• Bulletin of the Korean Chemical Society
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• 제28권3호
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• pp.447-450
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• 2007

Trap effects on the formation of space-charge field (SCF) associated with the photorefractivity of nonlinear optical polymers were studied by the Monte Carlo simulation using modified Gaussian disorder model. The charge transport dynamics influenced by the presence of trap molecules controls the formation of SCF via the charge distribution. Temporal behavior of SCF formation and SCF dependence on the trap depth are discussed in terms of the concentration and distribution of charges (holes and ionized acceptors) developed following illumination of light. The correlation of the trap depth and the energetic disorder is presented for an optimal efficiency for the SCF formation.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1997년도 추계총회 및 학술발표회 논문집
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• pp.27-31
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• 1997

• Journal of Photoscience
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• 제10권3호
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• pp.251-255
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• 2003

The composites fabricated by blending nonlinear optical (NLO) chromophore such as {4-[2-(4-nitrophenyl)-vinyl] phenyl}diphenylamine (NVPDA) with photoconducting crosslinkable matrix, bis-(4-ethynylphenyl)-(4-octyloxy-phenyl)amine (BEOPEA), showed photorefractive property. Many problems faced in typical organic photorefractive systems such as time-consuming chemical synthesis, difficulty in rational design, intrinsic instability and phase separation could be avoided by this fabrication method.

• Journal of Photoscience
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• 제11권3호
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• pp.101-106
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• 2004

The photorefractive composites fabricated by blending NLO chromophores such as 3-(4-{bis-[4-(2-ethylhexyloxy)-phenyl]-amino}-phenyl)-2-isocyano-acrylonitrile (PAIA), bis-[4-(2-ethyl-hexyloxy)-phenyl]-{4-[2-(4-nitrophenyl)-vinyl]-phenyl}-amine (PNPA) with photoconducting crosslinkable matrix, bis-(4-ethynylphenyl)-(4-octyloxyphenyl)-amine (BEOPEA), showed photorefractive property due to the high composition of NLO chromophores caused by introducing alkoxy chain, and many problems faced in typical organic photorefractive systems such as timeconsuming chemical synthesis, difficulty in rational design, intrinsic instability and phase separation could be avoided.

• Macromolecular Research
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• 제11권4호
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• pp.250-255
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• 2003

We prepared the photorefractive sol-gel glass based on organic-inorganic hybrid materials containing a charge transporting molecule, second-order nonlinear optical (NLO) chromophore, photosensitizer, and plasticizer. Carbazole and 2-{ 4-[(2-hydroxy-ethyl)-methyl-amino]-benzylidene}-malononitrile were reacted with isocyanato-triethoxy silane and the functionalized silanes were employed to fabricate the efficient photorefractive media induding 2,4,7-trinitrot1uorenone (TNF) to form a charge transfer complex. The prepared sol-gel glass samples showed a large net gain coefficient and high diffraction efficiency at a certain composition. As the concentration of photosensitizer increased, the photorefractive properties were enhanced due to an increment of charge carrier density. Dynamic behavior of the diffraction efficiency was also investigated with the concentration of the photosensitizer.