• Title/Summary/Keyword: phosphate of ammonium

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Preparation of Hexaaluminate Phosphor Particles with Spherical Shape by Gas Phase Reaction Process (기상 공정에 의한 구형 형상의 헥사알루미네이트계 형광체 제조)

  • Jung, Dae Soo;Hong, Seung Kwon;Koo, Hye Young;Ju, Seo Hee;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.616-620
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    • 2005
  • The morphology and photoluminescence characteristics of green light emitting hexaaluminate phosphor particles prepared by high temperature spray pyrolysis from spray solution with and without ammonium dihydrogen phosphate flux were investigated. The particles prepared from spray solution without flux material had hollow morphology at preparation temperatures between $900^{\circ}C$ and $1,650^{\circ}C$. Ammonium dihydrogen phosphate flux added into spray solution enabled the formation of particles with spherical shape and filled morphology at preparation temperatures between $900^{\circ}C$ and $1,650^{\circ}C$. The hexaaluminate phosphor particles with magnetoplumbite structure were directly prepared by spray pyrolysis from spray solution with ammonium dihydrogen phosphate flux above $1,600^{\circ}C$. Ammonium dihydrogen phosphate flux was effective in improving the photoluminescence intensity of the phosphor particles at low preparation temperatures. The phosphor particles prepared from spray solution with and without flux material by spray pyrolysis under reducing atmosphere at $1,650^{\circ}C$ had comparable photoluminescence intensities with that of the phosphor particles optimized by post-treatment.

A study on synthesis of polyurethane dispersion by $H_{12}MDI$ and how effect to mechanical properties by ammonium dihydrogen phosphate ($H_{12}MDI$를 이용한 수분산 폴리우레탄 수지의 합성 및 ammonium dihydrogen phosphate에 의한 물성변화에 관한 연구)

  • Lee, Joo-Youb;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.74-82
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    • 2014
  • For this research, prepared ammonium dihydrogen phosphate aqueous solution and polyurethane dispersion. Use these resin, this article has been analyzed about change of mechanical properties by increasing amount of ammonium dihydrogen phosphate aqueous solution in polyurethan resin on coated leather and dried film. According to measure data for solvent resistance, DPU(polyurethane dispersion) resin and DPU-AD1, D2, D3(samples of polyurethaneresin with ammonium dihydrogen phosphate aqueous solution) had good property. As known in the results, increase of ammonium dihydrogen phosphate constant did not influence to big change of polyurethane resin properties. As test of tensile strength, DPU had highest tensile characteristic($3.114kg_f/mm^2$) and DPU-AD3 had lowest tensile characteristic($2.510kg_f/mm^2$). As same as tensile characteristic, abrasion test determined DPU(50.5 mg.loss) had highest properties. In elongation case, DPU had best properties(602 %) in this experiment.

Metanol Metabolism and Extracellular Polysaccharide Biosynthesis in Methylovorus sp. strain SS1 DSM 11726 (Methylovorus sp. strain SS1 DSM 11726의 메탄올 대사와 세포외 다당류 생합성)

  • Kim, Jae. S.;Kim, Si W.;Kim, Young M.
    • Korean Journal of Microbiology
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    • v.34 no.4
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    • pp.207-211
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    • 1998
  • Melhylovorus sp. strain SS1 grown on methanol was found to show activities of key enzymes of the linear route, $NAD^+$-linked formaldehyde and formate dehydrogenases, and the cyclic route, hexulose-6-phosphate synthase, glucose-6-phosphate isomerase, glucose-6-phosphate dehydrogenase, and 6-phosphogluconate dehydrogenase, for formaldehyde oxidation. The activities of the cyclic route enzymes were higher than those of the linear route enzymes. The bacterium also exhibited activities of the key enzymes of the ribulose monophosphate and Entner-Doudoroff pathways and transaldolase involved in the formaldehyde assimilation and the enzymes involved in the biosynthesis of extracellular polysaccharide. Cells grown in the presence of 2.3 mM ammonium sulfate were higher in the productivity of extracellular polysaccharide, but lower in the growth yield, than those grown in the presence 7.6 mM ammonium sulfate. The activities of 6-phosphogluconate dehydrogenase, phosphoglucomutase, and UDP-pyrophosphorylase in cells grown under nitrogen-limited condition were higher, but that of 6-phosphogluconate dehydratase/2-keto-3-deoxy-6-phosphogluconate aldolase was lower, than those in cells grown in the presence of sufficient amount of nitrogen source.

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Applicability of Soil Washing with Neutral Phosphate for Remediation of Arsenic-contaminated Soil at the Former Janghang Smelter Site ((구)장항제련소 주변 부지 매입구역 비소 오염토양에 대한 중성 인산염 토양세척법의 적용가능성 평가)

  • Im, Jinwoo;Kim, Young-Jin;Yang, Kyung;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.19 no.4
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    • pp.45-51
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    • 2014
  • In accordance with the view on remediated soil as a resource, this study assessed the applicability of soil washing with the neutral phosphate for remediation of arsenic (As)-contaminated soil. Three soil samples of different land uses (i.e., rice paddy, upland field and forest land) were collected from the study site, and the aqua regia-extractable As concentrations were 59.2, 30.8 and 53.1 mg/kg, respectively. Among the neutral phosphate reagents, ammonium phosphate showed the highest As washing efficiency. The optimized washing condition was 2-hr washing with 0.5M ammonium phosphate solution (pH 6) and soil to liquid ratio of 1 : 5. The extraction efficiencies of As did not guarantee the residual soil As concentrations to satisfy the Korea soil regulatory level (i.e., Worrisome level) in the three soil samples. To enhance washing efficiency, the As-contaminated soil was submerged in washing solution (1 : 1, w/v) for 24 hr and 1-hr washing with 0.5M ammonium phosphate solution was tested. As extraction efficiencies of 36.1 (rice paddy), 21.4 (upland field) and 26.4% (forest land) were attained, which satisfied the Worrisome level for Region 1 (25 mg/kg of As) in rice paddy, but not in upland field and forest land.

Effect of Ammonium Phosphate Concentration on the Growth of Recombinant E. coli (재조합 대장균의 세포성장에 대한 인산암모늄 농도의 영향)

  • 김종수;석근영차월석
    • KSBB Journal
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    • v.11 no.4
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    • pp.389-397
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    • 1996
  • The growth of recombinant E. coli and formation of the by-products were investigated. Ammonium phosphate is known to affect the cell growth as well as the enzyme formation. When initial ammonium phosphate concentration was 0.5g/L, cell mass was 4.1g/L. By adding tryptone to the medium, acetic acid formation increased while lactic acid formation decreased. In cultivating recombinant E. coli, lactic acid and acetic acid turned out to be important by-products which affected cell yield and growth rate. Initial ammonium phosphate and tryptone concentration were optimized in our research and can be applied for other culture of recombinant E. coli.

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Early-Age Compressive Strength of Magnesia-Phosphate Composite with Phosphate Type (인산염 종류에 따른 마그네시아-인산염 복합체의 초기 압축강도 특성)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.185-186
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    • 2016
  • Four mortar mixes tested to evaluate the early-age compressive strength of magnesia-phosphate composite with phosphate type. Monopotassium phosphate, dipotassium phosphate, ammonium dihydrogen phosphate and diammonium phosphate used as phosphate. Test results show that the compressive strength of mortar used monopotassium phosphate as phosphate was highest, while compressive strength of mortars used dipotassium phosphate and diammonium phosphate as phosphate were not developed.

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Feasibility of Phosphorus Recovery from Biological Livestock Wastewater Treatment Plant (생물학적 축산분뇨처리시설에서 인 회수의 가능성 평가)

  • Ahn, Johwan;Kim, Jangho;Min, Sungjae
    • Journal of Korean Society on Water Environment
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    • v.32 no.4
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    • pp.343-348
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    • 2016
  • A chemical sequencing batch reactor was operated to test the feasibility of nutrient recovery from a biological livestock wastewater treatment plant. Both phosphate and ammonia could be successfully recovered as magnesium ammonium phosphate (MAP) crystals. The contents of TP and TN in the recovered MAP crystals were 26.2% and 4.0%, respectively. Zn, Cr and Ti were identified in the crystals, but the contents remained below the Korean standard for an organic fertilizer. Chemical analyses confirmed that the MAP crystals could be useful phosphate fertilizers. On the other hand, the results of physical analyses using an X-ray diffractometer and an energy dispersive X-ray spectrometer strongly suggested that crystalline materials like magnesium potassium phosphate (KMP) and hydroxyapatite (HAP) were also formed during the MAP crystallization, depending on the availability of K+ and Ca2+.

Study on Performance of pH Reduction for Recycled Aggregate by Using Phosphate of Ammonium (인산암모늄을 사용한 순환골재의 pH 저감 성능 검토)

  • Gao, Shan;Lee, Gun-Cheol;Park, Ji-Woong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.106-107
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    • 2016
  • Construction waste is recycled and used for the efficient and eco-friendly disposal of construction waste increasing due to reconstruction and redevelopment project and so on. There is recycled aggregate as a typical case. And this recycled aggregate shows strong alkalinity due to calcium hydroxide, and causes many environmental problems. Therefore, this is a study on reduction in the strong alkalinity of recycled aggregate by using phosphate of ammonium in order to reduce the pH of recycled aggregate. Besides, a possibility that a pH reducing agent of recycled aggregate could be applied to a site was evaluated. As a result, it was possible to verify that pH decreased as the percentage of pH reducing agent increased. It is thought that the pH reducing agent can be applied to a site by methods such as immersion and spray using the pH reducing agent in the process of producing recycled aggregates.

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Electrical and Rheological Behavior of the Anhydrous ER Fluids Based on Chitosan Derivatives as the Dispersion Phases

  • Choi Ung-su;Sung Bo-hyun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.323-329
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

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Study on the Reactivity of Sodium Phosphate Ammonium Chloride pH Reduction Agents (인산나트륨계 염화암모늄 pH저감제의 반응성 검토)

  • Shin, Ki-Don;Gao, San;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.105-106
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    • 2017
  • Previous studies have confirmed the performance of pH reduction agents using liquid sodium phosphate based ammonium chloride as a pH reduction agent. In this study, the pH reduction performance considering economical and applicability as a practical stage and the property change analysis for the identification of the reaction mechanism of the pH reduction agent were carried out. As a result, the pH reduction performance at a low rate of the pH reducing agent was confirmed. The specific gravity of CaO decreased significantly after XRF analysis. It is also believed that this reduces the amount of Ca(OH)2 produced and contributes to pH reduction.

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