• Title/Summary/Keyword: photochemical reduction

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A Numerical Simulation of High Ozone Episode Using OZIPR in Busan (OZIPR을 이용한 부산지역 고농도 오존 사례 모사)

  • Do, Woo-Gon;Lee, Hwa-Woon;Jung, Woo-Sik
    • Journal of Environmental Science International
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    • v.16 no.8
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    • pp.985-994
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    • 2007
  • To investigate the effect of NOx and VOCs(volatile organic compounds) on the generation of high ozone episode, examined the hourly variations of ozone, NOx and VOCs concentrations, and calculated the ozone isopleth about maximum ozone concentrations using OZIPR which was presented by U. S. EPA at three sites in Busan. There was some difference by the sites, but decreasing VOCs concentration was effective for reduction of ozone at 22 July, the episode day of 2005. In the year 2006, the episode day was 8 August and the variations of NOx and VOCs concentration was little than variation of ozone. So it was estimated that the photochemical production of ozone was low than transportation of ozone. And the result of the OZIPR modeling was that decreasing VOCs concentration was effective for reduction of ozone.

On Relationship of Low Visibility to Air Pollution in Cities (도시의 대기오염과 시정감소에 관하여)

  • 정용승;김태군;정재섭
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.1
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    • pp.1-6
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    • 1992
  • Using data measured in 1989, a study on variations of visibility and air pollution observed in Seoul, Chongju and Choopoongryong is carried out. Analysis includes on low visibility (< 10km) and smog occurring in the Metropolitan Seoul. It was observed that number of days of visibility less than 10km during 1989 was 56.7% (207 days) for Seoul, 45.7%(167 days) for Chongju and 5.8% (21 days) for Choopoongryong. Chongju is a medium size city (population : a half million) and Choopoongryong is a rural site. In the urban are as, however, the number of low visibility days was relatively large during the winter but with little seasonal variations. In each month these cities recorded more than 10 days of low visibility. The visibility reduction due to mist, fog and haze been occurred with air pollution. In particular, the reduction in a cold season related with an increase in high concentrations of $SO_x$ and aerosols. This type of low visibility occurring in Seoul is a similar type that is occurring in London, U.K. On the other hand, the visibility reduction during in a warm season is related with high concentrations of NOx and other photochemical precursors. The visibility reduction in Seoul during summer is the same type occurring in Los Angeles, U.S.A.

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Evaluating Applicability of Photochemical Reflectance Index using Airborne-Based Hyperspectral Image: With Shadow Effect and Spectral Bands Characteristics (항공 초분광 영상을 이용한 광화학반사지수 이용 가능성 평가: 그림자 영향 및 대체 밴드를 중심으로)

  • Ryu, Jae-Hyun;Shin, Jung Il;Lee, Chang Suk;Hong, Sungwook;Lee, Yang-Won;Cho, Jaeil
    • Korean Journal of Remote Sensing
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    • v.33 no.5_1
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    • pp.507-519
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    • 2017
  • The applications of NDVI (Normalized Difference Vegetation Index) as a vegetation index has been widely used to understand vegetation biomass and physiological activities. However, NDVI is not suitable way for monitoring vegetation stress because it is less sensitive to change in physiological state than biomass. PRI (Photochemical Reflectance Index) is well developed to present physiological activities of vegetation, particularly high-light-stress condition, and it has been adopted in several satellites to be launched in the future. Thus, the understanding of PRI performance and the development of analysis method will be necessary. This study aims to interpret the characteristics of light-stress-sensitive PRI in shadow areas and to evaluate the PRI calculated by other wavelengths (i.e., 488.9 nm, 553.6 nm, 646.9 nm, and 668.4 nm) instead of 570 nm that used in original PRI. Using airborne-based hyperspectral image, we found that PRI values were increased in shadow detection due to the reduction of high light induced physiological stress. However, the qualities of both PRI and NDVI data were dramatically decreased when the shadow index (SI) exceeded the threshold (SI<25). In addition, the PRI calculated using by 553.6 nm had best correlation with original PRI. This relationship was improved by multiple regression analysis including reflectances of RED and NIR. These results will be helpful to the understanding of physiological meaning on the application of PRI.

LIGHT-DEPENDENT CHANGES OF CHLOROPHYLL FLUORESCENCE AND XANTHOPHYLL CYCLE PIGMENTS IN MAIZE LEAVES DURING DESICCATION

  • Xu, Chang-Cheng;Lee, Choon-Hwan;Zou, Qi
    • Journal of Photoscience
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    • v.5 no.1
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    • pp.17-22
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    • 1998
  • Changes of chlorophyll fluorescence and xanthophyll cycle pigment contents in maize leaves were investigated dunng desiccation in darkness or in the light. In darkness, a drastic dehydration of detached maize leaves down to 50% relative water content (RWC) affected photochemical efficiency of photosystem II (Fv/Fm) and pht)tochemical quenching (qP) only slightly. In contrast, desiccation in the light with a moderate intensity led to a pronounced reduction in Fv/Fm with a Fo quenching when RWC was greater than 70%. This reduction in Fv/Fm could be recovered in darkness under hutrod condition. In leaves with RWC below 70%, significant reduction in Fv/Fm was accompanied by an increase of Fo, which could not be reversed within 5 h in darkness under humid condition. The nonphotochemical quenching increased during desiccation in the light with a concomitant rise in zeaxanthin at the expense of violaxanthin. Pretreatment with dithiothreitol (DTT), an inhibitor of zeaxanthin synthesis, inhibited the development of nonphotochemical quenching and prevented the xanthophyll interconversion during desiccation in the light. These results suggest that even light with a moderate intensity becomes excessive under dehydration and zeaxanthin-associated photoprotection of photosynthetic apparatus against photodamage is involved, but the protection is not complete against severe desiccation.

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An Analysis of Potential Environmental Impact Reduction for Combined Sewer Overflow Project using a LCA Methodology (LCA 기법을 활용한 합류식 하수도 월류수 사업의 잠재적 환경영향 저감효과 분석)

  • Jo, Hyun-Jung;Song, Jang-Hwan;Hwang, Yong-Woo;Park, Ji-Hyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.6
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    • pp.885-892
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    • 2011
  • In this study, LCA(Life Cycle Assessment) on 'Saemangum CSO Project' was carried out to evaluate environmental impact which occurred during the construction and operation periods and the potential environmental impact reduction was analyzed by comparing production and reduction level of pollution loads. LCA was conducted out according to the procedure of ISO14040 which suggested Goal and Scope Definition, Life Cycle Inventory Analysis, Life Cycle Impact Assessment and Interpretation. In the Goal and Scope Definition, the functional unit was 1 m3 of CSO, the system boundary was construction and operation phases, and the operation period was 20 years. For the data collection and inventory analysis, input energies and materials from civil, architecture, mechanical and electric fields are collected from design sheet but the landscape architecture field is excepted. LCIA(Life Cycle Impact Assessment) was performed following the procedure of Eco-Labelling Type III under 6 categories which were resource depletion, eutrophication, global warming, ozone-layer destruction, and photochemical oxide formation. In the result of LCA, 83.4% of environmental impact occurred in the construction phase and 16.6% in the operation phase. Especially 78% of environmental impact occurred in civil works. The Global warming category showed the highest contribution level in the environmental impact categories. For the analysis on potential environmental impact reduction, the reduction and increased of environmental impact which occurred on construction and operation phases were compared. In the case of considering only the operation phase, the result of the comparison showed that 78% of environmental impact is reduced. On the other hand, when considering both the construction and operation phases, 50% of environmental impact is increase. Therefore, this study showed that eco-friendly material and construction method should be used for reduction of environmental impact during life cycle, and it is strongly necessary to develop technology and skills to reduce environmental impact such as renewable energies.

Preliminary Research to Support Air Quality Management Policies for Basic Local Governments in Gyeonggi-do (경기도 기초지자체 대기환경 관리정책 지원을 위한 선행 연구)

  • Chanil Jeon;Jingoo Kang;Minyoung Oh;Jaehyeong Choi;Jonghyun Shin;Chanwon Hwang
    • Journal of Environmental Health Sciences
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    • v.49 no.5
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    • pp.275-288
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    • 2023
  • Background: When basic local governments want to improve their air quality management policies, they need fundamental evidence, such as the effectiveness of current policies or scenario results. Objectives: The purpose of this study is to lay the groundwork for a process to calculate air pollutant reduction from basic local government air quality policies and provide numerical estimates of PM2.5 concentrations following improved policies. Methods: We calculated the amount of air pollutant reduction that can be expected in the research region based on the Gyeonggi-do Air Environment Management Implementation Plan issued in 2021 and guidelines from the Korean Ministry of Environment. The PM2.5 concentration variations were numerically simulated using the CMAQ (photochemical air quality model). Results: The research regions selected were Suwon, Ansan, Yongin, Pyeongtaek, and Hwaseong in consideration of population, air pollutant emissions, and geographical requirements. The expected reduction ratios in 2024 compared to 2018 are CO (3.0%), NOx (7.9%), VOCs (0.7%), SOx (0.1%), PM10 (2.4%), PM2.5 (6.1%), NH3 (0.05%). The reduced PM2.5 concentration ratio was highest in July and lowest in April. The expected concentration reduction of yearly mean PM2.5 in the research region is 0.12 ㎍/m3 (0.6%). Conclusions: Gyeonggi-do is now able to quickly provide air pollutant emission reduction calculations by respective policy scenario and PM2.5 simulation results, including for secondary aerosol particles. In order to provide more generalized results to basic local governments, it is necessary to conduct additional research by expanding the analysis tools and periods.

Recent Development of Carbon Dioxide Conversion Technology (이산화탄소 전환 기술의 현황)

  • Choi, Ji-Na;Chang, Tae-Sun;Kim, Beom-Sik
    • Clean Technology
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    • v.18 no.3
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    • pp.229-249
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    • 2012
  • At present, global warming and depletion of fossil fuels have been one of the big issues which should be solved for sustainable development in the future. CCS (carbon capture and sequestration) technology as the post $CO_2$ reduction technology has been considered as a promising solution for global warming due to increased carbon emission. However, the environmental and ecological effects of CCS have drawn concerns. There are needs for noble post reduction technology. More recently, CCU (carbon capture and utilization) Technology, which emphasizes transforming carbon dioxide into value-added chemicals rather than storing it, has been attracted attentions in terms of preventing global warming and recycling the renewable carbon source. In this paper, various technologies developed for carbon dioxide conversion both in gas and liquid phase have been reviewed. For the thermochemical catalysis in gas phase, the development of the catalytic system which can be performed at mild condition and the separation and purification technology with low energy supply is required. For the photochemical conversion in liquid phase, efficient photosensitizers and photocatalysts should be developed, and the photoelectrochemical systems which can utilize solar and electric energy simultaneously are also in development for more efficient carbon dioxide conversion. The energy needed in CCU must be renewable or unutilized one. CCU will be a key connection technology between renewable energy and bio industry development.

Photosynthetic Responses of Populus alba×glandulosa to Elevated CO2 Concentration and Air Temperature (CO2 농도 및 기온 상승에 대한 현사시나무의 광합성 반응)

  • Lee, Solji;Oh, Chang-Young;Han, Sim-Hee;Kim, Ki Woo;Kim, Pan-Gi
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.1
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    • pp.22-28
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    • 2014
  • This study was conducted to investigate the photosynthetic characters of Populus alba${\times}$glandulosa cuttings in response to elevated $CO_2$ concentration and air temperature for selecting tree species adaptive to climate change. The cuttings were grown in environment controlled growth chambers with two combinations of $CO_2$ concentration and air temperature conditions: (i) $22^{\circ}C$ + $CO_2$ 380 ${\mu}mol$ $mol^{-1}$ (control) and (ii) $27^{\circ}C$ + $CO_2$ 770 ${\mu}mol$ $mol^{-1}$ (elevated) for almost three months. The cuttings under the elevated treatment showed reduced tree height and photosynthetic pigment contents such as chlorophyll and carotenoid. In particular, the elevated treatment resulted in a marked reduction in the chlorophyll a closely associated with $CO_2$ fixative reaction system. Different levels of reduction in photosynthetic characters were found under the elevated treatment. A decrease was noted in photochemical reaction system parameters: net apparent quantum yield (7%) and photosynthetic electron transport rate (14%). Moreover, a significant reduction was obvious in $CO_2$ fixative reaction system parameters: carboxylation efficiency (52%) and ribulose-1,5-bisphosphate(RuBP) regeneration rate (24%). These results suggest that the low level of photosynthetic capacity may be attributed to the decreased $CO_2$ fixative reaction system rather than photochemical reaction system.

An Analysis of Greenhouse Gas Reduction effect of Automotive Engine Re-manufacturing throug Whole Process Analysis (전과정 분석을 통한 자동차엔진 재제조시 온실가스 저감효과 분석)

  • Ji-Hyoung Park;Han-Sol Lee;Yong-Woo Hwang;Young-Chun Kim;Chung-geun Lee
    • Resources Recycling
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    • v.32 no.2
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    • pp.43-51
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    • 2023
  • In this research, through LCA analysis, the environmental impact of automotive engine manufacturing and re-manufacturing was analyzed from the perspective of the entire process, and the greenhouse gas reduction effect was calculated based on this. The amount of greenhouse gas emitted from the process of acquiring and manufacturing raw materials for automotive engines is about 3,473 kg for new manufacturing and 872 kg for re-manufacturing. Thus, the amount of greenhouse gas reduction by engaging in re-manufacturing is about 2,601 kg; the analysis shows a reduction effect in each part of the entire process except for the processing stage. As a result of the LCA weighted analysis, the environmental impact of new product manufacturing was found to be 1.07E+03 Eco-point, and it was 2.67E+02 Eco-point for re-manufacturing. The share of GWP(Global Warming Potential) among the six major impact categories(Abiotic Depletion Potential, Acidification Potential, Eutrophication Potential, Global Warming Potential, Ozone-layer Depletion Potential, Photochemical Oxidant Creation Potential) as high at 99.72%(new manufacturing) and 99.68%(re-manufacturing).

Fabrication of C2H2 Gas Sensors Based on Ag-Doped Hierarchical ZnO Nanostructures and Their Characteristics (Ag가 도핑된 계층적 ZnO 나노구조 기반 C2H2 가스센서의 제작과 그 특성)

  • Lee, Kwan-Woo;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.23 no.6
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    • pp.397-401
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    • 2014
  • This paper describes the fabrication and characteristics of $C_2H_2$ gas sensor based on Ag-doped hierarchical ZnO nanostructures. In this work, a pure hierarchical ZnO structure was prepared using a simple hydrothermal method, and Ag nanoparticles doped the hierarchical ZnO structure were uniformly synthesized through photochemical route. The synthesized samples were characterized by SEM, TEM, EDS, XRD and PL spectra. Average size of prepared ZnO structures was around $2{\sim}3{\mu}m$ and showed highly uniform. The average size of Ag nanoparticles was 70 nm. The gas sensing properties of as-prepared products were investigated using resistivity-type gas sensors. 5 at% Ag-doped ZnO based sensors exhibited good performances for $C_2H_2$ gas in comparison with the un-doped one. The sensor based on Ag-doped hierarchical ZnO structures had linear response property from 5~1000 ppm of $C_2H_2$ concentration at working temperature of $200^{\circ}C$. The response values with 100 ppm $C_2H_2$ at $200^{\circ}C$ were 10% and 75% for pure and 5 at% Ag-doped hierarchical ZnO nanostructures, respectively. Moreover, the device showed excellent selectivity towards to $C_2H_2$ gas at optimal working temperature of $200^{\circ}C$.