• Title/Summary/Keyword: physico-chemistry

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Pharmacognostical Evaluation of the Roots of Pseudarthria viscida (Linn.)

  • Rajendran, K.;Srinivasan, K.K.;Shirwaikar, Annie
    • Natural Product Sciences
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    • v.13 no.3
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    • pp.214-219
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    • 2007
  • The roots of Pseudarthria viscida (L.) Wight and Arnott. (Leguminosae) are used against various disorders in Indian systems of medicine, namely as anthelmintic, anti-inflammatory, cardiotonic, aphrodisiac, rejuvenating, tonic and as a remedy for cough, asthma, tuberculosis, diarrhoea and alternate fever. The present communication deals with the detailed pharmacognostical evaluation of the root sample using light and confocal microscopy, WHO recommended physico-chemical determinations and authentic phytochemical procedures. he physico-chemical, morphological and histological parameters presented in this paper may be proposed as parameters to establish the authenticity of P. viscida root and may possibly help to differentiate the drug from its other species.

Pharmacognostical Identification of Stem and Root of Ipomoea quamoclit (Linn.)

  • Rajendran, K.;Srinivasan, K.K.;Shirwaikar, Annie
    • Natural Product Sciences
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    • v.13 no.4
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    • pp.273-278
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    • 2007
  • This paper presents a detailed pharmacognostical study of the stem and root of the crude drug Ipomoea quamoclit Linn. (Convolvulaceae). Morphoanatomy of the stem and root have been studied with the aim to aid pharmacognostic and taxonomic species identification using light and confocal microscopy, WHO recommended physico-chemical determinations and authentic phytochemical procedures. The physico-chemical, morphological and histological parameters presented in this paper may be proposed as parameters to establish the authenticity of stem and root of I. quamoclit and may possibly help to differentiate the drug from its other species.

Comparative Study of Fatty Acid Composition and Characterization of Fixed Oil of Four Peanut Varieties Available in Pakistan

  • Akhtar, Hifza;Hamid, Shahnaz;Khan, Javed Iqbal
    • Natural Product Sciences
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    • v.11 no.4
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    • pp.225-228
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    • 2005
  • four varieties of ground nut (Arechis hypogea) were collected from different areas of Pakistan (Tillagang, Gujar khan, Hanoi and Pipplan) from Punjab province. The oils were extracted for the evaluation of lipid. Physico-chemical values of oils were determined like refractive index, peroxide value, unsaponifiable matter, acid value, iodine value, free fatty acid and ester value. The lipid profile as indicated by GLC showed that Palmitic acid ranged from 8.2-8.8%, proportions of oleic acid and linoleic acid varied from 57.8-59.87% and 22.5-24.1% respectively. Gujar khan variety of peanut has higher % age of oil (56.79). The higher yield of oil in this variety is not at the cost of any nutritional quality of peanut oil.

5-(Hydroxymethyl)-2-furfuraldehyde, Anticonvulsant Furan from the Arils of Euphoria longana L.

  • Kim, Dong-Hyun;Kim, Dae-Won;Choi, Soo-Young;Park, Chang-Ho;Baek, Nam-In
    • Journal of Applied Biological Chemistry
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    • v.48 no.1
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    • pp.32-34
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    • 2005
  • Arils of Euporia longana L. was extracted with 80% aqueous MeOH and partitioned successively with EtOAc, n-BuOH and $H_2O$. From the n-BuOH fraction, furan compound was isolated through silica gel column chromatography. The results of physico-chemical data including NMR, MS and IR revealed the compound to be 5-(hydroxymethyl)-2-furfuraldehyde. This compound stimulated GDH I activity by $19.2{\pm}0.6$, $41.2{\pm}0.9$, $68.4{\pm}1.1$, $80.3{\pm}0.9$ and $85.9{\pm}1.6%$ at in vitro concentrations of 0.005, 0.008, 0.02 and 0.03 %, respectively.

Development of Gold Phosphorus Supported Carbon Nanocomposites

  • Mayani, Vishal J.;Mayani, Suranjana V.;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.401-406
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    • 2014
  • Metal-containing carbon nanocomposites have shown significance promise in the area of energy storage, heterogeneous catalysis and material science because of their morphology and combined properties. Phosphorus-doped carbon nanocomposites with gold nanoparticles were developed by applying a simple impregnation method and metal deposition technique. Gold-phosphorus supported carbon nanocomposites with two sized (25 and 170 nm) were prepared from economical petroleum pitch residue as the carbon source using an advanced silica template method. These nanocomposites will lead to the novel applications in the field of material science with the combined properties of gold, phosphorus and carbon. The newly prepared gold phosphorus supported carbon nanocomposites were fully characterized using a range of different physico-chemical techniques.

Synthesis, Characterization and Enhanced Selectivity in RP-HPLC of Polar Carbonyl Group Embedded Poly (Vinyl Octadecanoate) Grafted Stationary Phase by Simple Heterogeneous "Graft from" Technique

  • Rana, Ashequl A.;Karim, Mohammad Mainul;Takafuji, Makoto
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.77-82
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    • 2011
  • A new high performance liquid chromatograpgy (HPLC) stationary phase that possesses an internal carbonyl functional group is synthesized by heterogeneous "graft from" method. This new stationary phase, poly (vinyl octadecanoate) grafted silica (Sil-2) is then characterized by different physico-chemical methods such as diffuse reflectance infrared fourier transform, suspension state $^1H$ NMR, solid state $^{13}C$ CP/MAS NMR, $^{29}Si$ CP/MAS NMR, elemental analysis and thermogravimetric analysis. Chromatographic properties of Sil-2 were evaluated under reversed phase condition by separating polycyclic aromatic hydrocarbons (PAHs) and comparing the chromatographic results with those on polymeric as well as monomeric octadecylated silica stationary phases.

Relatedness of Naturalized Bradyrhizobium japonicum Populations with Soil Physico-Chemical Characteristics as Affected by Paddy-Upland Rotation (답전윤환에 따른 토착 Bradyrhizobium japonicum의 서식밀도와 토양 이화학성과의 관계)

  • Park, Chang-Young;Youn, Moon-Tae;Choi, Sang-Uk;Ha, Ho-Sung;Kang, Ui-Gum
    • Applied Biological Chemistry
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    • v.40 no.5
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    • pp.438-441
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    • 1997
  • The relatedness of naturalized Bradyhizobium japonitum populations with soil physico-chemical characteristics as affected by paddy rice-upland soybean rotation cropping with conventional and none fertilization in Chilgog clay loam soils were determined as follows. The populations of B. japonicum in soils were increased from about $10^1$ in continuous paddy upto $10^1cells/g.soil$ only in one-year rotation of upland use with soybean cropping. Compared to the densities in plots of conventional fertilization, those in none fertilization were high ranging from 1.9 to 10 fold in 2-year upland use rotation and both in 3-year upland use rotation and 4-year upland use, respectively. The populations were positively correlated with soil organic matter $contents(r=0.83^*),\;Ca/K(r=0.74^*),\;and(Ca+Mg)/K(r=0.72^*)$ and were negatively correlated with soil $hardness(r=-0.73^*)$. And the soil populations increased by paddy-upland rotation resulted in superior symbiotic potentials to those in continuous paddy use in terms of nodule mass, nitrogenase activity, and soy-bean shoot dry weight.

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The Synthesis and Electrochemical Properties of Lithium Manganese Oxide (Li2MnO3)

  • Seo, Hyo-Ree;Lee, Eun-Ah;Yi, Cheol-Woo;Kim, Ke-On
    • Journal of Electrochemical Science and Technology
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    • v.2 no.3
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    • pp.180-185
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    • 2011
  • The layered lithium-manganese oxide ($Li_2MnO_3$) as a cathode material of lithium ion secondary batteries was prepared and characterized the physico-chemical and electrochemical properties. The morphological and structural changes of MnO(OH) and $Li_2MnO_3$ are closely connected to the changes of electrochemical properties. The crystallinity of $Li_2MnO_3$ is enhanced as the annealing temperature increase, but its capacity is reduced due to the easier structural changes of less crystalline $Li_2MnO_3$ than highly crystalline one. Moreover, the addition of buffer material such as MnO(OH) into cathode causes to reduce the morphological and structural changes of layered $Li_2MnO_3$ and increase the discharge capacity and cycleability.

Selection and Physico-Chemical Characteristics of Lactic Acid Bacteria which had Cholesterol Lowering Activities (콜레스테롤 저하 유산균의 분리 및 이들 균주의 이화학적 특성)

  • Oh, Min-Keun;Rhee, Yong-Hwan;Choi, Ki-Chun;Lee, Yong-Kyu;Shin, Seung-Yee;Kim, Jong-Hyun
    • Applied Biological Chemistry
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    • v.42 no.2
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    • pp.83-90
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    • 1999
  • Four strains of lactic acid bacteria which had cholesterol lowering activities were selected from foreign fermented milk. The strains were identified as Lactobacillus(L.) rhamnosus 2084, L. casei 0781, Lactococcus (Lacto.) lactis spp. 204, and Enterococcus(E.) faecium 402. We observed that the L. rhamnosus 2084 was the most tolerant against pH 1.5, L. casei 0781 against pH 2.0, but not significantly different in the tolerance against pH 3.0. The L. rhamnosus 2084 was the most tolerant against bile acid and prominent in the degree of lowering cholesterol level. All four strains were used as starters in producing yogurt, and then investigated physico-chemical characteristics, such as pH, titratable acidity, and viable cell counts of yogurt base. L. casei 0781, L. rhamnosus 2084, Lacto. lactis 204, and E. faecium 402 were incubated for 6 hours at $40^{\circ}C$, 4 hours at $40^{\circ}C$, 6 hours at $37^{\circ}C$, and 12 hours at $37^{\circ}C$ and $40^{\circ}C$, respectively, for the optimum conditions of fermented milk.

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