• Title/Summary/Keyword: petrochemical study

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Electrospinning of Asiaticoside/2-Hydroxypropyl-β-cyclodextrin Inclusion Complex-loaded Cellulose Acetate Fiber Mats: Release Characteristics and Potential for Use as Wound Dressing (Asiaticoside/2-Hydroxypropyl-β-cyclodextrin 포접화합물 함유 셀룰로오스 아세테이트 섬유 매트의 전기방사: 창상피복제로서 사용가능성과 방출특성)

  • Panichpakdee, Jate;Pavasant, Prasit;Supaphol, Pitt
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.338-350
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    • 2014
  • Cellulose acetate (CA) fiber mats containing inclusion complexes of asiaticoside (AC) in 2-hydroxypropyl-${\beta}$-cyclodextrin ($HP{\beta}CD$) for potential usage as wound dressings were developed. The AC/$HP{\beta}CD$ complex-loaded CA fibers at various $HP{\beta}CD$ to AC molar ratios of 0.5, 1, and 2 were prepared in 90:10 v/v mixture of 80% (v/v) acetic acid and N,N-dimethylacetamide (DMAc) via electrospinning. The maximum released amounts of AC depended on the $HP{\beta}CD$ content and were much greater than those released from the AC-loaded CA fiber mat. In the in vitro study, indirect cytotoxic evaluation with human dermal fibroblasts (HDFa) showed that these materials released no substances in the levels that were harmful to the cells and the cells appeared to attach and proliferate well on these substrates. However, only the CA fiber mats containing AC/$HP{\beta}CD$ complexes at the $HP{\beta}CD$ to AC molar ratio of 0.5 was effective in upregulating the production of collagen of the cultured cells.

A Study on Process Safety Incident Precursors to Prevent Major Process Safety Incidents in the Yeosu Chemical Complex

  • Baek, Seung-Hyun;Kwon, Hyuck-Myun;Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.212-221
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    • 2018
  • Process safety incidents and loss events can be prevented if we identify and adequately take measures on process safety incident precursors in a timely manner. If we look into and take action against the process safety hazard factors causing the incident in the refinery and petrochemical plant, major process safety incidents can be prevented through eliminating or decreasing hazardous factors. We conducted a survey for the major process safety incident precursor to look specifically into the potential process safety hazardous factors of refineries and petrochemical plants in the Yeosu chemical complex. A self-assessment checklist, which was published by Center for Chemical Process Safety "Recognizing catastrophic incident warning signs in the process industry" on major incidents warning sign, was used for the survey. Through this survey, the major process safety incident leading indicators in the process industry were found by process safety management elements, and each site and/or facility can use these leading indicators for activities for process safety incident prevention. In addition, we proposed action items required to eliminate the root cause of those process safety incident leading indicators.

Defect Detection of Steel Wire Rope in Coal Mine Based on Improved YOLOv5 Deep Learning

  • Xiaolei Wang;Zhe Kan
    • Journal of Information Processing Systems
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    • v.19 no.6
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    • pp.745-755
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    • 2023
  • The wire rope is an indispensable production machinery in coal mines. It is the main force-bearing equipment of the underground traction system. Accurate detection of wire rope defects and positions exerts an exceedingly crucial role in safe production. The existing defect detection solutions exhibit some deficiencies pertaining to the flexibility, accuracy and real-time performance of wire rope defect detection. To solve the aforementioned problems, this study utilizes the camera to sample the wire rope before the well entry, and proposes an object based on YOLOv5. The surface small-defect detection model realizes the accurate detection of small defects outside the wire rope. The transfer learning method is also introduced to enhance the model accuracy of small sample training. Herein, the enhanced YOLOv5 algorithm effectively enhances the accuracy of target detection and solves the defect detection problem of wire rope utilized in mine, and somewhat avoids accidents occasioned by wire rope damage. After a large number of experiments, it is revealed that in the task of wire rope defect detection, the average correctness rate and the average accuracy rate of the model are significantly enhanced with those before the modification, and that the detection speed can be maintained at a real-time level.

Human Health Risk Assessment of BTEX from Daesan Petrochemical Industrial Complex (대산 석유화학 산업단지 인근 지역에서의 BTEX 인체 위해성 평가)

  • Lee, Jihyeong;Jang, Yong-Chul;Cheon, Kwangsoo;Kim, Bora
    • Journal of Environmental Impact Assessment
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    • v.31 no.5
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    • pp.321-333
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    • 2022
  • In this study, the concentration and distribution characteristics of BTEX (benzene toluene, ethylbenzene, and xylene) emitted from Daesan Petrochemical Industrial Complex were examined to determine their potential hazards to local residents. Residents living nearby the complex areas may be exposed to the chemicals through various media (air, water, and soil), especially by air. This study evaluated human health risks by inhalation using both deterministic and probabilistic risk assessment approaches. As a result of the deterministic risk assessment, the non-cancer risk was much lower than the regulation limit of hazard index (HI 1.0) for all the points. However, in case of cancer risk evaluation, it was found that the risk of excess cancer for benzene at point A located in the industrial complex was 2.28×10-6, which slightly exceeded the standard regulatory limit of 1.0×10-6. In addition, the probabilistic risk assessment revealed that the percentile exceeding the standard of 1.0×10-6was found to be 45.3%. The sensitivity analysis showed that exposure time (ET) had the greatest impact on the results. Based on the risk assessment study, it implied that ethylbenzene, toluene, and xylene had little adverse effects on potential human exposure, but benzene often exceeded the cancer risk standard (1.0×10-6). Further studies on extensive VOCs monitoring are needed to evaluate the potential risks of industrial complex areas.

A Study for Treatment of Used Electrical Insulating Oil (廢電氣絶緣油 精製法에 관한 연구)

  • Kim, Ju-Hang
    • Tribology and Lubricants
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    • v.1 no.1
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    • pp.59-68
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    • 1985
  • Processes such as vacuum distillation, mixed solvent extraction, neutralization and clay treatment were used to refine an electrical insulating oil, The improved reused oil showed an excellent copper corrosion resistance and gave a better oder than that of oil refined from the conventional acid treatment method.

A Study on the Safety Management of the Petrochemical Complex Area (국가산업단지의 석유화학 안전관리 방안에 관한 연구)

  • Kim, Kug-Rae;Hwang, Sae-Yeon;Kim, Bong-Hoon
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2012.04a
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    • pp.194-197
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    • 2012
  • 울산, 여수 등 대단위 석유화학공장이 가동 중인 국가산업단지에서 화재 폭발 및 누출 등 중대산업사고가 발생되는 주요 원인과 안전관리 실태 등 문제점을 분석하여 이에 대한 제도적 측면 및 안전관리 측면에서 합리적인 대책을 제시해 보고자 한다.

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The Analysis of Chromosome Aberration in Workers Exposed to Low Level Benzene

  • Kim, Yangjee;Cho, Yoon-Hee;Chung, Hai-Won
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.147-147
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    • 2003
  • Human exposure to benzene is derived occupationally from the petrochemical and petroleum refining industries. This study was carried out to find whether the frequencies of chromosome aberrations in workers exposed to low level benzene in a petroleum factory were elevated compared to non-exposed workers.(omitted)

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The Research of Process High Alarm Priority Analysis for Efficient Emergency Response (효율적인 비상대응을 위한 Process High Alarm의 Priority 분석)

  • Kim, Youngse;Cho, Gyusun;Jun, Jinwoo;Kim, Byungjick;Lee, Joonwon;Park, Kyoshik
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.604-609
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    • 2020
  • The purpose of this study is to check the priority control status of the current operation process alarm by comparing the priority of the alarm set up in PV high trip point, which is being installed and operated in the domestic petrochemical industry, with the criteria presented in ISA 18.2 International Standard or EEMUA 191 Guidelines. In the event of a process problem, excessively set high alarm is provided to the driver in a short period of time, making it difficult to identify the alarm that needs to be handled first. As a result, it is likely that the operator will not be able to carry out appropriate actions within the specified time frame, and many cases have been reported leading to unexpected process shutdowns or process accidents. Therefore, this study aims to introduce international standards related to alarm management and identify the level of alarm control used at the domestic petrochemical industry site to inform potential risks that may occur in the petrochemical process of the national industrial complex in the future and suggest ways to reduce risk factors. This paper was submitted to Professor Lee Inbeom's retirement anniversary issue.

Study on the Method of Analyzing the Plasticizer of Petrochemical Products using MD-GC/MS (MD-GC/MS를 활용한 석유화학제품의 가소제(DOA, DOP) 분석방법 연구)

  • Doe, Jin-woo;Youn, Ju-min;Kang, Hyung-kyu;Hwang, In-ha;Ha, Jong-han;Na, Byung-ki
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1085-1093
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    • 2017
  • Plasticizers are materials added to give softness and elasticity to plastics having rigid properties to give soft properties as products, and they are mainly added to high molecular materials to give flexibility to improve workability and to improve cold resistance, resistance to volatility and electrical properties. It is used for the purpose. Most plasticizers are inert liquids, similar in function to solvents but with high molecular weight and no volatility. In addition, when dissolved in petrochemical products, only the plasticizer is separated by the matrix effect with other compounds, and qualitative and quantitative analysis. In this study, qualitative and quantitative analysis of DOA and DOP, which are representative components of petrochemical products, were conducted using MD-GC/MS and developed an optimal plasticizer analysis method.