• The Journal of Advanced Prosthodontics
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• v.11 no.1
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• pp.1-6
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• 2019

PURPOSE. The purpose of this in vitro study was to evaluate the effect of surface grinding and polishing procedures using high speed zirconia diamond burs with different grit sizes on the phase transformation and flexural strength of zirconia. MATERIALS AND METHODS. Forty disc shape specimens ($15{\times}1.25mm$) with a cylindrical projection in the center of each disc ($1{\times}3mm$) were fabricated with 3Y-TZP (Prettau, Zirkonzahn, Italy). The specimens were divided into 4 groups (n=10) according to the grinding and polishing procedures: Control group - grinding (coarse-grit diamond bur), Group 1 - grinding (coarse-grit diamond bur) + polishing, Group 2 - grinding (fine-grit diamond bur) + polishing, and Group 3 - grinding (fine grit diamond bur). Each specimen was analyzed by 3D-OM, XRD analysis, and biaxial flexural strength test. RESULTS. Based on the surface morphology by 3D-OM images, polished specimens showed smoother surface and lower roughness value (Ra). In the result of XRD analysis, partial phase transformation from tetragonal to monoclinic zirconia occurred in all groups. Control group, ground with a coarse grit diamond bur, showed more $t{\rightarrow}m$ phase transformation and lower flexural strength than Groups 1 and 2 significantly. CONCLUSION. The flexural strength in all specimens after grinding and polishing showed over 500 MPa, and those were clinically acceptable. However, grinding with a coarse grit diamond bur without polishing induced the phase transformation and low strength. Therefore, surface polishing is required for the occlusal adjustment using a high speed zirconia diamond bur to reduce the phase transformation and to prevent the decrease of flexural strength of zirconia.

• Journal of the Korean Society for Heat Treatment
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• v.36 no.6
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• pp.351-358
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• 2023

Bearings are mechanical components that support loads and transmit rotation. The inner and outer rings come into contact with the rotating mechanism, requiring a very high level of hardness. To meet this requirement, heat treatment is commonly performed. The heat treatment process inherently involves thermal deformation. Particularly in the case of large bearings, significant deformation relative to the bearing's shape can occur, making accurate deformation prediction during heat treatment essential. However, predicting deformation in heat treatment is challenging due to the simultaneous consideration of phase transformation, heat transfer, and bearing deformation. In this study, an analysis of heat treatment-induced deformation in bearings was conducted, taking phase transformation into account. The thermal and mechanical properties were calculated based on the chemical composition of the bearing material. This information was then used to perform a deformation-heat transfer-phase transformation analysis. To validate the reliability of the analysis, experiments were conducted under the same conditions. When comparing the analysis and experimental results, differences in deformation were observed. These differences were attributed to variations in phase transformation conditions between the analysis and experiments. Consequently, it is anticipated that supplementing these results will enable the prediction of deformation while considering phase transformation conditions in bearings.

• The Journal of Advanced Prosthodontics
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• v.10 no.2
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• pp.132-137
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• 2018

PURPOSE. The purpose of this study was to evaluate and compare three polishing systems on the surface roughness and phase transformation of monolithic zirconia. MATERIALS AND METHODS. 100 disk shaped specimens (10 mm diameter, 3 mm thickness) were fabricated from monolithic zirconia blocks. 20 specimens were left as a control group and remaining specimens were grinded by diamond bur to simulate the occlusal adjustments. Grinded specimens were randomly divided into 4 groups: group G (no polishing), group M (Meisinger, zirconia polishing kit), group E (EVE Diacera, zirconia polishing kit), and group P (EVE Diapol, porcelain polishing kit). Surface roughness was measured with profilometer and surface topography was observed with SEM. XRD analysis was performed to investigate the phase transformation. Statistical analysis was performed with one-way ANOVA and Tukey's post hoc tests at a significance level of P=.05. RESULTS. All polishing groups showed a smoother surface than group G. Among 3 polishing systems, group M and group E exhibited a smoother surface than the group P. However, no significant differences were observed between group M and group E (P>.05). Grinding and polishing did not cause phase transformations in zirconia specimens. CONCLUSION. Zirconia polishing systems created a smoother surface on zirconia than the porcelain polishing system. Phase transformation did not occur during the polishing procedure.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.87-91
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• 2009

Welding is one of the most important joining processes and the effect of welding residual stresses in the structure has a great deal of influence on its quality. In this paper, recent development in computational welding mechanics, particularly calculation of welding residual stresses, is introduced. The hypoelastic formulation of finite element analysis for thermoelastic-plastic deformation is applied to welding processes to find residual deformations and stresses. Leblond's phase evolution equation coupled with the energy equation is employed to calculate the phase volume fraction; this plays an important role as a kinetics parameter affecting phase fraction effects in the mechanical constitutive equation of welded materials. Furthermore, transformation plasticity is taken into account for an accurate evaluation of stress. The influence of the phase transformation and the transformation plasticity on residual stress is investigated by means of numerical analyses using metallurgical parameters in Leblond's phase evolution equation that are adjusted with respect to various cooling rates in a CCT-diagram. Coding implementation is conducted by way of the ABAQUS user subroutines, UMAT.

• Journal of the Korean Ceramic Society
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• v.27 no.8
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• pp.971-978
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• 1990

The ifluence of transformability and stabilized effects in tetragonal phase on the isothermal phase transformation of Y-TZP at low temperature were investigated. The transformability of Y-TZP powders were gradually increased with calcination temeprature and reached maximum at critical temperature, but when the Y-TZP powders were calcined above critical temperature, transformability of Y-TZP were gradually decreased with increasing calcination temperature. It was concluded that maximum transformability was appeared because particle size effects decreased and constrain effects increased with calcined temperature. The isothermal phase transformation during aging at 25$0^{\circ}C$ only observed in Y-TZP stabilized by constrain effects and the amounts of transformation during aging at 25$0^{\circ}C$ only observed in Y-TZP stabilized by constrain effects and the amount of transformed monoclinic phase during aging decreased with increasing constrain effects. From these results, the mechanism of isothermal phase transformation and degradation behaviors at low temperature in Y-TZP was concluded that occurred by decreasing of constrain effects due to stress relaxation at grian boundary.

• The Journal of Advanced Prosthodontics
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• v.11 no.5
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• pp.253-261
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• 2019

PURPOSE. To evaluate the influence of cyclic loading on phase transformation of zirconia abutments and to compare the effectiveness of three different quantitative ageing assessment techniques. MATERIALS AND METHODS. Thirty two Y-TZP prostheses fabricated from two brands, InCoris ZI and Ceramill ZI, were cemented to titanium bases and equally divided into two subgroups (n=8): control group without any treatment and aged group with cyclic loading between 20 N and 98 N for 100,000 cycles at 4 Hz in distilled water at $37^{\circ}C$. The tetragonal-to-monoclinic phase transformation was assessed by (i) conventional x-ray diffraction (XRD), (ii) micro x-ray diffraction (${\mu}XRD$), and (iii) micro-Raman spectroscopy. The monoclinic-phase fractions (M%) were compared by two-way ANOVA. RESULTS. InCoris Zi presented significantly higher M% than Ceramill Zi in both control and aged groups (P<.001). Both materials exhibited significant phase transformation with monoclinicphase of 1 to 3% more in aged groups than controls for all three assessment techniques. The comparable M% was quantified by both ${\mu}XRD$ and XRD. The highest M% was assessed with micro-Raman. CONCLUSION. Cyclic loading produced significant phase transformation in tested Y-TZP prostheses. The micro-Raman spectroscopy could be used as an alternative to XRD and ${\mu}XRD$.

• Journal of the Society of Naval Architects of Korea
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• v.41 no.6
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• pp.65-74
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• 2004

The inherent strain method is known to be very efficient in predicting the deformation of steel plate by line heating. However, in the actual line heating process in shipyard, the rapid quenching changes the phase of steel. In this study, In order to consider additional effects under phase transformation, inherent strain regions were assumed to expand. Also, when calculating inherent strain, material properties of steel in heating and cooling are applied differently considering phase transformation. In this process, a new method which can reflect thermal volume expansion of martensite is suggested.8y the suggested method, it was possible to predict the plate deformations by line heating more precisely.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1433-1435
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• 2001

The mechanical and phase transformation of the cold isostatically pressed $\beta$-SiC ceramic were investigated as a function of the sintering temperature. The result of phase analysis revealed 6H, 4H, 3C and phase transformation between 3C and 4H showed over 2000$^{\circ}C$ and the $\beta$ ${\rightarrow}$ $\alpha$ phase transformation was in saturation at 2200$^{\circ}C$. The relative density and the mechanical properties of $\alpha$-SiC ceramic was increased with increased sintering temperature. The flexural strength showed the highest value of 230 MPa at 2200$^{\circ}C$. This reason is because crack was propagated through surface flaw. The fracture toughness showed the highest value of 4.2 $MPa{\cdot}m^{1/2}$ at 2200$^{\circ}C$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.3
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• pp.186-193
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• 2009

In this article, the effect of silica addition on the phase transformation characteristics of $TiO_2$ nanoparticles synthesized by using an $O_2$-enriched coflow, hydrogen, diffusion flame was investigated. TTIP(titanium tetra-isopropoxide) and TEOS(tetraethyl-orthosilicate) were used as precursors for $TiO_2$ and $SiO_2$ nanoparticles, respectively. Based on the results from TEM and XRD analysis, it is believed that the silica addition on the flame synthesis of $TiO_2$ nanoparticles reduces the particle size distribution and raises the temperature of the phase transition from anatase to rutile. But the reduced sizes of the synthesized particles due to the silica addition made the sintering and phase transformation of particles more easily.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.879-880
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• 2006

Effect of phase transformation and grain-size variation of hot-pressed cobalt on its dry sliding wear was investigated. The sliding wear test was carried out against glass (83% $SiO_2$) beads at 100N load using a pin-on-disk wear tester. Worn surfaces, cross sections, and wear debris were examined by an SEM. Phases of the specimen and wear debris were identified by an XRD. Thermal transformation of the cobalt from the hcp $\varepsilon$ phase to the $\gamma$ (fcc) phase during the wear was detected, which was deduced as the wear mechanism of the sintered cobalt.