• Journal of the Korean Chemical Society
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• v.20 no.2
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• pp.118-128
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• 1976

The significant structure theory of liquids and the Bragg-Williams approximation of phase transition theory have been applied to the calculation of the thermodynamic properties of p-azoxyanisole which exhibits a liquid crystal phase of the nematic type. The isotropic phase was treated as a normal liquid; and for the nematic phase, in addition to its liquidity, the effect due to the arrangement of molecular-dipoles was considered. The liquidity of the p-azoxyanisole was described by the significant structure theory of liquids, and the Bragg-Williams approximation was used to consider the effect due to the arrangement of molecular-dipoles. The molar volume, vapor pressure, heat capacity at constant pressure, thermal expansion coefficient, compressibility, entropy and enthalpy change at the nematic-isotropic phase transition point, absolute entropy, and absolute Helmholtz free energy were calculated over the temperature range of the nematic and isotropic phases. The calculated results of the thermodynamic properties were compared with the experimental data.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.6
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• pp.324-330
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• 2013

The main objective of this work is to experimentally investigate the effect of inlet geometries on the distribution of two-phase annular flow at header-channel junctions simulating the corresponding parts of compact heat exchangers. The cross-section of the header and the channels were fixed to $16mm{\times}16mm$ and $12mm{\times}1.8mm$, respectively. Experiments were performed for the mass flux and the mass quality ranges of $30{\sim}140kg/m^2s$ and 0.3~0.7, respectively. Air and water were used as the test fluids. Three different inlet geometries of the header were tested:no restriction (case A), a single 8 mm hole at the center (case B), and nine 2 mm holes around the center (case C) at the inlet, respectively. The tendencies of the two-phase flow distribution were different, in each case. For cases B and C (flow resistance exists), more uniform flow distribution results were seen, compared with case A(no flow resistance), due to the flow pattern change to mist flow from annular flow at the inlet, and the flow recirculation near the end plate of the header.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.7
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• pp.956-962
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• 2003

The Lippmann-Young equation has been widely used in electrowetting to predict the contact-angle change of a droplet on a insulating substrate with respect to the externally-applied electrical voltage. The Lippmann-Young equation is derived by assuming a droplet as a perfect conductor, so that the effect of the electrical double layer and the line tension are not taken into account. The validity of the assumption has never been checked before, systematically. In the present investigation, a modified Lippmann-Young equation is derived taking into account of the effect of the electrical double layer and the line tension. To assess their influence on contact-angle change in electrowetting, the electrostatic field around the three-phase contact line is analyzed by solving the Poisson-Boltzmann equation numerically. The validity of the numerical methods is verified by using the past theoretical results on the electrostatic field around a wedge-shaped geometry, which shows fairly good agreement. The results of the present investigation clearly indicate that the effect of the electrical double layer and the line tension is negligible for a millimeter-sized droplet. On the other hand, for a micron-sized droplet, the effect of the line tension can become a dominating factor which controls the contact-angle change in electrowetting.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.17 no.4
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• pp.451-458
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• 2004

The study was focused on the development of computational scheme in three dimensional configurations by applying effective heat capacity model to the numerical procedure in order to predict the temperature profiles of a buried pipeline and the frozen penetration depth(FPD) of a freezing soil medium. To realize this, the investigator conducted the unsteady state heat transfer analysis, using the commercial code ABAQUS, for the freezing granite soil medium including a pipeline in a closed system. The proposed model took into consideration the phase change effect of in situ pore water in the frozen fringe. The comparison of results obtained by the proposed model and the actual performances was valuable in establishing a level of confidence in the application of introduced theory.

• Journal of Magnetics
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• v.7 no.4
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• pp.160-164
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• 2002

A new discovery of the super-giant magneto-impedance (SGMI) effect was found out in a LC-resonator consisted of a glass-coated amorphous $CO_{83.2}B_{3.3}Si_{5.9}Mn_{7.6}$ microwire. The measurement was carried out at high frequency range from 100 MHz up to 1 GHz of an ac-current flowing along the wire and at varying axial dcmagnetic field in its range of $\pm$120 Oe. The wires, about 16${\mu}m$ in diameter, were fabricated by a glass-coated melt spinning technique. The shape of the impedance curves plotted vs. a dc-field is changing dramatically with the frequency. The phase angle was also strongly dependent on this field. The external dc-magnetic field changes the circumferential permeability as well as the penetration depth, both in turn change the impedance of the sample. The drastic increments of SGMI at high frequency can be understood in terms of the LC-resonance phenomena. The sudden change of the phase angle, as large as $180^{\circ}$ evidenced the occurrence of the resonance at a given intensity of the external dc-field. The maximum ratio of SGMI reached in the experiment by precise tuning frequency equals 450,000％ at the frequency of around 551.9075 MHz.

• Geomechanics and Engineering
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• v.24 no.6
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• pp.531-543
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• 2021

Freezing and thawing of pore water within backfill can affect the stability of retaining wall as the phase change of pore water causes changes in the mechanical characteristics of backfill material. In this study, the effects of freezing and thawing on the mechanical performance of retaining wall with granular backfill were investigated for various temperature and groundwater level (GWL) conditions. The thermal and mechanical finite element analyses were performed by assigning the coefficient of lateral earth pressure according to phase change of soil for at-rest, active and passive stress states. For the at-rest condition, the mobilized lateral stress and overturning moment changed markedly during freezing and thawing. Active-state displacements for the thawed condition were larger than for the unfrozen condition whereas the effect of freezing and thawing was small for the passive condition. GWL affected significantly the lateral force and overturning moment (Mo) acting on the wall during freezing and thawing, indicating that the reduction of safety margin and wall collapse due to freezing and thawing can occur in sudden, unexpected patterns. The beneficial effect of an insulation layer between the retaining wall and the backfill in reducing the heat conduction from the wall face was also investigated and presented.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.7
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• pp.958-966
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• 2001

This study has examined the microstructural development in the Bridgman type directional solidification of hyper-peritectic Sn-Cd alloys, and the temperature and flow field have been numerically simulated to see if there is any change induced by convection. The directional solidification experiments carried out in quartz tubes with inside diameters of 0.4∼6mm showed that the resulting microstructures are clearly dependent on the size of tube diameters. The bigger ampoules where the effect of convection is highly expected produced saw-like structures resulting from the primary $\alpha$ and peritectic $\beta$ phase growing together at a planar solid-liquid front, with the former being surrounded by the latter. In the smaller ampoules, where the effect of convection is expected low however, the saw structure disappears, and as is understood from the theoretical prediction based on diffusion-controlled solidification the initial growth of the primary $\alpha$ phase is replaced by the nucleation of the peritectic $\beta$ phase whose growth continues to the end of the solidification.

• Computers and Concrete
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• v.23 no.4
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• pp.281-294
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• 2019

The post-fire behavior of structural elements and the cooling process has always been one of the main concerns of the structural engineers. The structures can be cooled at different rates, where they affect the structure's behavior. In the present study, a numerical model has been developed using the Abaqus program to investigate the effect of cooling rate on the post-fire behavior of the CFST column. To verify the model, results of an experimental study performed on CFST columns within a full heating and cooling cycle have been used. In this model, coMParison of the residual strength has been employed in order to examine the behavior of CFST column under different cooling rates. Furthermore, a parametric study was carried out on the strength of steel and concrete, the height of the specimens, the axial load ratio and the cross-sectional shape of the specimen through the proposed model. It was observed that the cooling rate affects the behavior of the column after the fire, and thus the higher the specimen's temperature is, the more effect it has on the behavior. It was also noticed that water cooling had slightly more residual strength than natural cooling. Furthermore, it was recognized from the parametric study, that by increasing the strength of steel and concrete and the load ratio, as well as modifying the cross-sectional shape from circular to square, residual strength of column at the cooling phase was less than that of the heating phase. In addition, with reducing column height, no change was witnessed in the column behavior after the cooling phase.

• Journal of the Korean Applied Science and Technology
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• v.39 no.5
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• pp.720-726
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• 2022

The behavior changes of the lipid bilayer, induced by the hydroxybutyric-acid incorporation, were investigated with respect to each phase of the layer using fluorescence intensity change. Spherical phospholipid bilayers, called vesicles, were prepared using an emulsion technique. Only in the aqueous inside of the vesicles was encapsulated 8-Aminonaphthalene-1,3,6-trisulfonic-acid-disodium-salt(ANTS). p-Xylene-bis-N-pyridinium-bromide(DPX) was included as a quencher only outside of the vesicles. The fluorescence scale was calibrated with the ANTS-encapsulated vesicles in DPX-dispersed-buffer taken as 100% and the mixture of ANTS and DPX in the buffer as 0%. Hydroxybutyric-acid addition into the vesicle solution led the change in the bilayer. The change was found to be related to the phase of each layer according to the ratio of hydroxybutyric-acid to lipid. These results seem to depend on the stability of the vesicles, due to the osmotic and volumetric effects on the arrangement in both head-group and tail-group.

• Journal of the Korean Vacuum Society
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• v.8 no.4B
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• pp.524-529
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• 1999

We deposited diamond phase carbon thin films on Si substrate by the electrolysis of methanol solution. A little amount of ammonia solution was added to increase the current density of the electrolyte. We analyzed films by XRD and SEM. The chemical change of electrolyte during the electrolysis process was characterized by FTIR. We obtained better quality diamond phase carbon films at a lower applying boltage(300V) and temperature ($40^{\circ}C$) by adding ammonia solution to methanol electrolyte. Diamond (111), (220), (311) peaks were shown distinctively in XRD graph. Addition of ammonia solution resulted in lowering the applying bias voltage to 300V and the substrate temperature to $40^{\circ}C$ still maintaining a high current density at 80mA/$\textrm{cm}^2$, which prohibited a great loss of solution from vaporization. Possible change of chemical reaction due to the addition of ammonia solution was also discussed.