• 제목/요약/키워드: phase behavior

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Elasto-Plastic Finite Element Analysis in Consideration of Phase Transformations (상변태를 고려한 탄소성 유한요소 해석)

  • Lee, M.G.;Kim, S.J.;Jeong, W.C.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.334-336
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    • 2009
  • An elastic-plasticity model during the austenitic decomposition was derived and implemented to incorporate the two important deformation behaviors observed during the phase transformations: the volumetric strain and transformation induced plasticity due to the temperature change and phase transformation. To obtain transformed phase volume fractions during cooling, the fourth order Runge-Kutta method was used to solve the Kirkaldy's phase kinetics model which is function of temperature, austenitic grain size and chemical composition. The volumetric strain was calculated by considering the densities of constituent phases, while the transformation induced plasticity was based on the micro-plasticity due to the volume mismatch between soft austenitic phase and other harder phases. The constitutive equations were implemented into the implicit finite element software and a simple boundary value problem was chosen as a model problem to validate the effect of transformation plasticity on the deformation behavior of steel under cooling from high temperature. It was preliminary concluded that the transformation plasticity plays a critical role in relaxing the developed stress during forming and thus reducing the magnitude of springback.

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A study on the Microstructure and Mechanical Properties of Two-Phase (($NiAl+Ni_3Al$) 2상 합금의 미세 조직과 기계적 특성에 관한 연구)

  • Lee, Jong-Hun;Choe, Byeong-Hak;Lee, Nam-Jin;Kim, Hak-Min;Lee, Jin-Hyeong
    • 연구논문집
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    • s.24
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    • pp.161-174
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    • 1994
  • The Ni-Al intermetallic compound that has the greatest potential to be commercialized shows the high ductility at room temperature with the addition of boron, but has extremely low ductility at high temperature and oxidation environment. On this research work, the changes of microstructure and compressive fracture properties were studied in ($NiAl+Ni_3Al$) two-phase alloys. The precipitation behavior of $Ni_3Al$ after solution treatment at $1300^\circC$ for 14hrs and aging treatment at $800^{\circ}C$ for 14hrs was varied with Al content in ($NiAl+Ni_3Al$) two-phase alloys. These microstructure could be modified dramatically by suitable heat treatments. Martensite or martensite plus $Ni_3Al$ microstructure was obtained upon oil quenching from $1300^\circC$. Aging of Martensite at $800^\circC$ resulted in the $Ni_3Al$ plus NiAl phase. The compressive fracture strength and compressive fracture strain were improved by the $Ni_3Al$ plus NiAl phase mixtures at room temperature and $1100^\circC$. Microcracks are observed mostly in the region of NiAl and the interface of $NiAl-Ni_3Al$ phase after compressive test at room temperature. In the case of high temperature compressive test, microcracks are formed in the region of $Ni_3Al$ phase.

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Wet preparation of calcium phosphates from aqueous solutions

  • Lee, Byeong Woo;Hong, Il Gok
    • Journal of Ceramic Processing Research
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    • v.20 no.6
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    • pp.655-659
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    • 2019
  • Calcium phosphates such as HA (hydroxyapatite), β-TCP (tricalcium phosphate) and biphasic HA/β-TCP, were synthesized by wet chemical precipitation in aqueous solution combined with ball milling process. Nanosize powders of the calcium phosphates were synthesized using Ca(OH)2 and H3PO4. The effects of initial precursor Ca/P ratio (1.30, 1.50 and 1.67), ball milling process and post heat-treatment on the phase evolution behavior of the powders were investigated. The phase of resulting powder was controllable by adjusting the initial Ca/P ratio. HA was the only phase for as-prepared powders in both cases of Ca/P ratios of 1.50 and 1.67. The single HA phase without any noticeable second phase was obtained for the initial Ca/P ratio of 1.67 in the overall heat-treatment range. Pure β-TCP and biphasic calcium phosphate (HA/β-TCP) were synthesized from precursor solutions having Ca/P molar ratios of 1.30 and 1.50, respectively, after having been heat-treated above 700 ℃. The β-TCP phase has appeared on the pre-existing DCPD (dicalcium phosphate dihydrate) and/or HA phase. Dense ceramics having translucency were obtained at a considerably lower sintering temperature. The modified process offered a fast, convenient and economical route for the synthesis of calcium phosphates.

Experimental study on single- and two-phase flow behaviors within porous particle beds

  • Jong Seok Oh;Sang Mo An;Hwan Yeol Kim;Dong Eok Kim
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.1105-1117
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    • 2023
  • In this study, the pressure drop behavior of single- and two-phase flows of air and water through the porous beds filled with uniform and non-uniform sized spherical particles was examined. The pressure drop data in the single-phase flow experiments for the uniform particle beds agreed well with the original Ergun correlation. The results from the two-phase flow experiments were analyzed using numerical results based on three types of previous models. In the experiments for the uniform particle beds, the data on the two-phase pressure drop clearly showed the effect of the flow regime transition with a variation in the gas flow rate under stagnant liquid condition. The numerical analyses indicated that the predictability of the previous models for the experimental data relied mainly on the sub-models of the flow regime transitions and interfacial drag. In the experiments for the non-uniform particle beds, the two-phase pressure loss could be predicted well with numerical calculations based on the effective particle diameter. However, the previous models failed to accurately predict the counter-current flooding limit observed in the experiments. Finally, we propose a relation of falling liquid velocity into the particle bed by gravity to appropriately simulate the CCFL phenomenon.

Assessment of MARS-KS prediction capability for natural circulation flow in passive heat removal system

  • Jehee Lee;Youngjae Park;Seong-Su Jeon;Ju-Yeop Park;Hyoung Kyu Cho
    • Nuclear Engineering and Technology
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    • v.56 no.8
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    • pp.3435-3449
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    • 2024
  • Considering that system analysis codes are used for the evaluation of the performance of Passive Safety Systems (PSSs), it is important to investigate the capability of the system analysis code to reliably predict the heat transfer and natural circulation flow, which are the main phenomena governing the performance of a PSS. Since MARS-KS has been widely validated for heat transfer models, this study focuses on evaluating its capability to predict the single and two-phase pressure drops and natural circulation flow. The straight pipe simulation results indicate that the pressure drop predictions are reliable within ±5 % error margin for the single-phase flow and the errors of pressure drop up to - 30 % for the two-phase flow. Through single-phase natural circulation flow analysis, it is concluded that the use of the appropriate K-factor modeling based on the flow regimes is important since the natural circulation flow rate in MARS-KS is mainly affected by the form loss factor modeling. With two-phase natural circulation flow analysis, this study emphasizes the behavior of the system could change significantly depending on the two-phase wall friction and pressure loss modeling. With the analysis results, modeling considerations for the PSS performance evaluation with the system analysis codes are proposed.

PHASE TRANSITIONS AND ELECTROCHEMICAL CORROSION BEHAVIORS OF Ti50Ni50-xCux SHAPE MEMORY ALLOYS FOR METALLIC BIOMATERIALS

  • KWANGMIN LEE;SANGHYUN RHO
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1303-1306
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    • 2020
  • TiNi alloys have excellent shape memory properties and corrosion resistance as well as high biocompatibility. This study investigated the effects of copper addition on the phase transitions and electrochemical corrosion behaviors of Ti50Ni50-xCux alloys. TiNi, Ti50Ni47Cu3, Ti50Ni44Cu6, and Ti50Ni41Cu9 alloys were prepared using vacuum arc remelting followed by 4 h homogenization at 950℃. Differential scanning calorimetry and X-ray diffraction analyses were conducted. The corrosion behaviors of the alloys were evaluated using potentiodynamic polarization test in Hank's balanced salt solution at a temperature of 36.5 ± 1℃. The TiNi alloy showed phase transitions from the cubic B2 phase to the monoclinic B19' phase when the alloy was thermally cycled. The addition of copper to the TiNi alloy played a major role in stabilizing the orthorhombic B19 phases during the phase transitions of Ti50Ni50-xCux alloys. The shifts in the corrosion potential toward the positive zone and the low corrosion current density were affected by the amount of Cu added. The corrosion resistance of the TiNi alloy increased with increasing copper content.

A convergence analysis of a PLL for a digital recording channel with an adaptive partial response equalizer (적응 부분응답 등화기를 갖는 디지탈 기록 채널의 PLL 수렴 특성 분석)

  • 오대선;양원영;조용수
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.6
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    • pp.45-53
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    • 1996
  • In this paper, the convergence behavior of timing phase when an adaptive partial response equalizer and decision-directed type of a PLL work together in a digital recording channel is described. The phenomena of getting biased in timing phase when the convergence parameter of an adaptive partial response equalizer and timing recovery constant of a PLL are not selected properly is introduced. The phenomena, occurring due to perturbation of timing phase, are analyzed, by computer simulation and the region of ocnvergence for timing phase is discussed. Also, a method to overcome the phenomena using a variable step-size parameter is described.

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Ferroelectric PLZT Thin Films Prepared by Sol-Gel Route (졸-겔법에 의한 PLZT 합성과 강유전성 박막 제조)

  • 오영제;김정기;주기태;현상훈;정형진
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.870-876
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    • 1992
  • Lead lanthanum zirconate titanate (PLZT, 6/65/35) powders, crack-free and dense thin films have been prepared by polymeric sol-gel process. Pyrolysis of the gel, crystallization and optical transmittance behavior of the PLZT thin film onto sapphire substrate have been studied. Esterification occurs during synthesis of PLZT complexation. Crystalline Pb phase was transiently formed near 450$^{\circ}C$. Content of perovskite phase in the films were increased with increasing thickness of film, but the kinetics of formation of perovskite phase in films was slower than that of powders. Transmittance of the films was decreased with increasing the temperature of heat treatment. Ferroelectric hysteresis loop measurements indicated increments of remanent polarization and coercive field for plenty more of perovskite phase.

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Hot Pressing of the Silicon Nitride Based Ceramics and Their Mechanical Behavior

  • Park, D.S.;Lee, S.Y.;Kim, H.D.;Park, W.S.;D.S. Lim;B.D. Han
    • The Korean Journal of Ceramics
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    • v.1 no.1
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    • pp.45-54
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    • 1995
  • Four kinds of silicon nitride based ceramic materials have been hot pressed. Effect of the sintering additives on the phase transformation, microstructural development and mechanical properties was investigated. While sintering under the same condition a big difference among the microstructures of the specimens, they appeared alike if sintered to have a similiar $\alpha$-$\beta$ phase ratio. The specimen of the stoichiometric $\alpha$-$\beta$ sialon composition showed very limited amount of the intergranular glassy phase and a significant degree of the residual stress. It exhibited almost no strength degradation up to $1300^{\circ}C$, and the strength of the specimen degraded more as its composition deviated from the stoichiometry.

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Analytical Proof of Conservation of Power in the LTV Phase Noise Theory for Noisy Oscillators (선형시변 발진기 위상잡음 이론의 전력 보존성의 증명)

  • Jeon, Man-Young
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.4
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    • pp.855-859
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    • 2012
  • This study derives a generalized PSD formula in the LTV phase noise theory for noisy oscillators. The derived formula analytically proves that the LTV phase noise theory can predict the conservation of the power in the noisy oscillation signals. Additionally, the derived formula allows the theory to account for the behavior of the power spectrum over the entire frequency range including the regions around higher harmonics as well as fundamental frequency.