• Korean Chemical Engineering Research
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• 제46권2호
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• pp.310-315
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• 2008

실란커플링제인 glycidoxypropyl trimethoxysilane(GPTMS)과 vinyltriethoxysilane(VTES)을 출발물질로 하여 sol-gel 법에 의해 유-무기 혼성 용액을 제조하였다. 이 용액에 spiropyran계 광 변색 염료를 ethylacetate에 용해시킨 용액을 혼합하여 광 변색 코팅 용액을 제조하였다. 그 후 기재인 polycarbonate 시트에 스핀 코팅 시키고 $100^{\circ}C$에서 2 h 동안 열 경화시켜 광 변색성을 갖는 하드 코팅 막을 제조하였다. 코팅 막은 UV 광을 조사함에 의해 투명색으로부터 푸른색으로 변했다가 다시 투명색으로 변하는 가역적인 색변화를 보여주었다. 이때 코팅 막의 소색속도 및 연필경도는 코팅 용액 중의 GPTMS의 mol비가 증가됨에 따라 증가하였다.

• 대한기계학회논문집B
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• 제21권5호
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• pp.628-636
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• 1997

Flow visualization technique incorporating photochromic dye is used to study the flow characteristics of the gravity driven laminar wavy film. The film thickness and wave speed are successfully measured by flow visualization. As the inclination angle increases, the waves have higher peaks and lower substrate thickness. The measured cross stream velocity at the free surface is up to 10% of stream wise velocity, which shows enhanced mixing in the lump of the film. The measured stream wise velocity profiles are close to parabolic profile near the substrate and the peak but show significant velocity defect near the rear side of the wave. The measured wall shear rate distributions show good agreement with the previous workers' numerical results.

• 한국인쇄학회지
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• 제10권1호
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• pp.1-13
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• 1992

The recent results concerning the synthesis and application of spiroxazine dyes have been summerized., The absorption bands of usual spiroxazine dyes are changed from colorless to colored from by irradiation of ultraviolet ray. This mechanism is derived from the cleavage of oxazine ring. Such properties are dependent on its chemical structure and surrounded matrix of spiroxazine dyes. the chemical structure of this dye is similar to the well known spriopyran. But spiroxazine dyes have noticed recently, because of excellent high light-sensitivity and superior fatigue-resistant property. This dye are already applied as photochromic lens, cloths and UV light checker.

• 한국염색가공학회지
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• 제3권3호
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• pp.1-5
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• 1991

Cationic azo dyes were synthesized by coupling aniline and its derivatives with 2,4-dimethyl imidazole as a coupler, and their photochromic behavior was investigated. The dyes exhibited little photochromism on wool, but to a considerable degree on Dacron T92(anionic modified polyester), the photochromism being prominent for the dye with electron-releasing substituent on diazo component. Little photochromism on wool can be attributed to a decreased mobility of dye by the various interactions between the dye and wool molecules, which interferes the cis-trans isomeriation of dye. On Dacron T92 there can not be any obstacle for the cis-trans isomerization of dye, hence reversible color change may occur. The electron-releasing substituent on diazo component may be helpful for the photochromism of dye by increasing the n-electron density of phenyl ring, which can stabilize the cis-form of the dye by the interaction with the positive charge of imidazole ring.

• Korean Chemical Engineering Research
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• 제49권5호
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• pp.535-540
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• 2011

금속염인 lanthanum nitrate를 증류수에 용해시킨 후 실란커플링제인 ${\gamma}$-glycidyloxypropyl trimethoxysilane과 금속산화물인 colloidal silica를 이 용액에 첨가하여 sol-gel법에 의해 유-무기 혼성 용액을 제조하였다. 또한 spiropyran계 광변색 염료를 용매인 tetrahydrofuran에 용해시킨 후 앞서 제조한 혼성 용액과 혼합하여 광 변색 코팅 용액을 제조하였다. 그 후 기재인 polycarbonate 시트에 코팅시키고 열 경화시켜 광 변색성을 갖는 하드 코팅 막을 제조하였다. 이 과정 중 colloidal silica의 첨가량이 코팅 막의 광변색 특성에 미치는 영향을 조사하였다. Colloidal silica의 첨가량이 증가할수록 코팅 막의 소색속도가 빨라졌으며 연필경도가 증가하였다.

• 한국인쇄학회지
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• 제12권1호
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• pp.133-143
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• 1994

A new photochromic spiroxazine dye having a pyridinium s-triazine moiety has been prepared. It shows a reversible photochemical color change from colorless to reddish-purple in ethanol solution. In ethanol solution the half life time of the open form was 150sec, which was shortened by raising temperature. Silica-immobilized spiroxazine(6). Fine power of silica-immobilized spiroxazine was changed intensely blue from colorless by U.V. light or sunlight.

• 한국인쇄학회지
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• 제12권1호
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• pp.159-168
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• 1994

The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2007년도 추계학술발표회
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• pp.101-102
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• 2007

• 대한전자공학회논문지SD
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• 제41권6호
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• pp.53-58
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• 2004

광기능성 색소가 분산된 평면도파로 결합기와 측면연마된 광섬유를 이용한 자외선 센서를 제작하여 광강도 변화에 따른 감도특성을 측정하였다. 광변색성 색소인 스파이록사진이 분간된 폴리머를 평면도파로로 사용하였다. 조사되는 자외선의 강도와 시간에 의해 유효굴절률이 변화하는 성질을 이용하였다. 자외선 조사시간을 3 초와 5 초로 고정한 상태에서 자외선 조사강도를 점차 증가시켰을 때 센서감도가 자각 $1.21{\mu}W/mw$와 $2.75{\mu}W/mw$로 나타났다. 자외선 조사 강도에 따른 출력 광강도의 변화를 측정한 결과 자외선 강도가 클수록 출력 광강도도 증가하고 포화시간은 단축됨을 알 수 있었다.

• 대한기계학회논문집B
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• 제26권11호
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• pp.1570-1577
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• 2002

In order to investigate the characteristics of two-phase slug flow, an electromagnetic flowmeter with 240Hz triangular AC excitation was designed and manufactured. The signals and noise from the flowmeter were obtained, and analyzed in comparison with the observations with a high speed CCD camera. The uncertainty of the flowmeter under single-phase flow was $\pm$ 2.24% in real-time. For two-phase slug flow, electromagnetic flowmeter provided real-time simultaneous measurements of the mean film velocity around Taylor bubble and the relative location and the length of the bubble. Besides, it is an easier and cheaper method for measuring mean film velocity than others such as photochromic dye activation method or particle image velocimetry.