• Carbon letters
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• 제1권1호
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• pp.6-11
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• 2000

Coal tar pitch was chemically modified with 10 wt% benzoquinone (BQ) to raise the softening point of isotropic pitch precursor and the precursor was melt-spun into pitch fibers, stabilized, carbonized and activated with steam at $900^{\circ}C$. The weight loss of carbon fiber-benzoquinone (CF-BQ) increased with the increase of activation time like other fibers, but was lower than those of Kureha fiber at the same activation time in spite of larger geometric surface area. Those adsorption isotherms fitted into 'Type I' according to Brunauer, Deming, Deming and Teller classification. However, there was very thin low-pressure hysteresis that lower closure points of the hysteresis are about 0.42-0.45. From the pore size distribution curves, there might be some micropores having narrow-necked bottle; a series of interconnected pore is more likely than discrete bottles. FT-IR studies showed that the functional groups such as carboxyl, quinone, and phenol were introduced to ACFs-BQ surface after steam activation. Methylene blue decolorization and iodine adsorption capacity of ACF-BQ increased linearly with the increase of specific surface area and was larger than that of ACF-Kureha at the same specific surface area.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.343-349
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• 1994

The purpose of this study is to investigate the mechanical properties of floor slab structures with high-strength and lightweight CFRC panel using fly ash, PAN-derived and Pitch-derived carbon fiber. As a result, the flexural strength of CFRC is remarkably increased by CF contents, but compressive strength of the CFRC is not so increased as flexural strength. The bulk specific gravity is influenced by FA contents more than by CF contents, The compressive strength and the flexural strength are increased by FA contests, but decreased the case of 30% of contents. In order to increasing the flexural-carrying capacity of floor slab structures, it is recommended that the shape of anchor for reinforcement is required type-C and the spacing of anchor is required below 60mm.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.655-660
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• 2002

The purpose of this study is to analyze void ratio, coefficient of water permeability, and strength characteristics when silica fume and carbon fibers were added in order to improve the strength of porous concrete, and when recycled aggregates were used. Comparing with the case that recycled aggregate was not used, as the replacement ratio of recycled aggregate increased, the differences in void ratios and strength characteristics were decreased. In the case that silica fume was used, the content of 10% silica fume was most effective in improving strength. In the case that carbon fibers were used, the content of 3% carbon fiber were good to achieve the highest flexural strength, and Pan-derived CF was much better than pitch-derived CF in improving these effects.

• International Journal of Concrete Structures and Materials
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• 제18권1E호
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• pp.29-34
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• 2006

Elastic modulus, tensile and bond capacities are important factors for developing an effective reinforcing action of a flexural member as a reinforcing material for concrete structures. Reinforcement must have enough bond capacity to prevent the relative slip between concrete and reinforcement. This paper presents an experimental study to clarify the bond capacity of prestressed carbon fiber reinforced polymer(CFRP) rod manufactured by an automatic assembly robot. The bond characteristics of CFRP rods with different pitch of helical wrapping were analyzed experimentally. As the result, all types of CFRP rods show a high initial stiffness and good ductility. The mechanical properties of helical wrapping of the CFRP rods have an important effect on the bond of these rods to concrete after the bond stress reached the yield point. The stress-slip relationship analyzed from the pull-out test of embedded cables within concrete was linear up to maximum bond capacity. The deformation within the range of maximum force seems very low and was reached after approximately 1 mm. The average bond capacity of CF20, CF30 and CF40 was about 12.06 MPa, 12.68 MPa and 12.30 MPa, respectively. It was found that helical wrapping was sufficient to yield bond strengths comparable to that of steel bars.

• Korean Chemical Engineering Research
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• 제45권3호
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• pp.269-276
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• 2007

$TiO_2$ 함유 피치섬유의 최적 안정화 조건을 도출하기 위하여 $TiO_2$의 함유량을 달리하여 피치섬유를 제조한 후, 여러가지 안정화 조건에 대한 섬유의 특성 변화와 금속입자의 거동을 관찰하였다. 공기에 의한 피치섬유의 안정화시 안정화온도가 높고, $TiO_2$ 함유량이 적을수록 산화에 의한 무게증가가 컸다. 안정화된 섬유를 탄화하면 수율은 71~82 wt.% 수준인데, $TiO_2$가 활성촉매 역할을 하여 $TiO_2$의 함유량이 많을수록 탄화수율은 낮았다. 안정화 과정에서 열가소성의 피치섬유는 산소의 도입으로 카르보닐기(C=O)와 카르복실기(-COOH) 등이 형성되며 동시에 이들이 가교결합을 이루고 수소를 탈리시켜 열경화성 섬유로 전환되었다. 활성탄소섬유의 기공크기는 $TiO_2$ 함유량이 증가함에 따라 점점 커졌으며, 주사전자현미경과 투과전자현미경을 통하여 섬유의 표면과 내부에 분포된 $TiO_2$ 입자와 분포를 관찰한 결과 안정화, 탄화 및 활성화공정 중 일부 $TiO_2$가 서로 뭉침을 알 수 있었다. 최종적으로 0.5 wt.% $TiO_2$ 함유 석유계 피치섬유는 $280^{\circ}C$에서 3 hr를 최적 안정화 조건으로 제시할 수 있었다.

• 콘크리트학회지
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• 제4권1호
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• pp.107-118
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• 1992

본 연구는 고강도 고내구성이면서 신뢰성이 높은 폴리머 함침 탄소섬유보강 시멘트복합에의 개발 응용을 위한 여러 가지 특성을 검토하기 위하여, 복합체는 PAN계 및 Pitch계 탄소섬유, 조강포틀랜드 시멘트, Silica Powder 및 폴리머 함침재를 사용하여 제조하였고, 배합조건별, 재령별, 그리고 양생조건별로 역학적특성, 동결융해저항성 및 장기변형특성에 관한 실험연구를 행하였다. 연구결과, CFRC의 Flow값은 CF혼입율 증가에 따라 거의 직선적으로 저하하였고, 폴리머 함침 CFRC의 압축 인장 휨강도는 CF혼입율 증대에 따라 오토클래브 양생 및 기건양생의 경우에 비하여 현저히 증대하였으며, 또한 월등히 높은 강도를 나타내었다. 그리고, 인자응력-변형관계 및 휨응력-처짐관계는 기건양생 및 오토클래브 양생의 경우 연성적인 비선형을 나타낸 데 비하여 폴리머함침의 경우는 거의 직선적 으로 변화하였고, 동결융해저항성, 건조수촉변형특성 및 내크리프 특성도 다른 양생 방법의 경우에 비하여 크게 개선됨을 확인하였다.

• Carbon letters
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• 제1권2호
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• pp.69-75
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• 2000

Naphtha cracking bottom oil was reformed with heat treatment and then spun at $310^{\circ}C$. These pitch-based carbon fibers were carbonized at $1000^{\circ}C$ after oxidation at $280^{\circ}C$, for 90 min. These fibers were chemically activated with molar ratio of KOH/CF (1 : 1) at different temperatures ($250{\sim}900^{\circ}C$) for 1 hr. The process of activation was characterized with DTA, TGA, BET surface area and pore size distribution. The activation of fibers by KOH was performed by several process. One is the reduction process that carbon fiber was reacted with $K_2O$ produced from dehydration process above $400^{\circ}C$. The other is the process that $K_2CO_3$ was directly reacted with carbon fiber. At $800^{\circ}C$, the activation was performed by catalyzed mechanism that $K_2O$ was obtained from the reaction of metal potassium with $CO_2$, then was changed to $K_2CO_3$. At $870^{\circ}C$, the activation was also observed that activation mechanism was promoted by metal catalyst with $CO_2$ from decomposition of $K_2CO_3$. The specific surface area of prepared activated carbon fibers was dependent on the activation mechanism. The specific surface area was in the range of $1519{\sim}2000\;cm^3/g$ and was the largest prepared at $870^{\circ}C$. The pores developed were mostly micropores which was very narrow and uniform. The total pore volume was $0.58{\sim}0.77\;cm^3/g$.