• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.82-87
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• 2007

New porous separators based on non-polyolefin materials including the blend of poly (vinyl chloride) (PVC)/poly (vinylidene fluoride-co-hexafluoropropylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA), and the porous separator based on poly (vinylidene fluoride) (PVdF) were prepared by phase inversion method. The porosity and morphology were controlled with phase inversion rate, which is governed by the relative content of non-solvent and solvent in coagulation bath. To enhance tensile strength, the solvent pre-evaporation and uni-axial stretching processes were applied. The ionic conductivity was increased with increasing stretching ratio, and tensile strength was increased with increasing solvent pre-evaporation time and stretching ratio. The 200% stretched PVdF separator showed 56 MPa of tensile strength, and the ionic conductivity of the stretched PVdF separator was $8.6{\times}10^{-4}\;S\;cm^{-1}\;at\;25^{\circ}C$.

• Membrane Journal
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• v.22 no.3
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• pp.178-190
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• 2012

Flat sheet membranes were prepared with polysulfone (PSF) by an immersion precipitation phase inversion method. Membranes were prepared with PSF/N-methylpyrrolidone (NMP)/polyvinylpyrrolidone (PVP)/phosphoric acid casting solution and water coagulant. By using the successive process of the vapor-induced phase inversion (VIPS) followed by the nonsolvent-induced phase inversion (NIPS), the effect of phosphoric acid addition to casting solution on morphology and permeability of membrane was studied. The mean pore size, the porosity, and the water flux of membranes were increased by the addition of small amount of phosphoric acid. Furthermore, the morphology of the prepared membranes were changed from a dense sponge-like structure to highly enhanced asymmetric structure. PSF/NMP/PVP/phosphoric acid/2-butoxyethanol (BE) casting solution were prepared and cast the successive VIPS-NIPS process with same experimental condition. Due to the addition of BE to casting solution, the mean pore size and almost 0.1 ${\mu}m$ and the water flux increased about 10 to 12 $L/cm^2{\cdot}min{\cdot}bar$.

• Membrane Journal
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• v.28 no.3
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• pp.187-195
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• 2018

In this work, the morphology of polyvinylidene-co-hexafluoropropylene (PVDF-co-HFP) membranes were systemically investigated using phase inversion technique, to target membrane contactor applications. As the presence of macrovoids degrade the mechanical integrity of the membranes and jeopardize the long-term stability of membrane contactor processes (e.g. wetting), a wide range of dope compositions and casting conditions was studied to eliminate the undesired macrovoids. The type of solvent had significant effect on the membrane morphology, and the observed morphology were correlated to the physical properties of the solvent and solvent-polymer interactions. In addition, to fabricate macrovoid-free structure, the effects of different coagulation temperatures, inclusion of additives, and addition of nonsolvents were investigated. Due to the slow crystallization rate of P(VDF-co-HFP) polymer, it was found that obtaining porous membrane without macrovoids is difficult using only nonsolvent-induced phase separation method (NIPS). However, combined other phase inversion methods such as evaporation-induced phase separation (EIPS) and vapor-induced phase separation (VIPS), the desired membrane morphology can be obtained without any macrovoids.

• KSBB Journal
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• v.17 no.2
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• pp.207-211
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• 2002

The theophylline imprinted membrane was prepared by a wet phase inversion method. Theophylline was implanted during copolymerization of acrylonitrile with acrylic acid or implanted in the dimethyl sulfoxide solution containing10 wt% copolymer, p(AN-co-AA). Rolling the glass plate, on which the copolymer solution was cast, in water removed the sponge layer and thus made the membrane symmetric. The adsorption selectivity of the membrane toward template molecule was increased with the coagulation temperature of the membrane and the initial concentration of the theophylline and caffeine mixture.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.9 s.252
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• pp.891-897
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• 2006

The SRS method is applied to a turbulent flame with radiation/turbulence interaction to invert the temperature and concentration profile. The flame is conditioned as optically thin per each fluctuation length and the flame spectral intensity is measured for inversion. From inversion result, we find that SRS can successfully invert the coupled temperature/concentration fluctuation amplitudes. For two cases of experiments, inverted values are within approximately 1% over the full range of fluctuation amplitude. However, SRS cannot find the detailed local fluctuation parameters such as pattern and phase, etc. as far as they do not affect the resulting radiation intensity. Important available parameters are the mean temperature and the temperature fluctuation amplitude. The radiation/turbulence interaction effect is verified to play an important role in the radiation.

• Journal of Institute of Control, Robotics and Systems
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• v.16 no.4
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• pp.329-334
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• 2010

This paper presents the design of a neural network based adaptive control for missile. Acceleration of missile by tail fin control cannot be controllable by DMI (Dynamic Model Inversion) directly because it is non-minimum phase system. To avoid the non-minimum phase system, dynamic model inversion is applied with output-redefinition method. In order to evaluate performance of the suggested controllers we selected the three cases such as control surface fail, control surface loss and wing loss for model uncertainty. The corresponding aerodynamic databases to the failure cases were calculated by using the Missile DATACOM. Using a high fidelity 6DOF simulation program of the missile the performance was evaluates.

• Transactions of the Society of Information Storage Systems
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• v.3 no.1
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• pp.5-12
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• 2007

This paper investigates the design of disturbance observer for rotational vibration suppression in disk drive systems. The design aims to provide an optimal controller which satisfies both vibration performance and robust stability. It consists of an inversion method, a special filter, and optimization scheme. Firstly a new inversion method is introduced, which provides more accurate inversion compared to conventional zero phase error method. The inversion is to deal with unstable zeros in the plant model. Secondly a special filter for disturbance selection is given, which features adjustable gain and band pass characteristics so that it enables flexible shaping of the loop considering the trade-off between performance and stability margins. And finally the parameters of disturbance observer are optimized in conjunction with external disturbance model. Simulation and experiment on commercial hard disk drives confirm that the design is very effective to such disturbance which is hard to be handled by conventional approach.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.29 no.7A
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• pp.719-726
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• 2004

In this paper, compensation characteristics of distorted WDM channel due to both chromatic dispersion and self phase modulation (SPM) is numerically investigated under the assumptions of non-uniformly distributed fiber dispersion, in order to inspect the application of mid-span spectral inversion (MSSI) to any exact transmission links. The MSSI is compensation method used in this approach. This method has an optical phase conjugator (OPC) placed in mid-way of total transmission length to compensate distorted WDM channels. It is confirmed that MSSI will become applicable to long-haul WDM systems by controlling input light power of transmission channels, when the averaged dispersion of both fiber sections with respect OPC was varied and distributed unequally each other. Applying MSSI to long-haul WDM system, it is possible to remove all in-line compensator, consequently it will be expected to reducing system cost.

• Polymer(Korea)
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• v.30 no.2
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• pp.108-111
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• 2006

In this work, the effect of the hydrophobicity of acrylic polymers on the membrane morphology was investigated. The membranes were prepared with poly(methyl methacrylate) (PMMA), poly(ethyl methacrylate) (PEMA), poly (butyl methacrylate) (PBMA), poly(isobutyl methacrylate), and their blends using the wet phase inversion method. PMMA and PEMA having a relatively less hydrophobicity formed the channel-like structure, whereas PBMA and PIBMA having more hydrophobic units formed the finger-like structure. These morphological changes were attributed to differences in the solidification process of the polymer-rich phase determine d by the polymer/solvent/nonsolvent ternary phase diagram. The membrane structures of the blends were controlled by the main component of their blends.

• Proceedings of the Membrane Society of Korea Conference
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• 1999.10b
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• pp.37-40
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• 1999