• Title/Summary/Keyword: petroleum oil

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Adsorption Treatment of Petroleum Oil on Aqueous Phase (수용액중에 함유된 석유화합물들의 흡착처리에 관한 연구)

  • Lee, T.H.;Son, B.C.;Lee, S.B.;Kim, l.H.
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.1-5
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    • 1992
  • The adsorption amount of petroleum oil on XAD-4, XAD-7 and replacement adsorbents as rice bran, rice straw and sawdust were studied by using batch method measured in the optimum adsorption condition. The adsorption capacity of rice bran and rice straw of petroleum oil were excellent as well as adsorption ability about 50% of XAD resins and adsorption capacity of their replacement adsorbents were increased with optimum condition that pyrolysis time was 30 min. at $200^{\circ}C$. Adsorption ability of sawdust was very weak on the 30% MeOH aqueous medium but adsorption ability was range of about 50% of XAD resin's adsorption capacity on the 0.5M NaCl aqueous medium. Adsorption ability of rice bran and rice straw showed the same adsorption capacity even if difference external structure. Therefore, showing that rice bran and rice straw were have to good adsorption ability as replacement adsorbent for XAD resins.

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Quantitative Analysis of Fuel in Engine Oil (엔진오일 내 연료성분 정량분석)

  • Lim, Young-Kwan;Kim, Jiyeon;Na, Yong-Gyu;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.714-719
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    • 2017
  • The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

Treatment of Oil Contaminated Groundwater Using DAF and Fenton Oxidation Process (DAF와 펜톤 산화 공정을 이용한 유류 오염 지하수 처리)

  • Lee, Chaeyoung
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.10
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    • pp.49-55
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    • 2010
  • The oil spill occurred frequently due to probably the increased consumption of oil as the energy source and the raw materials of various chemicals. For the treatment of oil contaminated groundwater, DAF(Dissolved Air Flotation) is being used but the removal efficiency is low. Therefore it is necessary to reduce the free phase oil, oil-in water type or water-in oil type emulsified oil, and soluble oil which are the main sources of contaminated groundwater. In this study, treatment of contaminated groundwater was performed using the Fenton oxidation process. The optimum conditions for the removal of THP(Total Petroleum Hydrocarbon) were 3 of pH, 25mM of $H_2O_2$ concentration and 25mM of $Fe^{2+}$ concentration. THP and COD(Chemical Oxygen Demand) concentrations decreased less than 1.5mg/L and 40.0mg/L in 7 minutes using DAF and Fenton oxidation process. However it is necessary to install the settling basin as the sludge concentration increased approximately 5 times.

The Interpretation of Petroleum Species from Contaminated Soil by Complex Oil (복합유류 토양오염에 따른 유종 해석)

  • Lim, Young-Kwan;Kim, Ji-Yeon;Kim, Wan-Sik;Lee, Jeong-Min
    • Journal of Soil and Groundwater Environment
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    • v.24 no.1
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    • pp.17-23
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    • 2019
  • Clean soil environment is of crucial importance to sustain lives of ecosystem and humans. With rapid industrialization, there has been a great increase of soil contamination by accidental releases of petroleum products. In general, soil remediation is an expensive and time-consuming process as compared to cleanup of water and air. Moreover, determining the source and responsible parties of soil pollution often turns into legal conflicts and that further delay the cleanup process of contaminated sites. In practice, total petroleum hydrocarbon (TPH) analysis has been employed to determine the petroleum species and to track down the responsible polluters. However, this approach often suffers from differentiating similar TPH species. In this study, we analyzed TPH chromatogram patterns of 24 domestic petroleum products in specific carbon ranges (${\sim}C_{10}$, $C_{10}-C_{12}$, $C_{12}-C_{36}$, and $C_{36}{\sim}$) and the fractional changes of THP ratio in the mixture products of gasoline, kerosene and diesel. The proposed TPH analysis method in this study could serve as a useful tool to better analyze the petroleum species in soils contaminated with complex oil mixtures, and ultimately be used to identify the polluters of soil.

A Study on the Performance Evaluation and Quality for Power Bio-Fuel Oil (발전용 바이오중유의 품질 및 성능 평가 특성 연구)

  • Ha, Jong-Han;Jang, Eun-Jung;Kwon, Yong-Chai
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.588-598
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    • 2015
  • Recently, the government is actively promoting the RFS(Renewable Fuel Standards) and RPS(Renewable Portfolio Standards). Therefore, the importance of renewable energy fuel is being highlighted more than ever. Now is the time required active research in Korea. Since power bio-fuel oil demonstration project is underway dissemination to meet RPS quota. In this study, we investigated emission performance to make the performance standard draft of bio-fuel oil. In addition, the quality properties of the fuel oil and bio-oil, and after combustion in industrial boilers and compared the amount of exhaust gas. It was reduced emissions of bio-oil in industrial boilers due to bio-fuel properties as compare with fuel oil.

Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

해외석유정보

  • Korea Petroleum Association
    • Korea Petroleum Association Journal
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    • no.5 s.242
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    • pp.95-100
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    • 2004
  • 본란은 해외석유산업에 대한 동향과 정보를 파악하기 위하여 석유협회 홈페이지(www.oil.or.kr)에서 연재중인 석유정보다이제스트 내용을 발췌하여 실은 것이다.

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