• 대한환경공학회지
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• 제22권4호
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• pp.723-731
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• 2000

유해유기화합물질 처리시 처리효율을 증대시키기 위하여, 본 연구에서는 GAC를 이용한 RSTA에서 phenol과 4-nitrophenol 의 경쟁흡착을 연구하였다. 이성분계 흡착등온시 phenol은 Freundlich 흡착동온식 적용이 불가능하였다. 그리고 활성탄 주입량이 적어짐에 따라 또 흡착질의 농도가 증가함에 따라 두 성분간의 경쟁흡착은 심화되었다. RSTA를 이용한 연속식 실힘에서는 유입유량이 감소할수록 두 성분간의 경쟁흡착성향은 증가하는 것으로 나타났다. 수축 각 변화에 따른 경쟁흡착실험에서는 수축각이 커질수록 파과시간이 증가하였으며, 활성탄 충전층 수를 변화시킨 실험에서는 충전층 수를 증가시킴에 따라 각 성분의 흡착효율 및 phenol에 대한 4-nitrophenol 경쟁흡착능은 증가하였다. RSTA에서의 이러한 성능 증대는 유체의 정제와 분리에 적용할 수 있을 것이다.

• 한국지반공학회지:지반
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• 제11권2호
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• pp.121-138
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• 1995

여러종류의 화합물질들이 동시에 토양에 유출되었을 때 이들이 토양에 흡착하는 정도를 예측 함에는 Langmuir Competitive Model과 IAS(Ideal Adsorption Model) 등이 널리 사용되고 있 는데, 5개의 유기화합물질(Phenol, 2,4-Dichlorophenol, 2,4,6-Trichlorophenot Brucine, Thiourea)과 2종류의 토양을 이용한 흡착실험을 통해서 이 Model들의 예측도를 비교분석하였다. 흡착실험은 이 화합물질들이 독자적인 상태에서 그리고 혼합상태에서 각각 구분하여 실헙하였다. 일반적으로 IAS Model이 Langmuir Model보다 혼합상태에서 각 구성 화합물질들의 흡착을 더 정확히 예측하였다. Langmuir Model은 Phenol과 함께 섞여있는 다른물질의 농도가 높을 때 Phenol의 흡착을 낮게 예측하였다. 두가지 Model모두 Thiourea가 혼합상태에 있을때 흡착정도를 만족스럽게 예측하지 못했는데 Thiourea는 Aliphatic화합물이고 나머지 4개는 Aromatic화합물이다.

• Archives of Pharmacal Research
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• 제14권3호
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• pp.249-254
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• 1991

Activated carbons from rice-straw can be used as an adsorbents for the purification of water were prepared and evaluated. The adsorptive capacities of activated carbons were measured by iodine, potassium permangante, phenol and metals. It was observed by electron microscope (SEM) and IR spectrum that organic components in the rice-straw and its carbonization product were disappeared. Slit-shaped and porousstructures were formed by activation. There was no relationship between temperature and adsorption of iodine but adsorption of potassium permanganate increased as temperature rose. The adsorption of the phenol was greater than 99%. The adsorption data of phenol at $25^\circ{C}$ obeyed the Freundlich's isotherm. Various metals except sodium were not removed by activated carbon.

• 한국환경과학회지
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• 제7권6호
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• pp.773-782
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• 1998

The adsorption experiment of phenol(Ph) from aqueous solution on granular activated carbon was studied in order to design the fixed-bed adsorption column. The experimental data were analyzed by unsteady-state, one-dimensional heterogeneous model. Finite element method(FEM) was applied to analyze the sensitivity of parameter and to predict the fixed-bed adsorption column performance on operation variable changes. The prediction model showed similar effect to mass transfer and intraparticle diffusion coefficient changes suggesting that both parameter present mass transfer rate limits for GAC-phenol system. The Freundlich constants had a greater effect than kinetic parameters for the performance of fixed-bed adsorption column. FEM solution facilitated prediction of concentration history in solution and within adsorbent particle.

• Carbon letters
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• 제7권3호
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• pp.188-195
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• 2006

Phosphoric acid-activated carbon WP's and zinc chloride-activated carbons WZ's were developed from wild cherry stones. The textural properties of the activated carbons were determined from nitrogen adsorption data at 77 K and the chemistry of the carbon surface, i.e. the surface carbon-oxygen groups (type and amount) was determined from the base and acid neutralization capacities (Boehm method). The adsorption of phenol, p-nitrophenol, p-chlorophenol, dinitrophenol and dichlorophenol was followed at 298 K. The activated carbons obtained were characterized by high surface area and large pore volumes as well as by high surface concentration of C-O groups. The investigated carbons exhibited high adsorption capacities towards phenols with these capacities increased with the increase of molecular weight and the decrease of the solubility of phenol in water. However, no general relationship could be observed between the adsorption capacities of carbons and any of their textural parameters or their surface chemistry. This may be attributed to the many factors controlling phenol adsorption and the different types and mechanisms of adsorption involved.

• 분석과학
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• 제20권3호
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• pp.193-197
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• 2007

본 연구에서는 금속침적처리에 의한 입상활성탄의 페놀흡착에 관하여 고찰하였다. 금속침적 용액으로는 질산코발트와 질산아연용액을 사용하였다. 77K에서의 질소 흡탈착 특성을 통한 비표면적 및 포어 구조를 측정하였다. 페놀 흡착량 및 흡착속도는 분광광도계를 이용하여 측정하였다. 요오드흡착 용량은 금속 침적 처리되지 않은 활성탄보다 코발트 금속이 침적된 코발트침적 활성탄이 크게 흡착됨을 알 수 있다. 코발트 침적 활성탄은 중기공이 발달되었고, 이것은 메틸렌블루와 같은 고분자 물질의 흡착에 다른 흡착제보다 효과적이다. 페놀 흡착용량은 금속 침적활성탄의 금속 침적에 따른 비표면적 감소에도 불구하고 Co-GAC>Zn-GAC>R-GAC 순서로 측정되었다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.15-18
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• 2001

Sorption/desorption studies were conducted to determine sorption/desorption characteristics of phenolic compounds (phenol and 4-chlorophenol) in organically modified natural bentonite. The cationic exchange capacity (CEC) of bentonite was exchanged with a cationic surfactant, hexadecyltrimethylammonium (HDTMA), to enhance the removal capacity of organic phenol contaminants dissolved in aqueous solution. This modification produces a change of the surface property of bentonite from hydrophilic to organophilic. The single-solute and bi-solute competitive adsorptions were performed In batch mode to investigate the removal of two toxic organic Phenols, chlorophenol and 4-chlorophenol on the HDTMA-bentonite. The adsorption affinity of the 4-chlorophenol was higher than phenol due to higher octanol:water partition coefficient (Kow). The single-solute and bi-solute competitive desorptions were also performed investigate the competitive desorption of the phenolic compounds from HDTMA-bentonite. Freundlich model was used to analyze the single-solute adsorption/desorption results, while the IAST model predicted the hi-solute adsorption/desorption equilibria. The IAST model well predicted hi-solute competitive adsorption/desorption behaviors.

• 한국환경과학회지
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• 제16권2호
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• pp.143-149
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• 2007

The effect of precoating of silica with polyamine surfactants on the adsorption of five model compounds containing asphalt-like functionalities was studied. Hexadecyltrimethylammonium chloride (HDTMA) and 1-hexadecylamine were used for silica precoating. The model compounds representing five asphalt functionalities were benzoic acid, phenol, benzylbenzoate, benzophenone, and quinoline. All the adsorption isotherms conformed well to the Langmuir adsorption model. All the model compounds showed decreased adsorption with the HDTMA precoating. However, two acidic compounds, benzoic acid and phenol, showed enhanced adsorption on the silica precoated with 1-hexadecylamine. In aqueous solutions, the adsorption of the acidic compounds were in the following order: silica precoated with 1-hexadecylamine > silica precoated with HDTMA > uncoated silica.

• 상하수도학회지
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• 제23권5호
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• pp.609-618
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• 2009

Repeated phenol spill in the Nakdong River has been a big issue in Korea since 1991. In this study, treatment of phenol in each water treatment process and total water treatment system is evaluated. Phenol was highly volatile, easily oxidized by ozone, and readily absorbed onto GAC. When there was phenol of 0.3mg/L in water, by ozonation of 1mg/L or by GAC adsorption with EBCT of 10minutes or longer, it could be treated to lower than 0.005mg/L, the national drinking water standard of phenol. Even when a sufficient contact time(70minutes) was allowed, only 35 to 40% of phenol could be removed by powdered activated carbon(PAC). Based on the test results, it can be concluded that 1.0mg/L or less concentration of phenol can be treated at the plants adopting the combination process of ozone and GAC down to the safe level. In this study, removal characteristics for phenol were evaluated with the existing pilot plant and demo plant in different advanced water treatment processes(AWTPs). In the future, studies on changes in oxidation and adsorption characteristics caused by competitive matters such as DOC and removal characteristics by other various AWTPs including ozone/filter adsorber need to be performed.

• 한국환경과학회지
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• 제23권11호
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• pp.1821-1826
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• 2014

The adsorption characteristics of the methylene blue (MB) were studied using three activated carbons such as ACA and ACB with similar specific surface area (1,185 and $1,105m^2/g$), and ACC with relatively high specific surface area ($1,760m^2/g$). The surface chemical properties of these activated carbons were investigated by X-ray photoelectron spectroscopy (XPS). The results indicated that ACA had more functional groups (with phenol, carbonyl, and carboxyl etc.) than ACB (with carbonyl and carboxyl) and ACC (with carboxyl). The isotherm data were fitted well by Langmuir isotherm model. The adsorption capacities of ACA, ACB, and ACC for MB were 454.7 mg/g, 337.7 mg/g, and 414.0 mg/g, respectively. As phenol and carboxyl content of the surface on activated carbon increased, MB adsorption capacity was increased. Although ACA had a smaller specific surface area than ACC, the content of phenol and carboxyl group was abundant, so MB adsorption capacity was found to be higher than ACC.