• Title/Summary/Keyword: phase change effect

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Analysis on the Property Modification in Solution-processed SnZnO Through Composition Ratio Controlling (용액 공정으로 제작된 주석-아연 산화물의 조성 변화에 따른 특성 변화 분석)

  • Kim, Dong-Lim;Rim, You-Seung;Jeong, Woong-Hee;Kim, Hyun-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.6
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    • pp.414-419
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    • 2012
  • In this paper, the properties of SnZnO films obtained from solution process with different component fractions were compared. The thermal behavior of the SnZnO solutions showed only a slight change according to the component fraction change. However, the definite changes were revealed at the structural properties of the SnZnO films. With diverse analyses, the origin of the changes was proved to the influence of phase change from $SnO_2$ to ZnO in SnZnO lattice. With the $SnO_2$-phase-dominant SnZnO, the highest field effect mobility and on/off ratio of about 8.6 $cm^2/Vs$ and $2{\times}10^8$ were achieved, respectively.

A Reaserch on the Performance Verification of Energy Storage Mortar Enhanced in Thermal Efficiency and Strength by Applying Microencapsulated Phase Change Materials and Nanomaterials (마이크로캡슐로 코팅한 상변화 물질과 나노소재를 적용한 고효율 열저장 시멘트 복합체 성능 검증 연구)

  • Ahn, Jun Hyuk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.4
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    • pp.433-441
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    • 2024
  • This study aims to prevent freezing of existing domestic buildings by developing an energy storage mortar with increased energy efficiency that can reduce the increase in carbon emissions and maintenance costs due to external energy use due to heat wires in civil engineering and buildings with embedded heat wires. I suggest. Research has focused on incorporating phase change materials (PCMs) into common cement composites to provide latent heat performance. However, concrete mixed with phase change materials shows problems such as leakage of phase change materials, decreased strength, and insufficient thermal performance. To overcome this problem, we encapsulate phase change materials using microcapsules and mix them into cement composites to minimize strength loss and leakage, and use multi-walled carbon nanotubes and silica fume to minimize the strength reduction of concrete. A heat storage cement composite was developed. When high-efficiency heat storage cement was used as a replacement for ordinary cement composite in an environment where heat wires were buried, the effect was shown to reduce energy by about 42 %, and compared to a cement composite containing only PCM, the compressive strength and bending strength were 18 % and 23 %, respectively. was improved and its effectiveness was proven.

Analysis of Wall-Thinning Effects Caused by Power Uprates in the Secondary System of a Nuclear Power Plant (원전 2차계통의 출력증강 운전에 따른 배관감육 영향 분석)

  • Yun, Hun;Hwang, Kyeongmo;Lee, Hyoseoung;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • v.15 no.3
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    • pp.135-140
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    • 2016
  • Piping and equipment are degraded by flow-accelerated corrosion (FAC) in nuclear power plants. FAC causes numerous problems and nuclear utilities maintain programs to control FAC. The key parameters influencing FAC are hydrodynamic conditions, water chemistry, and effect of materials. Recently, a nuclear utility has planned slight power uprates in Korea. Operating conditions need to be changed in the secondary system according to power uprates. This study analyzed the effect of wall-thinning caused by power uprates. The change of operation data in the secondary cycle is reviewed, and wall-thinning rates are analyzed in the main lines. As a result, two phase (mixture of water and steam) lines have a greater impact than a water line under power uprate conditions. Also, the quality of steam is the most important factor for FAC in two phase lines.

Sintering Behavior, Dielectric and Pyroelectric Properties of $(Pb, La)TiO_3$ Ceramics ($(Pb, La)TiO_3$ 세라믹스의 소결 거동 및 유전.초전 특성)

  • 최동구;최시경
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.841-848
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    • 1994
  • The sintering behavior of La-modified PbTiO3 ceramics was investigated in order to improve the poor sinterability of PbTiO3. Addition of La improved the sinterability. It was confirmed that this improvement was due to the decrease in tetragonality ratio c/a of crystal lattice. The variations of dielectric constant and pyroelectric coefficient were measured with temperature. It was observed that with the increase of La content, Curie temperature decreased and dielectric constant at room temperature increased. La-modified PbTiO3 ceramics had smaller pyroelectric figure of merits than those of pyroelectric materials in use. The effects of grain size on dielectric and pyroelectric properties were also investigated. The change of grain size had effect on maximum dielectric constant and pyroelectric coefficient, but is had little effect on pyroelectric figure of merit at room temperature. The closer examination near ferro-paraelectric phase transition temperature revealed that the behavior of phase transition approached a more relaxor character with the increase of La content and the decrease of grain size.

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The Grain Size Control of A356 Aluminum Alloy by Electromagnetic Stirring (수평식 전자교반을 이용한 A356 합금의 결정립 제어)

  • Ko J. H.;Seo P. K.;Choi W. S.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.111-114
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    • 2004
  • It is many devices to obtain the globular structure because the globularity of the structure is the key to the low apparent viscosity and also to good rheological properties. In this study, the morphology of the change of primary Al phase in A356 alloy by electro magnetic stirrer was investigated to obtain the globular structure. The parameters are the current, stirring time, pouring temperature individually. The greater current and longer stirring time was to get the finer the primary however in case of over the 80A of current and 60sec of stirring time, the primary Al was merged together and was increased. The effect of pouring temperature has an important effect on the size of primary phase. About the $675^{\circ}C$, the primary Al was very fined.

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The Natural Frequency of a Coaxial Cylindrical Shell with Fluid Coupling (유체 연성이 작용하는 동축 원통형 쉘의 고유진동)

  • 안병준;정경훈;이성철
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1994.10a
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    • pp.975-979
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    • 1994
  • The experimental and finite element studies of a coaxial cylindrical shell filled with liquid in the annular gap were performed to understand its vibration characteristics. Finite element analysis was achieved by using ANSYS code. Form the investigation of the changing trend of natural frequencies for the change of annular gap we know that the natural frequency of the coaxial cylindrical shell varies according to the mode shape. that is, in case of in-phase mode the natural frequency decrease as annular gap increase, but in case of out-of-phase mode the natural frequency increase. Finite element analysis results show the excellent agreement with the experimental results both in air and in water case, so that analysis on other cases with be possible without experiment.

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An Investigation on Flow Stability with Damping of Flow Oscillations in CANDU-6 heat Transport System (CANDU-6 열수송 계통의 유동 진동감쇠에 의한 유동안정성 연구)

  • 김태한;심우건;한상구;정종식;김선철
    • Journal of KSNVE
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    • v.6 no.2
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    • pp.163-177
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    • 1996
  • An investigation on thermohydraulic stability of flow oscillations in the CANada Deuterium Uranium-600(CANDU-6) heat transport system has been conducted. Flow oscillations in reactor coolant loops, comprising two heat sources and two heat sinks in series, are possibly caused by the response of the pressure to extraction of fluid in two-phase region. This response consists of two contributions, one arising from mass and another from enthalpy change in the two-phase region. The system computer code used in the investigation os SOPHT, which is capable of simulating steady states as well as transients with varying boundary conditions. The model was derived by linearizing and solving one-dimensional, homogeneous single- and two-phase flow conservation equations. The mass, energy and momentum equations with boundary conditions are set up throughout the system in matrix form based on a node-link structure. Loop stability was studied under full power conditions with interconnecting the two compressible two phase regions in the figure-of-eight circuit. The dominant function of the interconnecting pipe is the transfer of mass between the two-phase regions. Parametric survey of loop stability characteristics, i. e., damping ratio and period, has been made as a function of geometrical parameters of the interconnection line such as diameter, length, height and orifice flow coefficient. The stability characteristics with interconnection line has been clarified to provide a simple criterion to be used as a guide in scaling of the pipe.

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Analysis of Thermo Environment Change by Introduction of Indoor Water Space (실내 수공간 도입에 따른 온열 환경 변화 분석)

  • Oh, Sang Mok;Oh, Se Gyu
    • KIEAE Journal
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    • v.12 no.3
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    • pp.53-60
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    • 2012
  • This research is an illustrative research to verify the thermo environmental change created after introduction of indoor pond through abridged model test and simulation analysis. Especially, temperature and comfort level are analyzed by adjusting factors like size of water space, distance length, and location. Summary of the research is as follows. First, the most effective size of water space is 7% of the indoor size, from southern side. Temperature reduction effect is about $1.6^{\circ}C$(5.5%), and for the comfort level, it is found that pmv index increases 8%. Second, based on the simulation of distance length with the sphere, it is more effective as it is close to the surface. If distance length is more than 0.5m, there is no effect on reduction of temperature and comfort level of indoor environment. Lastly, for the analysis by location of the introduced water space, simulation is undertaken by dividing the water space (14% of the indoor size) with front, side, rear and center types. Temperature reduction effect is found to be : front type ($-1.53^{\circ}C$), side type ($-0.82^{\circ}C$), rear type ($-0.44^{\circ}C$), center type ($-0.28^{\circ}C$), respectively. The indoor environment change data by introduction of water space, found in this research, is at initial phase, but it is deemed to be a basic data to refer when planning actual water space.

Change of TC Activity Around Korea by Arctic Oscillation Phase (북극진동의 위상에 따른 한국 부근에서의 태풍 활동 변화)

  • Choi, Ki-Seon;Kim, Tae-Ryong
    • Atmosphere
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    • v.20 no.4
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    • pp.387-398
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    • 2010
  • This study shows that frequency of tropical cyclone (TC) around Korea in summer (June-September) has positive relation with Arctic Oscillation (AO) in the preceding April. In a positive AO phase, each of anomalous cyclone and anomalous anticyclone is developed in low latitude and middle latitude regions of East Asia from the preceding April to summer. As a result, while anomalous southeasterly around Korea serves as a steering flow that TCs move toward this area is strengthened, northwesterly that reinforced in southeastern area of East Asia plays a role in preventing TCs from moving toward this area. In addition, due to this distribution of pressure systems developed in this AO phase, TCs tend to occur, move and recurve in further northeastern region in the western North Pacific than TCs in a negative AO phase. On the contrary, TCs in a negative AO phase mainly move westward toward southern China or Indochina Peninsula from Philippines. Eventually, intensity of TCs is weaker than those in a positive AO phase due to the terrain effect caused by high passage frequency of TCs in mainland China.

Determination of Co(II) Ion as a 4-(2-Thiazolylazo)resorcinol or 5-Methyl-4-(2-thiazolylazo)resorcinol Chelate by Reversed-Phase Capillary High-Performance Liquid Chromatography

  • Chung, Yong-Soon;Chung, Won-Seog
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1781-1784
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    • 2003
  • Determination of Co(II) ion as a 4-(2-thiazolylazo)resorcinol(TAR) or 5-methyl-4-(2-thiazolylazo)resorcinol(5MTAR) chelate was accomplished by reversed-phase capillary high-performance liquid chromatography (RP-Capillary-HPLC) using a Vydac $C_4$ column and MeCN-water mixture as mobile phase. The effect of change in pH and MeCN percentage of the mobile phase on the retention factor, k and peak intensity were evaluated. It was found that 30% MeCN (v/v) of pH 5.60 or 7.20 was adequate as mobile phase when TAR or 5MTAR is used. Detection limit (D.L., S/N=3) in each case was $2.0\;{\times}\;10^{-7}$M (11.8 ppb) and $3.0\;{\times}\;10^{-7}$ M (17.7 ppb). The Co(II) ion in mineral and waste water was determined with the optimum column and mobile phase.