• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.2
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• pp.205-214
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• 1999

The objective of this paper is to investigate the thermal properties of TMA clathrate compound applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are performed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of density, temperature of heat source and charging quantity in TMA clathrate compound. The results are summarized as follows:1) $-15^{\circ}C$ is not proper as the temperature of heat source because the temperature of subcooling is above $8.3^{\circ}C$ 2) temperature of phase change is dropped as the temperature of heat source is lower, 3) the effect of subcooling suppression with about 8$^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 26, 27, and 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 26 and 30wt%. Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$. Thus, it is concluded that TMA clathrate compound has enough thermal properties as the cold storage medium for building air-conditioning.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.8
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• pp.725-734
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• 2000

The objective of this paper is to investigate the thermal properties of TMA clathrate applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are peformed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of concentrations and temperature of heat source in TMA clathrate. The results are summarized as follows; 1) temperature of phase change is dropped as the temperature of heat source is lower, 2) the effect of subcooling suppression with about $9.3^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 29wt% and 30wt% . Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$ Thus, it is concluded that TMA clathrate has proper properties as the cold storage medium for building air-conditioning.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.2
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• pp.86-90
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• 2017

This work reports the phase-change behavior and thermal stability of doped GeSbTe/GeSbTe bilayers. We prepared the bilayers using RF sputtering, and annealed them at annealing temperature ranging from $100^{\circ}C$ to $400^{\circ}C$. The sheet resistance of the bilayer decreased and saturated with increasing annealing temperature, and the saturated value was close to that of pure GeSbTe film. The surface of the bilayer roughened at $400^{\circ}C$, which corresponds to the surface roughening of doped GeSbTe film. Mixed phases of face-centered cubic and hexagonal close-packed crystalline structures were identified in the bilayers annealed at elevated temperature. These results indicate that the phase-change behavior of the bilayer depends on the concurrent phase-transitions of the two GeSbTe-based films. The dopants in the doped GeSbTe film were diffused out at annealing temperatures of $300^{\circ}C$ or higher, which implies that the thermal stability of the bilayer should be considered for its application in phase-change electronic devices.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.1 no.2
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• pp.138-145
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• 1989

Experimental and numerical analysis were performed to investigate the heat transfer phenomena during phase change. N-octadecane were used as a phase change material and TRUMP computer code was used as a numerical tool. Also, two quarter segment of cylinder shape was chosen as a vessel to simulate to this research. The major contribution factor on the solidus surface movement was environmental temperature and the effect of roller gap and material initial temperature were insignificant. Experimental and numerical results were generally in good agreement and the effect of the mesh size ($22{\times}22$ and $33{\times}33$) was negligible.

• Journal of the Korean Solar Energy Society
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• v.33 no.3
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• pp.9-16
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• 2013

In this research, the effect of a heating system, which is powered by direct solar energy accumulated in phase change material (PCM) as heat storage material installed on the floor surface, on the cooling load was studied. Cooling load of a test building designed for this research was measured with fan coil unit and factors affecting it were also estimated. Experiments were performed with and without PCM installed on the building floor to understand the effect of the PCM on the cooling load. Additionally, to confirm the experiments results, the prediction calculation formula by average outside temperature and integrated solar radiation was composed using multivariate regression model. The results suggested that the heating system with PCM on the floor surface has the potential to shift electric power peak by radiating heat, stored during the daytime in it, at night, not increasing the total cooling load much.

• Solar Energy
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• v.5 no.2
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• pp.77-83
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• 1985

An analysis is performed to investigate the influence of the buoyancy force and the thickness variation of melting layer in the containment that is filled with phase-change Material surrounding a cylindrical heating tube during melting process. The phase-change material is assumed to be initially solid at its phase-change temperature and the remaining solid at any given time is still at the phase-change temperature and neglecting the effect of heat transfer occuring within the solid. At the start of melting process, the thickness of melting layer is assumed to be a stefan-problem and after the starting process, the change of temperature and velocity is calculated using a two dimensional finite difference method. The governing equations for velocity and temperature are solved by a finite difference method which used SIMPLE (Semi Implicit Method Pressure linked Equations) algorithm. Results are presented for a wide range of Granshof number and in accordance with the time increment and it is founded that two dimensional fluid flow occurred by natural convection decreases the velocity of melting process at the bottom of container. The larger the radius of heating tube, the higher heat transfer is occurred in the melting layer.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.11
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• pp.1097-1105
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• 2001

The purpose of this study is to investigate the propriety of TMA clathrate as a cold storage medium. Particularly, this is to examine the extent of subcooling improvement when the additives are added to the TMA clathrate, because water used cold storage material has low phase change temperature and subcooling. This study has been analysed and compared with TMA 30 wt% clathrate how phase change temperature, subcooling and specific heat in the various concentrations are changed. This results view to be improved phase change temperature and subcooling of TMA 30 wt% as a cold storage medium, when it had some additive. Additional1y, it is found that the additive must be controlled under available solution limit and study for new additive must be lasted to know its effect.

• Proceedings of the SAREK Conference
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• 2005.11a
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• pp.392-397
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• 2005

This study is investigated the supercooling improvement and the phase change temperature of the TMA clathrate compound including TMA(Tri-Methyl-Amine, ($(CH_3)_3N$) of 25 wt% with additive as a low temperature storage material at $6^{\circ}C$ and $-7^{\circ}C$ of heat source. The additive is ethanol of 0.1, 0.3 wt% and 0.5 wt%. The results showed that as the concentration of ethanol is increased, the phase change temperature, the degree of supercooling and the retention time of liquid phase are decreased. Especially, TMA 25 wt% clathrate compound with ethanol of 0.5wt% has the average of phase change temperature of $3.8^{\circ}C$, degree of supercooling of $0.9^{\circ}C$, $0.8^{\circ}C$ and retention time of liquid phase for 6, 5 minutes at $-6^{\circ}C$, $-7^{\circ}C$ of heat source. From the results of this study, TMA 25wt% clathrate compound with ethanol 0.5wt% showed supercooling repression effect.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.322-322
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• 2016

Phase change memory (PCM) has attracted much attention as one of the most promising candidates for next-generation nonvolatile memory. In that regard, the purposes of the study are to propose reference of effective pulse parameter to control phase switching operation and to invest the effect of nitrogen doped in PCM materials for improved cycling stability and economic energy consumption. Switching operation of PCM is affected by electric pulse parameter and as shown in figure.1 are composed to RT(rising time), ST(setting time), FT(falling time) and the effect of these parameter was precisely investigated. Transmission electron microscope (TEM) was used to confirm fine structure and retention cycle test was conducted to confirm reliability. Finally improvement reliability and economic power consumption in quantitatively are obtainable by optimum pulse parameter and nitrogen doping in GST material. these study is related to the engineering background of other semiconductor industries and it have confirmed to possibility further applications.

• Journal of the Optical Society of Korea
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• v.12 no.4
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• pp.319-325
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• 2008

We propose a phase contrast filter using photopolymer, for the phase contrast projection display. The photopolymer has high photosensitivity such that its optically induced refractive index change has a linear dependency on the illuminating light intensity. We implemented a phase contrast projection display using photopolymer as a phase contrast filter. By controlling the refractive index change of the photopolymer, we successfully convert an input phase image into a high contrast intensity image. We also investigated the effect of the photopolymer illumination condition on the quality of the displayed intensity image. As a projector, we achieved 82% phase to intensity conversion efficiency, which implies that the proposed method can potentially have much higher light efficiency than conventional projection display.