• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2897-2902
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• 2010

Seven fully optimized geometries of 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) dimers have been obtained with density functional theory (DFT) method at the B3LYP/$6-311++G^{**}$ level. The intermolecular interaction energy was calculated with zero point energy (ZPE) correction and basis set superposition error (BSSE) correction. The greatest corrected intermolecular interaction energy of the dimers is $-23.69\;kJ{\cdot}mol^{-1}$. Natural bond orbital (NBO) analysis is performed to reveal the origin of the interaction. Based on the vibrational analysis, the changes of thermodynamic properties from the monomers to dimer with the temperature ranging from 200.0 K to 800.0 K have been obtained using the statistical thermodynamic method. It was found that the hydrogen bonds dominantly contribute to the dimers, while the binding energies are not only determined by hydrogen bonding. The dimerization process can not occur spontaneously at given temperatures.

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2086-2092
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• 2013

Two new high-nitrogen energetic compounds $ZTO{\cdot}2H_2O$ and $ZTO(phen){\cdot}H_2O$ have been synthesized (where ZTO = 4,4-azo-1,2,4-triazol-5-one and phen = 1,10-phenanthroline). The crystal structure, elemental analysis and IR spectroscopy are presented. Compound 1 $ZTO{\cdot}2H_2O$ crystallizes in the orthorhombic crystal system with space group Pnna and compound 2 $ZTO(phen){\cdot}H_2O$ in the triclinic crystal system with space group P-1. In $ZTO(phen){\cdot}H_2O$, there is intermolecular hydrogen bonds between the -NH group of ZTO molecule (as donor) and N atom of phen molecule (as acceptor). Thermal decomposition process is studied by applying the differential scanning calorimetry (DSC) and thermo thermogravimetric differential analysis (TG-DTG). The DSC curve shows that there is one exothermic peak in $ZTO{\cdot}2H_2O$ and $ZTO(phen){\cdot}H_2O$, respectively. The critical temperature of thermal explosion ($T_b$) for $ZTO{\cdot}2H_2O$ and $ZTO(phen){\cdot}H_2O$ is $282.21^{\circ}C$ and $195.94^{\circ}C$, respectively.

• Polymer(Korea)
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• v.38 no.4
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• pp.425-433
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• 2014

In this study, microstructure and gel content (C-C) of polybutadiene rubber (PBR) were investigated using various techniques including ASTM D 3616, attenuated total reflectance Fourier transform infrared spectrometry (ATR FTIR), differential scanning calorimetry (DSC) and nuclear magnetic resonance spectroscopy (NMR). The ATR FTIR spectra of the samples were investigated to determine the cis, trans, 1, 2-vinyl and the C-C gel content in PBR. The absorbance ratios of specific peaks in different grades of PBR were correlated with the C-C gel content measured by the ATR FTIR techniques. Physico-mechanical and rheological properties of rubber compounds based on BR with various amounts of gel were determined. The results showed that there is an acceptable correlation between these properties and the C-C gel content of PBR.

• Applied Biological Chemistry
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• v.41 no.6
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• pp.451-456
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• 1998

To find out the repeated application effect of chicken and pig manure composts on tomato growth and soil physico-chemical properties, different rates of the composts were applied to greenhouse soils with low fertility for 3 years and tomato was grown annually. As application rate of compost increased, the growth and fruit yield of tomato increased markedly, and there are also a little increase in sugar content in fruit juice and weight per fruit. When only compost was applied, however, physical and chemical properties in soil showed to be unbalanced such as significantly low bulk density and hardness, and high porosity as well as high organic matter and exchangeable K content, and low exchangeable Ca content than those of optimum range for soil diagnosis. Therefore mixed use of compost and chemical fertilizer is more promising way than the only use of compost to make suitable physico-chemical properties for tomato growth.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1305-1311
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• 2014

The nickel oxide, the most widely used cathode material for the molten carbonate fuel cell (MCFC), has several disadvantages including NiO dissolution, poor mechanical strength, and corrosion phenomena during MCFC operation. The surface modification of NiO with lanthanum maintains the advantages, such as performance and stability, and suppresses the disadvantages of NiO cathode because the modification results in the formation of $LaNiO_3$ phase which has high conductivity, stability, and catalytic activity. As a result, La-modified NiO cathode shows low NiO dissolution, high degree of lithiation, and mechanical strength, and high cell performance and catalytic activity in comparison with the pristine NiO. These enhanced physico-chemical and electrochemical properties and the durability in marine environment allow MCFC to marine application as a auxiliary propulsion system.

• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.239-247
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• 2022

The physico-chemical properties of agricultural soil are factors that affect crop productivity and soil fertility. In Korea, agricultural environment change surveys have been conducted every four years since 1999. The purpose of this study is to investigate the status and changes in the physico-chemical properties of agricultural soil in Chungcheongnam-do. Samples were collected from the exact location of the aforementioned environment survey, and environmental variables (land use, type of crop cultivated) were investigated in relation to the samples. Soil collection was conducted using a core sampler and a single gouge auger. The bulk density of the soil generally increased up to a depth of sampling of 40 cm but decreased thereafter to a depth of 60 cm. Additionally, the bulk density was highest in the upland soil case and stood at 1.59 g·cm^-3, while the lowest value of 1.52 g·cm^-3 was obtained from orchard soil samples. Conversely, the porosity and moisture gradually decreased at soil depths of 0 - 40 cm and increased at depths of 40 - 60 cm. Most of the soil chemical properties generally decreased with an increase the soil depth from 0 to 70 cm, but electrical conductivity (EC) increased up to a depth of 40 cm. Therefore, it is judged that it is necessary to lower the bulk density by supplying organic matter for agricultural land in Chungcheongnam-do.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2000.06a
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• pp.53-53
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• 2000

• Journal of the Korea Organic Resources Recycling Association
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• v.7 no.1
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• pp.23-30
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• 1999

The changes of soil physico-chemical properties were investigated in the sandy loam soil amended with various application rates of chicken and pig manure composts. After repeated application of the composts for 3 years, total nitrogen content in soil treated with applied 120Mg/ha of chicken and pig manure composts was 2.1 g/kg equally. Organic matter content was 38.8 and 39.1 g/kg, available phosphate content was 602 and 585 mg/kg, and cation exchange capacity(CEC) was 10.1 and 12.4 cmol/kg in chicken and pig manure compost 120 Mg/ha treatment, respectively. Exchangeable K, Ca, Na, Mg contents, and electrical conductivity(EC) increased with the amount of applied compost. Also, with increased amount of applied compost, porosity of soil increased, but hardness, bulk density and Y value decreased.

• Korean Journal of Environmental Agriculture
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• v.17 no.2
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• pp.170-173
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• 1998

This study was conducted to investigate the effect of municipal sludge application on the change of physico-chemical properties and contents of heavy metals in soils. The application of the sludge resulted in increasing the content of total nitrogen, available phosphate,exchangeable K, Ca, Mg, and the soil porosity and permeability but soil hardness was reduce. It is clear that application of municipal sewage sludge would not due to increase in the heavy metals content in soil because of the lower concentration of heavy metal in the sludge. Totally it is evident that municipal sewage sludge application should play an important role in improving soil physico-chemical properties.

• Proceedings of the Korean Society of Crop Science Conference
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• 2005.08a
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• pp.162-163
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• 2005