nd}$ metatarsal head were increased (p=0.009, p=0.001). The AOFAS and VAS score were improved (p<0.001, p<0.001). Conclusion: Non-traumatic osteoarthritis of the tarsometatarsal joints seems to be associated with long 2nd metatarsal length, metatarsus adductus and flatfoot deformity. Spur excision may be successful to relieve symptoms when the arthritis was diagnosed in early stage.

Performance of Structural Glulam Laminated with CuAz-3 Preservative Treated Lumber (CuAz-3처리 리기다소나무 제재목을 이용한 구조용 집성재 성능 평가)

  • Kim, Kwang-Mo;Eom, Chang-Deuk;Lee, Sang-Joon
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.6
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    • pp.521-530
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    • 2011
  • Nowadays, market demand of structural Glulam is growing and diversifying. The durability of Glulam should be significantly considered when they are intended to apply for out-door use such as timber bridge and pergola. This study was aimed to develop the manufacturing process of preservative treated structural Glulam using domestic softwood species. 10 m long structural Glulam were manufactured from domestic pitch pine logs with CuAz-3 preservative treatment. At each manufacturing process, the production yield was evaluated. Finally, bending tests were performed to verify the structural performance of manufactured Glulam. From the results, it was shown that the preservative treatment process hardly influenced on the production yield. But domestic pitch pine was proved to not be suitable for making the preservative treated Glulam due to the large difference of preservative permeability between sapwood and heartwood.

New emerging surface treatment of GFRP Hybrid bar for stronger durability of concrete structures

  • Park, Cheolwoo;Park, Younghwan;Kim, Seungwon;Ju, Minkwan
    • Smart Structures and Systems
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    • v.17 no.4
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    • pp.593-610
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    • 2016
  • In this study, an innovative and smart glass fiber-reinforced polymer (GFRP) hybrid bar was developed for stronger durability of concrete structures. As comparing with the conventional GFRP bar, the smart GFRP Hybrid bar can promise to enhance the modulus of elasticity so that it makes the cracking reduced than the case when the conventional GFRP bar is used. Besides, the GFRP Hybrid bar can effectively resist the corrosion of conventional steel bar by the GFRP outer surface on the steel bar. In order to verify the bond performance of the GFRP hybrid bar for structural reinforcement, uniaxial pull-out test was conducted. The variables were the bar diameter and the number of strands and pitch of the fiber ribs. Tensile tests showed a excellent increase in the modulus of elasticity, 152.1 GPa, as compared to that of the pure GFRP bar (50 GPa). The stress-strain curve was bi-linear, so that the ductile performance could be obtained. For the bond test, the entire GFRP hybrid bar test specimens failed in concrete splitting due to higher shear strength resulting in concrete crushing as a function of bar deformation. Investigation revealed that an increase in the number of strands of fiber ribs enhanced the bond strength, and the pitch guaranteed the bond strength of 19.1 mm diameter hybrid bar with 15.9 mm diameter of core section of deformed steel the ACI 440 1R-15 equation is regarded as more suitable for predicting the bond strength of GFRP hybrid bars, whereas the CSA S806-12 prediction is considered too conservative and is largely influenced by the bar diameter. For further study, various geometrical and material properties such as concrete cover, cross-sectional ratio, and surface treatment should be considered.

Shoulder and Elbow Injury Rates and Patterns in Korean Rookie Professional Baseball Pitchers

  • Park, Jin-Young;Lee, Seung-Jun;Kim, Yong-Il;Heo, Gu-Yeon
    • Clinics in Shoulder and Elbow
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    • v.19 no.1
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    • pp.15-19
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    • 2016
  • Background: To investigate how many rookie pitchers suffered from injuries while playing in the amateur league without guidelines for prevention of excessive pitching, we analyzed their amateur pitching patterns based on the pitch count, use of breaking balls, and pitches during winter camp. Methods: Forty-one rookie pitchers who graduated from high school or university in 2013 and joined professional baseball teams. Participants were interviewed by a trainer using our questionnaire. Injury inclusion criteria were 1) history of shoulder surgery, 2) history of elbow surgery, 3) shoulder pain requiring treatment, and 4) elbow pain requiring treatment. Results: Mean number of pitches per game and warm-up pitches for practice was 84.5 pitches (range, 15 to 130 pitches) and 16.4 pitches (range, 2 to 210 pitches), respectively. Mean number of pitches during the last year was 906.9 (range, 80 to 2,000). Mean number of maximal pitches was 127 pitches (range, 50 to 210 pitches). Fourteen pitchers had pitched over 150 pitches. Twenty-seven pitchers (65.9%) had pitched in spite of enduring pain. During winter training (mean 1.8 months), mean number of pitches per day was 162.5 pitches, and 20 pitchers (48.8%) had practiced pitching excessively despite the cold weather. Twenty-six rookies (63.4%) had shoulder pain or history of shoulder surgery, and 31 pitchers (75.6%) had elbow pain or history of elbow surgery. Only four participants (9.8%) did not have pain and history of surgery. Conclusions: For young baseball pitchers, guidelines for prevention of excessive pitching and for regulating the winter training program may be needed.

Patterning of high resolution metal electrodes using selective surface treatment and dip casting for printed electronics (선택적 표면처리와 딥코팅 방법을 이용한 고해상도 금속 패턴 형성연구)

  • Kim, Yong-Hoon;Eom, You-Hyun;Park, Sung-Kyu;Oh, Min-Seok;Kang, Jung-Won;Han, Jeong-In
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1340_1341
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    • 2009
  • In this report, high-resolution metal electrode patterning is demonstrated by using selective surface treatment and dip casting for low-cost printed electronic applications. On hydrophobic octadecyltrichlorosilane treated $SiO_2$ surface, deep UV irradiation was performed through a patterned quartz photomask to selectively control the surface energy of the $SiO_2$ layer. The deep UV irradiated region becomes hydrophilic and by dipping into Ag nano-ink, Ag patterns were formed on the surface. Using this patterning technique, line patterns and dot arrays having less than $10{\mu}m$ pitch were fabricated.

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Viscoelastic Damping Treatment Analysis and Aeroelasticity for Vibration Reductions of a Hingeless Composite Helicopter Rotor System (무힌지 복합재 헬리콥터 로터 시스템의 진동 저감을 위한 점탄성 감쇠처리 해석 및 공탄성 연구)

  • Hwang, Ho-Yon
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.15 no.3
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    • pp.6-14
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    • 2007
  • In this research, vibration reduction and aeroelastic stability of a composite hingeless rotor hub flexure with viscoelastic constrained layer damping treatment(CLDT) were investigated. The composite flexures with viscoelastic CLDT were applied to hingeless rotor system to improve the in-plane stability of the lead-lag motion causing resonance. The modal test was performed and dynamic properties(natural frequency and loss factor) were acquired. Also, complex eigenvalue analysis(SOLlO7) in the NASTRAN structural analysis module was performed and compared with results of the modal test. To insure aeroelastic stability, damping ratio analyses of the hingeless rotor system with CLDT were accomplished at hovering condition due to collective pitch angle changes. Satisfactory results of increasing structural damping and stability were obtained.

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