• Title/Summary/Keyword: photo

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A study of N-generation digital photographic culture (N세대 디지털 사진 문화에 관한 연구 -dcinside.com의 사례분석 연구-)

  • 강홍규
    • Proceedings of the Korea Contents Association Conference
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    • 2003.05a
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    • pp.127-131
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    • 2003
  • In this study, I intend to analyze to cultural phenomenon centering around a digital photo. Especially, I consider digital camera and digital photo's culture of N-generation by studying a case of digital camera's internet silt, DCINSIDE.COM A digital photo in daily life is one of the remarkable phenomenon of digital culture. Photography that is faster to understand and more familiar than letter leads 0 digital culture. Digital photo takes charge of a group at display phone with sound. N generation who is familiar to image takes with a digital photo in every ways of communication. Recently our communication culture use a image to new communication through digital camera and development of digital photo. Digital photo deeply comes into our ordinary life when we never recognize in advance. And it let us recognize a lot of changes and communication. In this point of time, it demand that we must have a responsible attitude for development of digital photographic culture.

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Decomposition of Gas-Phase Benzene on TiO2 Coated Alumina Balls by Photocatalytic Reaction (이산화티탄이 코팅된 알루미나 볼에서 광촉매 반응에 의한 기상벤젠의 분해)

  • Lee Nam-Hee;Jung Sang-Chul;Sun Il-Sik;Cho Duk-Ho;Shin Seung-han;Kim Sun-Jae
    • Korean Journal of Materials Research
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    • v.14 no.6
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    • pp.407-412
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    • 2004
  • Photo decomposition of gas phase benzene by $TiO_2$ thin films chemically deposited on alumina balls were investigated under UV irradiation. Photo decomposition rates were measured in real time during the reaction using a photo ionization detector, which ionizes C-H bonding of benzene molecules and then converts into volatile organic compounds (VOCs) concentrations. From the measuring results, the VOCs concentration increased instantly when IN irradiated because C-H bonds of benzene molecules strongly absorbed on the surface of $TiO_2$ films before the IN irradiation was destroyed by photo decomposition. After that, the VOCs concentration decreased with increasing surface area of $TiO_2$ and reaction time under the IN irradiation. At the optimal conditions for the photo decomposition of gas phase benzene, the reaction rate of the photo decomposition for high concentrations (over 60 ppm) was slow but that of relatively low concentration (under 60 ppm) was fast, due to limited surface area of $TiO_2$ thin films for the reaction. Thus, it is concluded that the photo decomposition rate was mainly affected by the surface area of $TiO_2$ or absorption reaction.

Thermal and Photochemistry of Methyl Iodide on Ice Film Grown on Cu(111)

  • Sohn, Young-Ku;White, John M.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1470-1474
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    • 2009
  • Thermal and photochemistry of methyl iodide ($CH_3I)\;adsorbed\;on\;D_2O$ ice film on Cu(111) at 100 K were studied using temperature-programmed desorption (TPD) time-of-flight mass spectrometry (TOF-MS), X-ray and ultraviolet photoelectron spectroscopies. On the basis of TPD, multilayer and monolayer $CH_3I$ molecules desorb from $D_2O$ ice layer at 120 and 130 K, respectively. Photo-irradiation at 100 K exhibits dramatic changes in the TPD and I $3d_{5/2}\;XPS\;of\;CH_3I$ on ice film, due to a dramatic dissociation of $CH_3I$. The dissociation is likely activated by solvated electrons transferred from the metal substrate during photo-irradiation. No other photo-initiated reaction products were found within our instrumental detection limit. During photo-irradiation, the $CH_3I$, $CH_3$ and I could be trapped (or solvated) in ice film by rearrangement (and self-diffusion) of water molecules. A newly appeared parent molecular desorption peak at 145 K is attributed to trapped $CH_3I$. In addition, the $CH_3$ and I may diffuse through ice and chemisorb on Cu(111), indicated by TPD and I $d_{5/2}$ XPS taken with photo-irradiation time, respectively. No molecular ejection was found during photo-irradiation at 100 K. The work functions for $CH_3I/Cu(111),\;D_2O/Cu(111)\;and\;CH_3I/D_2$O/Cu(111) were all measured to be about 3.9 eV, 1.0 eV downward shift from that of clean Cu(111).

A Study on the degradation of Lindane in water by a Photo-Fenton process and a UV/$H_2O_2$ process (Photo-Fenton 공정과 UV/$H_2O_2$ 공정을 이용한 Lindane의 분해특성 비교 연구)

  • Lee, Ju-Hyun;Choi, Hye-Min;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.109-117
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    • 2010
  • In the present study, the degradation characteristics of Lindane by Advanced Oxidation Processes(UV/$H_2O_2$, Photo-Fenton process) were studied. The degradation efficiency of Lindane in aqueous solution was investigated at various initial pH values, Fenton's reagent concentrations and initial concentrations of Lindane. GC-ECD was used to analyze lindane. Lindane has not been degraded without application of AOPs over two hours. But, approximately 5% of lindane was degraded with UV or $H_2O_2$ alone. Lindane with UV/$H_2O_2$ process showed approximately 7% higher removal efficiency than $H_2O_2$ process. In the UV/$H_2O_2$ process, the pH values did not affect the removal efficiency. The optimal mole ratio of $H_2O_2/Fe^{2+}$ for lindane degradation is about 1.0 in Photo-Fenton process. Also, the experimental results showed that lindane removal efficiency increased with the decrease of initial concentration of lindane. Under the same conditions, the order lindane of removal efficiency is as following : Photo-Fenton process > UV/$H_2O_2$ process > $H_2O_2$ process. In addition, intermediate products were identified by GC-MS techniques. Than PCCH(Pentachlorocyclohexene) was identified as a reaction intermediate of the Photo-Fenton process.

A Study on the Utilization of Photo Contents based Electronic Cultural Atlas (전자문화지도 기반 사진 콘텐츠 활용에 관한 연구)

  • Lee, Dong-Yul;Kang, Ji-Hoon;Moon, Sang-Ho
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.5 no.2
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    • pp.315-323
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    • 2015
  • As a form of convergence studies, many studies on electronic cultural atlas have been performed. In this paper, our objective is to design an electronic cultural atlas for utilizing photo contents based on display and sharing effect. This is one of the ways to effectively use various photo contents. Through electronic cultural atlas, photo contents are recognized as an object that contains a lot of information. To do this, we design an electronic cultural atlas for utilizing photo contents, and investigate the utilization differences through comparison with existing systems. In detail, we examine the limits of the traditional photo exhibition method, and research on usability of users when an electronic cultural atlas was used to exhibit and share the photos contents efficiently.

The Photoreactivity of 2-Halobenzyl Phenyl Ether (2-할로벤질 페닐 에델의 광반응성)

  • Park, Yong Tae;Kim, Young Hee;Shin, Hyun Il
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.203-208
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    • 1998
  • The photochemical reactivities of 2-halobenzyl phenyl ether, in which 2-halobenzyl moiety are tethered to phenyl moiety by the etheral alkyl linkage, has been studied. In the presence of nitrogen, the photochemical reaction of 2-chlorobenzyl phenyl ether (1) produces mainly phenol and photo-Fries type reaction products, while the corresponding bromo analog 2 produces photocyclization and photoreduced products, along with phenol and photo-Fries type products. The former result implies that since chlorine is bound to the benzyl ring firmly, the rather weaker $CH_{2}-O$ bond of 1 is cleavaged to produce the photo-Fries type product. The latter implies that the photoinduced fission of phenyl-bromine bond of 2 can compete with the fission of $CH_{2}-O$ bond, since the bond energy of phenyl-bromine is lower than that of phenyl-chlorine. Since by the presence of oxygen the formation of phenol is not affected much, the formation of photo-Fries type products is changed a little, and the formations of photocyclization and photoreduced products are affected effectively, a singlet state is involved in the formation of phenol, and both singlet and triplet state may be involved in the formation of photo-Fries type reaction, while a triplet state is involved in the formation of photocyclization and photoreduction products.

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