• Title/Summary/Keyword: photovoltaic device

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유기태양전지의 장시간 안정성 향상을 위한 PEDOT:PSS층의 연구

  • 양혜진;장소라;최철호;최주환;신진국
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.469.1-469.1
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    • 2014
  • 일반적으로 유기전자소자의 제작에 있어서 Indium tin oxide (ITO)는 뛰어난 전기 광학적 특성을 바탕으로 가장 보편적으로 사용되는 투명전극이다. 특히 유기태양전지(Organic Photovoltaic, OPV)나 유기발광디스플레이(Organic Light Emitting Device)는 ITO 위에 PEDOT:PSS 층을 형성하여 HOMO, LUMO를 조절하고 효율을 향상시키는 역할을 수행하고 있다. 특히 ITO 위의 PEDOT:PSS는 사용되는 용제의 종류나 첨가제 등에 따라 특성이 크게 영향을 받는다. 이때 PEDOT:PSS는 일반적으로 강산성을 띄게 됨으로써 유기전자소자의 장시간 안정성을 저하시키는 원인으로 작용한다. 본 연구에서는 각각 다른 pH level을 가진 PEDOT:PSS의 시간 경과에 따라 투과도와 면저항을 측정하고 각각의 PEDOT을 사용하여 유기태양전지 소자를 제작하였다. 소자제작 30일 경과 후 소자의 효율이 감소하기는 하였으나 그 변화가 일반적으로 사용되는 pH 2의 감소보다 현저히 적었음을 알 수 있다. 이러한 pH 변화가 이를 적용한 투명전극 필름의 전기 광학적 특성인 투과도 면저항 등에는 영항을 거의 미치지 않으면서도 OPV의 효율 변화에는 큰 차이를 보이는 것을 알 수 있다.

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Electrical Characterization of Cu(InxGa1-x)(SySe2-y) Thin Film Solar Cells

  • Kim, Dahye;Kim, Ji Eun;Cho, Yunae;Kim, Dong-Wook
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.464.1-464.1
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    • 2014
  • Among numerous material candidates, Cu(InxGa1-x)(SySe2-y) (CIGS) thin films have emerged as promising material candidates for thin film solar cell applications due to the high energy conversion efficiency and relatively low fabrication cost. The CIGS thin film solar cells consist of several materials, including Mo back contacts, ZnO-based window layers, and CdS buffer layers. All these materials have different crystal structures and contain quite distinct chemical elements, and hence the device characterization requires careful analyses. Most of all, identification of the major trap states resulting in the carrier recombination processes is a key step toward realization of high efficiency CIGS solar cells. We have carried out electrical investigations of CIGS thin film solar cells to specify the major trap states and their roles in photovoltaic performance. In particular, we have used the temperature-dependent transport characterizations and admittance spectroscopy. In this presentation, we will introduce some exemplary studies of DC and AC electrical characteristics of the CIGS solar cells.

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3,6-Carbazole Incorporated into Polymer Effects on Solar Cells

  • Lee, Gang-Young;Cha, Hyojung;Park, Chan Eon;Park, Taiho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.481.2-481.2
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    • 2014
  • Bulk hetero junction (BHJ) polymer solar cell (PSCs) is one of the most promising fields as alternative energy source. Especially, the development of new p-type conjugated polymer is one of the main issues to get core technology. In this study, we investigated the chemical doping effects of incorporating 3,6-carbazole units into conjugated polymers based on 2,7-carbazole. We assessed the structural effects of this chemical doping by measuring the photovoltaic device performance of the copolymers with and without annealing. Note that the use of nanostructures in the bulk heterojunction layer could be a major obstacle to commercialization because nano-morphologies are frequently unstable at high temperatures. Therefore, the development of thermally stable polymer:fullerene blends with optimized PCEs is an important goal in this area of research. We studied the morphologies of the copolymers incorporating 3,6-carbazole units resulting from thermal annealing to investigate the effects of the difference between the T g values of the 2,7-carbazole unit and the 3,6-carbazole unit.

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Temperature and the Interfacial Buffer Layer Effects on the Nanostructure in the Copper (II) Phthalocyanine: Fullerene Bulk Heterojunction

  • Kim, Hyo Jung;Kim, Jang-Joo;Jeon, Taeyeol;Kong, Ki Won;Lee, Hyun Hwi
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.275.1-275.1
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    • 2014
  • The effects of the interfacial buffer layer and temperature on the organic bulk heterojunction (BHJ) nanostructures of copper phthalocyanine (CuPc) and fullerene (C60) systems were investigated using real time in-situ x-ray scattering. In the CuPc:C60 BHJ structures, standing-on configured ${\gamma}$-CuPc phase was formed by co-deposition of CuPc and C60. Once formed ${\gamma}$-phase was thermally stable during the annealing upon $180^{\circ}C$. Meanwhile, the insertion of CuI buffer layer prior to deposition of the CuPc:C60 BHJ layer induced lying-down configured CuPc crystals in the BHJ layer. The lying CuPc peak intensity and the lattice parameter were increased by the thermal annealing. This increment of the intensity seemed to be related to the strain at the interface between CuPc:C60 and CuI, which was proportional to the enhancement of the power conversion efficiency of the device.

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광센서를 이용한 태양위치 추적장치 개발 (Development of Solar Tracking using a Photovoltaic Sensor)

  • 장현진;진태석
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2012년도 추계학술대회
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    • pp.1023-1025
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    • 2012
  • 본 연구에서는 태양광 발전의 효율을 향상시키기 위하여 발전시스템의 태양추적에 기초가 되는 태양 추적 장치를 설계하였다. 태양광발전분야에서는 셀의 발전특성 향상을 위한 연구와 함께 태양에너지의 효과적인 집광을 위한 연구가 다양하게 진행되고 있다. 일사량은 지역에 따라 차이가 발생하는 요소로 발전효율을 증대시키기 위해서는 발전 장치의 설치장소가 달라져야 한다는 제약이 있는 반면, 발전 셀 단면이 태양과 이루는 각도는 발전장치의 기구부를 회전시킴으로서 태양과 이루는 각도를 가변 할 수 있는 장치를 개발하고 실험을 통하여 발전 효율 향상 성능을 확인하였다.

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배터리 에너지 저장장치용 고효율 2kW급 양방향 DC-DC 컨버터 설계 (Design of a 2kW Bidirectional Synchronous DC-DC Converter for Battery Energy Storage System)

  • 이태영;조병극;조영훈;홍찬욱;이한솔;조관열
    • 전력전자학회논문지
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    • 제22권4호
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    • pp.312-323
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    • 2017
  • This paper introduces the bidirectional dc-dc converter design case study, which employs silicon-carbide (SiC) MOSFETs for battery energy storage system (BESS). This converter topology is selected as bidirectional synchronous buck converter, which is composed of a half bridge converter, an inductor, and a capacitor, where the converter has less conduction loss than that of a unidirectional buck and boost converter, and to improve the converter efficiency, both the power stage design and power conversion architecture are described in detail. The conduction and switching losses are compared among three different SiC devices in this paper. In addition, the thermal analysis using Maxwell software of each switching device supports the loss analyses, in which both the 2 kW prototype analyses and experimental results show very good agreement.

불연속 에너지 발생장치의 에너지 보상 시스템에 대한 연구 (A Study on the Discontinuous Energy Ceneration System for Power Compensation)

  • 이정일;임중열;강병복;차인수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.133-138
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    • 2002
  • The developments of the solar and the wind power energy are necessary since the future alternative energies that have no pollution and no limitation are restricted. Currently power generation system of MW scale has been developed, but it still has a few faults with the weather condition. In order to solve these existing problems, combined generation system of photovoltaic(400W) and wind power generation system(400W) was suggested. It combines wind power and solar energy to have the supporting effect from each other. However, since even combined generation system cannot always generate stable output with ever-changing weather condition, power compensation device that uses elastic energy of spiral spring to combined generation system was also added for the present study. In an experiment, when output of system gets lower than 12V(charging voltage), power was continuously supplied to load through the inverter by charging energy obtained from generating rotary energy of spiral spring operates in small scale generator.

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Wet-Chemically Prepared NiO Layers as Hole Transport Layer in the Inverted Organic Solar Cell

  • Lim, Dong-Chan;Kim, Young-Tae;Shim, Won-Hyun;Jang, A-Young;Lim, Jae-Hong;Kim, Yang-Do;Jeong, Yong-Soo;Kim, Young-Dok;Lee, Kyu-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제32권3호
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    • pp.1067-1070
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    • 2011
  • We have demonstrated that solution-based fabrication of NiO films as HTL can be used for the construction of IOSCs. Type of solvent of NiO-solution, and annealing procedure of the active layers were optimized for obtaining a PCE of 3% of IOSC. The photovoltaic performance of NiO-based device is comparable to that of the same type of solar cell using PEDT:PSS instead of NiO. These solution-based processes can be a promising method for a mass production OSCs under ambient condition.

포토센서를 이용한 태양위치 추적기의 성능분석에 관한 연구 (Performance Evaluation of a Solar Tracking PV System with Photo Sensors)

  • 정병호;조금배;이강연
    • 조명전기설비학회논문지
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    • 제27권5호
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    • pp.67-73
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    • 2013
  • The conversion of solar radiation into electrical energy by Photo-Voltaic (PV) effect is a very promising technology, being clean, silent and reliable, with very small maintenance costs and small ecological impact. The output power produced by the PV panels depends strongly on the incident light radiation. The continuous modification of the sun-earth relative position determines a continuously changing of incident radiation on a fixed PV panel. The point of maximum received energy is reached when the direction of solar radiation is perpendicular on the panel surface. Thus an increase of the output energy of a given PV panel can be obtained by mounting the panel on a solar tracking device that follows the sun trajectory. Tracking systems that have two axes and follow the sun closely at all times during the day are currently the most popular. This paper presents research conducted into the performance of Solar tracking system with photosensors. The results show that an optimized dual-axis tracking system with photosensor performance and analysis. From the obtained results, it is seen that the sun tracking system improves the energy and energy efficiency of the PV panel.ti-junction CPV module promises to accelerate growth in photovoltaic power generation.

염료감응형 태양전지의 광전변환효율 향상을 위한 무반사 박막 (Anti-Reflection Thin Film For Photoelectric Conversion Efficiency Enhanced of Dye-Sensitized Solar Cells)

  • 정행윤;기현철;홍경진
    • 한국전기전자재료학회논문지
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    • 제29권12호
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    • pp.814-818
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    • 2016
  • DSSCs (dye-sensitized solar cells) based on $TiO_2/SiO_2$ multi layer AR (anti-reflection) coating on the outer glass FTO (fluorine-doped tin oxide) substrate are investigated. We have coated an AR layer on the surface of a DSSCs device by using an IAD (ion beam-assisted deposition) system and investigated the effects of the AR layer by measuring photovoltaic performance. Compared to the pure FTO substrate, the multi layer AR coating increased the total transmittance from 67.4 to 72.9% at 530 nm of wavelength. The main enhancement of solar conversion efficiency is attributed to the reduction of light reflection at the FTO substrate surface. This leads to the increase of Jsc and the efficiency improvement of DSSCs.