• Title/Summary/Keyword: phase behavior

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A behavioral approach to increase recycling behavior: An examinination of effect of environmental alteration and prompts (환경문제에서의 재활용 행동 증진을 위한 행동분석적 실험 연구 - 환경적 변화와 프롬트의 효과를 중심으로-)

  • 오세진;양병화;현보성;황혜연
    • Hwankyungkyoyuk
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    • v.14 no.1
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    • pp.19-31
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    • 2001
  • This study examined the effect of environmental alteration and prompts on recycling behavior. An A-B-BC with a control condition design was employed. Subjects in this study were college students, professors, and employees at a university building. After a baseline phase, environmental alteration was I effect in the next phase and both environmental alteration and prompts were in effect in the final phase for the control condition. The environmental alteration consisted of providing four separation containers for the paper cups, cans recyclable paper, and the disposable on each floor in the building. The prompts consisted of providing the information about the importance of environmental preservation and how to separate the materials in the appropriate containers using an information board and pamphlets. The dependent variables were (1) the number of cans collected in can container, (2) the number of paper cups collected in cup container, (3) the rate of correct separation of cans, (4) the rate of correct separation of paper cups, and (5) the weight of disposable. The rates of correct separations of cans and paper cups were obtained by calculating the percentage of thenumber of recyclable cans and paper cups in the corresponding containers. The results indicated that environmental alteration had positive effects on all the dependent variables. Also, when the prompts were added to the environmental alteration, the incremental effect of the prompts was demonstrated. The implications and limitations of theses findings were discussed and the direction of future studies was also proposed.

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Effect of Hydrophilic-Lipophilic Balance of Drugs on Their Release Behavior from Amphiphilic Matrix

  • Yoo, Young-Tai;Shin, Hyun-Woo;Nam, Byung-Guk
    • Macromolecular Research
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    • v.11 no.4
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    • pp.283-290
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    • 2003
  • Organic drugs including aspirin, omeprazole, and naproxen with three different levels of octanol/water partition coefficient were examined for their release behavior from the amphiphilic PCL-b-PEO-b-PCL (PCEC) matrix. Scanning electron micrograph (SEM) of PCEC illustrated a well defined two-phase morphology consisted of dispersed poly(ethylene oxide) (PEO) domain and continuous polycaprolactone (PCL) phase. Differential scanning calorimetry (DSC) and X-ray diffractometry (XRD) experiments veri tied that three model drugs are dissolved as a molecular dispersion in PCEC matrix. The release of hydrophilic aspirin closely followed the water absorption profile of the matrix indicating that its major fraction is present in PEO domain. However, substantial amount of aspirin present in less hydrophilic region displayed discontinuous biphasic release pattern. In the case of omeprazole with intermediate hydrophobicity consistent release behavior was observed for a period of 24 hrs after the rapid liberation of ca. 10% of the drug presumably partitioned in PEO phase. It was ascribed to the fact that the progressive hydration of PCEC matrix gradually increased the chance of drug/water exposure to compensate the exhaustion of device. Naproxen with the highest octanol/water distribution coefficient among three model drugs exhibited a limited release of 35% for 24 hrs. Finally, hydroxypropyl methylcellulose phthalate (HPMCP)/PCEC blend matrix demonstrated an accelerated and quantitative release of hydrophobic naproxen by generating high porosity and thereby expanding polymer/water interface.

Analysis of Flow Rate Inducing Voltage Loss in a 100 cm2 Class Molten Carbonate Fuel Cell

  • Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.20-25
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    • 2011
  • This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

The Effect of Ageing on the Transformation Behavior of Ti-50.4at.% Ni Alloy(II) (Ti-50.4at.%Ni합금의 변태거동에 미치는 시효처리의 영향(II))

  • Kim, Sung-Jin;Woo, Heung-Sik;Park, Sung-Bum
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.27-33
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    • 2005
  • The shape memory effect in Ti-50.4at.%Ni alloy after solution treatment at 1273K for 2h and aged at 350, 450, $550^{\circ}C$ for 0.5, 1, 1.5, 2, 4, 10hrs had been investigated by differential scanning calorimetry measurement. It was found that ageing in the temperature range of $350^{\circ}C{\sim}550^{\cric}C$ induced complex transformation behavior, involving the R-phase and multiple-stage martensitic transformation. Usually aged Ni-rich NiTi alloys undergo martensitic transformation on cooling from high temperatures in two step : Austenite to R-phase and then R-phase to Martensite (normal behavior). In sample aged at $350^{\circ}C$ two distinct DSC peaks arised giving evidence of intermediate stages of martensite transformation. This results in the nucleation and growth of coherent $Ni_4Ti_3$-precipitate. These explain all features of the evolution of DSC charts during ageing including the number of distinct DS peaks and their positions.

Effect of MgO on the Viscous Behavior of CaO-SiO2-Al2O3-MgO Welding Flux System (CaO-SiO2-Al2O3-MgO계 용접 플럭스계의 점성에 미치는 MgO의 영향성에 관한 연구)

  • Kim, Hyuk;Jung, Eun Jin;Jeon, Young Duck;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.114-120
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    • 2009
  • The viscosities of $CaO-SiO_2-Al_2O_3-MgO$ flux were measured under the condition of $CaO/SiO_2=1.0-1.3$ and 5-20 wt%MgO. Submerged arc welding flux with $5wt%Al_2O_3$ content had the lowest critical temperature and widest solid-liquid coexisting region at about 5 wt%MgO. It indicateds that both critical temperature and viscosity depend on the kind of primary phase of molten flux. Viscous behavior of the molten flux at 1773 K was analyzed in the view of silicate structure changed by FT-IR spectroscopy. Based on the critical temperature and the behavior of viscosity at a fixed temperature, it could be proposed that the contents of MgO and $Al_2O_3$ in SAW flux show a pronounced effect on preventing contamination in maintaining the liquid phase flux after welding process.

Finite thickness and tow phase shift effects on the mechanical behavior of plain weave textile composites (두께와 위상각의 변화가 평직복합재료 미세구조의 거동에 미치는 영향)

  • 우경식
    • Composites Research
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    • v.13 no.1
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    • pp.11-24
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    • 2000
  • In this paper, finite thickness and tow phase effects on the mechanical behavior were studied numerically for plain weave textile composites. Unit cell analysis based on a superposition method was employed to simulate uniaxial tensile loading condition and macro-element post-processor was used to reduce computer resource requirement. The effective moduli and micro-stress distribution were calculated for finite thick plain weave composites with phase shifts. Single layer and infinitely thick configurations were also considered for comparison.

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Thermal Behavior of Dickite (딕카이트의 열적 특성 연구)

  • 조현구
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.1
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    • pp.11-22
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    • 1999
  • Thermal behavior of dickite was studied by thermal analysis, X-ray diffraction analysis, electron microprobe analysis, and scanning electron microscopy, Dickite has an endothermic peak at about$ 650^{\circ}C$ and an exothermic one at $960^{\circ}C$ in the differential thermal analysis. The endothermic reaction is assigned to the decomposition of dickite to meta-dickite. Hydroxyl radicals are removed from dickite structure by the reaction, resulting in the weight loss about 10.5~14.5% and appearance of a 14$\AA$ phase different from other kaolin minerals. The reaction slowly proceed in the range of $200^{\circ}C$. As the completion of decomposition, aciclular mullite forms at the expense of meta-dickite plates with random crystallographic relationship. Mullites have diverse silica versus alumina ratio. The exothermic reaction without weight loss seems to be due to the formation of spinel and amorphous silica. The spinel phase shows cryptocrystalline globular morphology accompanying a little amount of silica. From spinel phase shows cryptocrystalling globular morphology accompanying a little amount of silica. From this work, it is suggested that mullite is formed from meta-dickite much lower temperature than the reported one in the previous works.

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A Dependability Estimation of Microprocessor-based Software under Memory Faults using Stochastic Activity Network (SAN)

  • Park, Jong-Gyun;Seong, Poong-Hyun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.725-730
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    • 1996
  • In this work, the software behavior under memory faults in operation phase is modeled and simulated using the stochastic activity network, generalized stochastic Petri nets. This networks permit the representation of concurrency, timeliness, fault tolerance, and degradable performance of system and provide a means for determining the stochastic behavior of a complex system. We estimate the reliability of an application software in the digitized system in nuclear power plants and show the sensitivity of the software reliability to the major physical parameters which affect the software failure in normal operation phase. We found that the effects of the hardware faults on the software failure should be considered for predicting the software dependability accurately in operation phase.

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Low Temperature Degradation Behavior for CaO Doped 2.5Y-TZP Ceramics (CaO를 첨가한 2.5Y-TZP 세라믹스의 저온열화 거동)

  • 박정현;이한주;문성환;박한수
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.341-346
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    • 1992
  • The effects of CaO addition on the low temperature degradation behavior of 2.5Y-TZP ceramics were investigated. Y2O3-CaO-ZrO2 ceramics were prepared from the commercial Y-TZP powder added within 1 mol% of CaO. Fully tetragonal phase could be obtained at each composition under sintering condition of 1500$^{\circ}C$ for 1 hour. As the amount of CaO increased, grain size was decreased. From the result of heat treatment at 200$^{\circ}C$, volume fraction of monoclinic phase formed on the surface of each specimen was decreased with higher CaO amount. Stability of tetragonal ZrO2 phase for low temperature heat treatment was increased by CaO addition without the degradation of mechanical properties.

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Sintering Behavior of 2xxx Series Al alloys with Variation of Sintering Temperature (2xxx Al 합금계 혼합분말의 소결온도에 따른 소결거동)

  • 민경호;김대건;장시영;임태환;김영도
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.40-45
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    • 2003
  • Sintering behavior of 2xxx series Al alloy was investigated to obtain full densification and sound microstructure. The commercial 2xxx series Al alloy powder. AMB2712, was used as a starting powder. The mixing powder was characterized by using particle size analyzer, SEM and XRD. The optimum compacting pressure was 200 MPa, which was the starting point of the "homogeneous deformation" stage. The powder compacts were sintered at $550~630^{\circ}C$ after burn-off process at $400^{\circ}C$. Swelling phenomenon caused by transient liquid phase sintering was observed below $590^{\circ}C$ of sintering temperature. At $610^{\circ}C$, sintering density was increased by effect of remained liquid phase. Further densification was not observed above $610^{\circ}C$. Therefore, it was determined that the optimum sintering temperature of AMB2712 powder was $610^{\circ}C$.}C$.