• 제목/요약/키워드: physico-chemical change

검색결과 168건 처리시간 0.024초

Iopamidol과 Ioversol 제제 조영제의 온도변화에 따른 물리화학적 분석 (Physicochemical Analysis according to Temperature Changes of Iopamidol and Ioversol Formulation Contrast Agents)

  • 한범희
    • 대한방사선기술학회지:방사선기술과학
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    • 제43권4호
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    • pp.273-280
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    • 2020
  • In this study, the P contrast agent of Iopamidol, which is a nonionic iodide contrast agent most commonly used as a vascular contrast agent in medical institutions, and the O contrast agent of Ioversol, were studied. The physicochemical changes according to the temperature change were compared and analyzed using the Bruker Avance 500MHz Nuclear Magnetic Resonance Spectrometer owned by the Korea Basic Science Institute (KBSI). There was no physical or chemical change in the O contrast medium of Ioversol formulation in temperature change. However, in the P contrast agent of Iopamidol, a doublet peak began to appear in the 1.1 ppm region of the sample at 60℃, and the doublet peak was clearly observed in the sample at 80℃. As a result of this study, 1H-NMR analysis revealed that the P contrast agent of the Iopamidol formulation was dissociated from chemical bonds as it rose to a high temperature of 60℃ or higher, resulting in the formation of foreign substances. It was evaluated that the O contrast agent of Ioversol formulation had physico-chemical stability than the P contrast agent of Iopamidol formulation. As shown in this study, it is necessary to analyze the physical and chemical changes of contrast agents according to various environmental factors.

동결속도에 따른 닭고기의 냉동 저장 중 이화학적 변화 (The Effect of Freezing Rates on the Physico-Chemical Changes of Chicken Meat during Frozen Storage at -2$0^{\circ}C$)

  • 김영호;양승용;이무하
    • 한국가금학회지
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    • 제14권2호
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    • pp.145-151
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    • 1987
  • 식육을 장기저장 할 때 발생되는 단백질의 변성과 해동시 육량감소를 줄이기 위한 방법의 하나로써 최적동결방법을 모색하고자 동결속도에 따른 저장중 닭고기의 물리화학적 변화를 조사한 결과 동결속도가 빠를수록 pH증가가 지연되어 장기보존의 가능성을 보였다. TBA가 및 유리지방산 생성율은 저장기간이 길어짐에 따라 증가하는 추세를 보이고 있으나 부위육의 종류에 따라 동결속도의 영향이 다르게 나타나고 있다. 그러나 단백질추출성을 비교할 때 염용성단백질과 수용성단백질의 추출성은 부위육의 종류에 관계없이 3cm/hr이상의 동결속도에서 저장기간 중 추출성이 가장 높게 나타났으며, 이러한 경향은 다리살 보다 가슴살의 추출성이 더욱 높게 유지되고 있다. 이상의 결과에서 송풍동결기를 이용하여 닭고기를 동결시킬 경우 3cm/hr이상의 동결속도로 동결시켜 냉동저장 할 때 좋은 품질의 냉동육을 얻을 수 있는 것으로 판단되었다.

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자주복(Takifugu rubripes) 정액의 물리$\cdot$화학적 성상과 냉동보존 전후 정자의 미세구조 (Physico-chemical Properties of Milt and Fine Structure of Cryopreserved Spermatozoa in Tiger Puffer (Takifugu rubripes))

  • 장윤정;장영진;임한규
    • 한국수산과학회지
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    • 제31권3호
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    • pp.353-358
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    • 1998
  • Experiments were performed to find out the physico-chemical properties of milt, and morphological changes of cryopreserved spermatozoa in tiger puffer, Takifugu rubripes. The average number of sperm and spermatocrit in milt stripped were $9.81{\pm}0.34{\times}10^{10}/m{\ell}$ and $97.8{\pm}0.8$, respectively. While total lipid concentration from seminal fluid was higher than that from sperm, total protein concentration from sperm was higher than that from seminal fluid, Na and K concentrations in sperm and those in seminal fluid were similar each other, However, glucose from sperm and seminal fluid were not detectable. Spermatozoon of tiger puffer was consisted of head, middle Piece and tail. Size of head showing horseshoe shape was $0.65{\pm}0.10{\mu}m$ in diameter and $1.35{\pm}0.30{\mu}m$ in length. The head fully containing chromatin did not have acrosome. Mitochondrion in middle piece was $0.2{\mu}m$ in average diameter and flagellum showed 9+2 structure. A few of cryopreserved spermatozoa showed morphologically loose or swollen plasma membranes.

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Occurrence, Seasonal Changes and Vertical Distribution of Silica-scaled Chrysophytes in a Small Fish-free Pond in Japan

  • Kim, Han-Soon;Noriko Takamura
    • Animal cells and systems
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    • 제5권2호
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    • pp.117-126
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    • 2001
  • Occurence, seasonal changes and vertical distribution of the silica-scaled chrysophytes in a small fish-free pond were studied using electron microscopy (EM) and light microscopy (LM) from October 1998 to July 1999. The phytoplankton community was characterized by Chrysophyta and Cryptophyta. Ten species of the silica-scaled chrysophytes of genera Mallomonas, Synura, Chrysosphaerella and Spiniferomonas were identified by EM, and the most abundant species were Mallomonas akrokomos and M. portae-ferreae. The maximum population density of M. akrokomos was observed in December and several peaks appeared periodically at about one to two month intervals, whereas M. portae-ferreae developed the maximum density in March. The diurnal vertical distribution of M. akrokomos exhibited clear downward migration at night and slightly upward migration in the morning. A complex interaction among physico-chemical and biological factors seemed to affect the vertical distribution of M. akrokomos. However, the seasonal changes of M. akrokomos did not show significant corre1ations with the physico-chemical and some biologica1 factors. Although M. akrokomos was evenly distributed throughout the water column during some experimental periods, the diurnal patterns found in the two diurnal cycles showed consistency in that it clearly avoided the surface water during the day. This suggested that M. akrokomos may be a shade plankton with maximum densities below surface layer.

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하수처리수의 농업용수 재이용시 시비량 변화에 따른 환경영향 분석 (Environmental Effects Analysis by the Fertilizer Change with Wastewater Reuse in Paddy Fields)

  • 장태일;박승우;조재영
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2005년도 학술발표논문집
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    • pp.643-648
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    • 2005
  • The objective of this paper is to analyze the environmental effects by the fertilizer change with wastewater reuse for agriculture. For this research, Lysimeter tests are being implemented to cultivate rice with different levels of fertilizer applications with wastewater irrigation., and to analyze the nutrient loading by wastwater reuse in paddy fields was examined the CREAMS-PADDY model. CREAMS-PADDY model is modified from CREAMS model for considering the hydrologic cycles in paddy field. As a result, in the lysimeter treated by irrigation with wastewater and chemical fertilizer with half of the conventional amount showed generally similar tendency to the control plot. This may require the modifications of standard cultural practices for rice in terms of fertilizer and pesticide applications. However, high concentration of sodium in wastewater might cause damage to physico-chemical properties of paddy soil. And the wastewater reuse effects on nutrient loads were quantitatively analyzed and this results provide the reasonable management for agricultural reuse.

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포장방법이 냉장 쇠고기의 이화학적 성질 변화에 미치는 영향 (Effects of Packaging Method on Physico-chemical Properties of Korean Beef)

  • 김대곤;이신호;김수민;석영수;성삼경
    • 한국식품영양과학회지
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    • 제25권6호
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    • pp.944-950
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    • 1996
  • 본 연구는 외국산 냉장쇠고기의 국내 수입에 따른 한우쇠고기의 경쟁력 제고와 저장성 증진을 위하여 한우 암소 1등급의 등심을 재료로 포장방법에 따른 냉장저장 중 이화학적 성질 변화를 조사하였다. 시료는 진공포장(포장재: polyamide/polyethylene, $50ml/\m^2.24h.$ atm)과 일반포장(포장재: polyvinylchloride, $80~320ml/\m^2.24h.atm)을$ 하였으며, 포장된 각군은 다시 형광등 조사군과 암실 보존군으로 나누었다. pH 변화는 저장 21일 동안 진공포장군의 경우 형광등 조사 여부에 관계없이 점차 감소하는 경향이었으나, 일반포장군은 점차 상승하는 경향을 보였다. VBN값은 진공포장군과 일반포장군 모두 저장기간에 따라 증가하는 경향을 나타내었으며, 진공포장군이 일반포장군에 비하여 저장 15일째 이후부터 유의하게 낮았다. TBA 값은 저장 초기에 비하여 저장 전기간 동안 진공포장군이 일반포장군에 비하여 낮게 유지되었다. 적색도에서는 진공포장군과 일반포장군 모두 저장기간에 따라 점차 감소하는 경향이었으며, 진공포장군은 일반포장군에 비하여 전저장기간 동안 높은 값을 나타내었다. 지방산 조성변화를 보면, 저장기간에 따라 포화지방산의 함량은 점차 증가하는 반면, 불포화지방산의 함량은 감소하였는데, 그 변화정도는 진공포장군이 일반포장군에 비하여 크게 낮았다. 본 연구에서 형광등 조사군과 암실 보존군간에는 이화학적 성질의 차이가 뚜렷하지 않았다.

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한약의 수치에 관한 연구(제 7보) -치자의 수치에 의한 성분변화 및 생리활성- (Studies on the Processing of Crude Drugs(VII) -On the Constituents and Biological Activities of Gardeniae Fructus by Processing-)

  • 신용욱;김동현;김남재
    • 생약학회지
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    • 제34권1호통권132호
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    • pp.45-54
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    • 2003
  • We have conducted to characterize the physico-chemical change and pharmacological transformation of traditional herbal medicines by means of processing. Processed Gardeniae Fructus was prepared by heating of fruit of Gardenia jasminoides(GF) for $30{\sim}50\;minute$ in the roster designed for herb processing. The contents of drying loss, water extract, diluted ethanol extract, ether extract and geniposide in non-processed GF and processed GF were examined. The contents of drying loss, water extract and geniposide in processed GF showed a decrease as compared with those of non-processed GF, however the contents of dilute ethanol and ether extract showed a increase as compared with those of non-processed GF. The rate of decrease/increase of those index were in proportion to heating time. And, biological activities of methanol extract of non-processed GF and processed GF were investigated. DPPH scavenging effects and inhibitory effect of xanthine oxidate and hemolysis of processed GF exhibited more effective than those of non-processed GF in vitro. Accelerating effect of large intestinal transport and purgative action of non- processed GF were discriminated by processing of GF. Methanol extracts of non-pro- cessed GF and processed GF showed the protective effects against the hepatotoxicity induced by ${\alpha}-naphthylisothiocyanate$ in rats. These results suggested that the transformation of biological activities of GF by means of processing may be due to the physico-chemical change of the constituents in GF by heating.

키위 농축액을 첨가한 키위 죽의 품질 특성에 관한 연구 (A Study on Quality Characteristics of Kiwi Fruit-Gruel with Added Kiwi Concentrate)

  • 김종욱;성기협
    • 동아시아식생활학회지
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    • 제20권2호
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    • pp.313-320
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    • 2010
  • In this study, kiwi fruit, which has various medical actions and excellent functionality, was used together with gruels for comparison and analysis of to compare and analyze the changes in physico-chemical quality of a kiwi fruit-gruel according to the amount of kiwi concentrate added to the gruel. Analysis on the sensual quality of kiwi fruit-gruel spread was done to indicate to it was executed to find out the merchandising potential of the preparation and to provide basic data for gruel commercialization. Increasing content of kiwi concentrate decreased the solid content and pH of kiwi fruit, and increased sweetness and viscosity. Significant changes in chromaticity to L(lightness) and a(redness), texture qualities of hardness and cohesiveness, gumminess, springiness, color, flavor, sourness, and sweetness were evident with increasing kiwi concentrate. Concerning overall acceptability and sensory evaluation, 20% softness samples were most preferred. The findings may lead to enhanced medical/nutritional activity and functionality of kiwi fruit-supplemented gruel. The more the kiwi concentrate was added to the gruel, solid content and pH of the kiwi fruit-grue decreased. The sweetness and viscosity of kiwi fruit-gruel increased. For chromaticity to L(lightness) and a(redness) of the gruel decreased and showed significant difference between sample groups. For texture, there were significant changes shown for hardness and cohesiveness the amount of kiwi concentrate added was different, increased There was a significant change between samples for gumminess. As for springiness, there was a significant change between samples. There were significant difference between each sample for color, flavor, sourness, sweetness. For softness, overall-acceptability and sensory evalution 20% group was most preferred based on this study, from the physico-chemical and sensual perspective, 20% group is highly recommended for adding kiwi concentrate into gruel. In conclusion, this study is meaningful as it enhanced the functionality and quality of a gruel by combining kiwi fruit with various medical action and excellent functionality, with Kiwi Fruit and presented a basic material for creating a kiwi concentrate combined gruels.

메추리알 초란의 이화학적 특성과 기호성 평가 (Studies on the Physico-chemical Properties and Sensory Evaluation of Pickled Quail Egg)

  • 양철영
    • 한국축산식품학회지
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    • 제25권4호
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    • pp.472-477
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    • 2005
  • 메추리알과 감식초를 이용하여 15일간 담금 유지하면서, 물리, 화학적 변화와 완성 초란 시료에 부재료를 혼합하여 음료적 가치 평가를 위한 관능평가를 실시한 결과를 보면 다음과 같다. 메추리알의 중량 변화는 담금 5일에서 큰 증가율을 보이고, 15일 담금은 10일에 비해 약간의 감소현상을 나타내며, $20^{\circ}C$ 담금구가 $10^{\circ}C$ 담금구에 비해 약간의 중량 증가율이 높음을 볼 수 있었다. 영양 조성분은 수분, 조단백질, 조지방 및 조회분은 각각 75.24, 12.13. 9.53, $1.20\%$로 측정되었고, 담금기간 중 조회분의 증가율이 높게 나타내고 있었다. 감식초액의 pH는 3.12, 3.24이었고 5일 담금구의 담금액의 증가가 큰 폭으로 보이나 초란 고형분인 난백과 난황은 낮아지는 경향을 보이는 것은 $10^{\circ}$$20^{\circ}$ 담금구에서 유사하게 나타내었으며 $10^{\circ}$ 담금이 $20^{\circ}$ 담금보다 약간의 높은 pH값을 보였다 난백중 수용성 질소물의 함량 변화는 $10^{\circ}$ 담금 5일에 감소량이 높고 10일, 15일 담금에서는 증가율이 적었다. 비단백태 질소물은 수용성 질소물에 비해 함량이 적게 측정되었으며 담금기간에 따라서 그 함량이 증가함을 보였다. 점도의 변화는 담금기간이 길어질수록 그 값이 증가함을 보이고 있는데 특히 5일 담금구에서 증가율이 높게 나타내고 있었다. 15일 담금된 초란의 관능평가는 전체 수용도로 보면 S-3>S-2>S-1의 순으로 높은 평가를 보이며 평가 요소 중 냄새 항목이 낮은 편이었다.