• Title/Summary/Keyword: permeate improvement

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Ultrafiltration of palm oil mill effluent: Effects of operational pressure and stirring speed on performance and membranes fouling

  • Yunos, Khairul Faezah Md;Mazlan, Nurul Ain;Naim, Mohd Nazli Mohd;Baharuddin, Azhari Samsu;Hassan, Abdul Rahman
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.263-270
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    • 2019
  • Palm oil mill effluent (POME) is the largest pollutant discharged into the rivers of Malaysia. Thus UF membrane study was conducted to investigate the effect of pressure and stirring speed on performance of POME treatment and fouling of membrane. Two types of membrane polyethersulfone (PES) and regenerated cellulose (RC) with molecular weight cut-off (MWCO) 5 and 10 kDa were used in this study. Results showed that, as pressure increased, fouling increased however permeate quality improved, the best pressure was 1.0 bar, where the fouling was not too high and produce good permeate quality. As stirring speed increased, fouling reduced and permeate quality improved, however, when stirring speed increased from 600 rpm to 800 rpm, there was no significant improvement on the permeate quality. Therefore, the best condition was at 1.0 bar and 600 rpm. PES membrane with MWCO 5 kDa showed the best permeate quality, even fouling slightly higher than RC membrane. The permeate quality obtained were analyzed in term of dissolved solid, turbidity, suspended solid, biological oxygen demand ($BOD_5$) and chemical oxygen demand (COD) were 538 mg/L, 1.02 NTU, < 25 mg/L, 27.7 mg/L and 62.8 mg/L, respectively with dominant type of fouling is cake resistance. Thus, it can be concluded water reuse standard was successfully achieved in terms of $BOD_5$ and suspended solid.

Experimental Study on the Backflushing for Ultrafiltration Treatment of Alkaline Cleaner Containing Cutting Oils (오일 함유 세척수의 한외여과 처리에서의 역세척에 관한 실험연구)

  • 김종표;정명석;김재진;정건용;전성덕
    • Membrane Journal
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    • v.8 no.2
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    • pp.94-101
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    • 1998
  • The oil separation is effectively performed from the oil containing alkaline cleaner solution by using a backflushed ultrafiltration system, where hollow fibers commercially made by polyacrylonitrile copolymer are bundled. Backflushing to reduce membrane fouling during crossflow ultrafiltration is investigated. Experimental observations allow us to understand the behavior of permeate flux according to the relative operating conditions, and determine the optimum condition of normal operation and backflushing. The maximum improvement of net permeate flux owing to backflushing was found to be about 23 % with the condition of 10 min/40 sec for the cycle of normal/backflushing operations. Note that, however, the maintenance of stable permeate flux is lost as the duration of normal operation is increased. The permeate flux depends on both the backflushing pressure and the feed flow rate. It is obvious that there is a critical velocity of feed flow, in which permeate flux is practically independent of backflushing pressure. Above this critical value, the permeate flux is proportional to an appropriate power of the backflushing pressure, $\Delta P_{back}^n$, where exponent n is enhanced with increasing feed velocity.

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Permeation Characteristics of the Plate & Frame Membrane Module with Protuberances (돌기형 평판 분리막 모듈의 투과특성)

  • Chung, Kun-Yong;Jeon, Sung-Il
    • Membrane Journal
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    • v.18 no.2
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    • pp.168-175
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    • 2008
  • This study was carried out for the plate and frame membrane modules equipped with and without plastic protuberances on the support frame in order to determine the effect of eddy flow induced by the protuberances on permeate flux. The initial time for rapidly declined permeate flux on the module with protuberances was delayed twice or more than that on the module without protuberances when kaolin solution was permeated at the operating pressures from 0.4 to 1.6 bar. Also decreasing ratio of the kaolin solution to pure water flux for module with protuberances was 1 to 5% lower than that for module without protuberances. The flux improvement due to protuberances at laminar flow corresponding Reynolds number 1,750 was about double as compared with that in the transition flow region. In general, the kaolin fouling reduction for the plate module with protuberances during initial filtration process was very effective, even though the permeate flux after 60 minutes filtration did not increase significantly.

The Effect of the Variation of Hollow Fiber Diameter and Curvature and Turn Number on Performance for Microfiltration Helical Modules (Microfiltration Helical Module들에서 Hollow Fiber의 Diameter과 Curvature 및 Turn수의 변화에 따른 성능변화에 관한 연구)

  • 이광현
    • Membrane Journal
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    • v.7 no.2
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    • pp.84-94
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    • 1997
  • The performances of both module sets made by different methods for helical module were compared. All experiments were conducted simultaneously at the same transmembrane pressure and energy cosumption per membrane area. The effects of Dean vortices for reducing concentration polarization and fouling were low for the first module set. The increase of 115% for permeate flux improvement(permeate flux difference ${\times}100$/pemeate flux of linear module) was measured. The second module set was more effective in reducing concentration polarization and fouling.

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Application of Coagulation-UF Hybrid Membrane Process for Reuse of Secondary Effluent (하수 2차 처리수 재이용을 위한 hybrid 응집-UF 막분리 공정의 적용)

  • Lee, Chul-Woo;Shon, Jung-Ki;Shon, In-Shik;Han, Seung-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.605-612
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    • 2005
  • The objective of this study was to evaluate the factors affecting the optimization of coagulation hybrid UF membrane processes for the reuse of secondary effluent from sewage treatment plant. The experimental results obtained from the UF membrane process showed that organic colloids in the size range of $0.2{\mu}m{\sim}1.0{\mu}m$ caused the most substantial influence on the fouling of UF membrane. When using a coagulation pretreatment to UF membrane, alum dosage of 50mg/L resulted in the least reduction in membrane permeate flux. Also, for the rapid mixing process, in-line mixer type was more efficient for organic removal than back mixer type. Therefore, it may be concluded that coagulation-UF hybrid membrane process comparing to UF alone process showed not only higher removal efficiency of organic matter, but also substantial improvement of permeate flux of UF membrane.

Clarification of Apple Vinegar by Ultrafiltration and Flux Charcateristics (한외여과를 이용한 사과식초의 청징화와 투과특성)

  • Kim, Soon-Dong;Chung, Ho-Duck;Choi, Yong-Hee;Youn, Kwang-Sup
    • Applied Biological Chemistry
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    • v.43 no.1
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    • pp.24-28
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    • 2000
  • This study was conducted to evaluate the effect of ultrafiltration (UF) process variables on permeate flux and membrane resistance and to clarify apple vinegar for quality improvement. Apple vinegar was clarified in a laboratory ultrafiltration system with hollow fiber membrane made of polysulfone and MWCO 30,000 and 10,000. The permeate flux increased with the increase of flow rate and the optimum pressure was $1.5\;kgf/cm^2$ in this system. The turbidity of clarified apple vinegar treated UF largely decreased. pH and acidity of treated samples showed the same level as those of untreated apple vinegar. The permeate flux continuously declined while the fouling material accumulated on the membrane as the operation time increased. Resistance decreased with lower pressure, which could be explained by expansion of pore size at lower pressure and minor compaction of the polarized layer at lower pressure.

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Pretreatment of Acrylic Wastewater and Application of UF/RO Processes (Acrylic폐수의 전처리 및 UF/RO공저의 적용)

  • 이광현
    • Proceedings of the Membrane Society of Korea Conference
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    • 2001.05a
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    • pp.135-138
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    • 2001
  • Acrylic wastewater flux was discussed using modules of ultrafiltration hollow fiber and reverse osmosis spiral wound. The optimum backflushing times of membranes were decided and the degree of fouling was discussed with operating time. Permeate flux was decreased rapidly at 12hrs. Separation processes with ultrafiltration and reverse osmosis membranes were not suitable to remove COD and TDS. The improvement of pretreatment processes was needed.

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Reactive modification of PVC membranes for the improved performance

  • Jhaveri, Jainesh H.;Patel, Chetan M.;Murthy, Z.V.P.
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.385-392
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    • 2018
  • Poly vinyl chloride (PVC) was chemically modified, and used for ultrafiltration to analyze the performance. Non-solvent induced phase separation (NIPS) method was used to prepare membranes. The neat PVC membrane was casted and used as a control membrane. Modified membrane was prepared by reacting PVC with ethanolamine (EA) in the casting solution (labeled as CM-PVC). Pure water permeability (PWP) was evaluated by measuring pure water flux. Humic acid was used as model foulant solute to analyze flux and rejection ability of membranes. Flux and rejection data of neat and modified membranes were compared to prove the improvement in the filtration performance. The experimental results showed that for PVC and CM-PVC, PWP was calculated to be ~64 and ${\sim}143L/m^2{\cdot}h$, respectively, and the rejection of humic acid was found to be 98% and 100%, respectively. TGA was carried out to analyze the effect of chemical modification on the thermal stability of polymer. FT-IR analysis was another characterization technique used for the comparative study.

Pretreatment Process for Performance Improvement of SIES at Kori Unit 2 in Korea

  • Lee, Sang-Jin;Yang, Ho-Yeon;Shin, Sang-Woon;Song, Myung-Jae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.12-27
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    • 2004
  • Pretreatment process consisted of submerged hollow-fiber microfiltration(HMF) membrane and spiral-wound nanofiltration(SNF) membrane has been developed by NETEC, KHNP for the purpose of improving the impurities of liquid radioactive waste before entering Selective Ion Exchange System(SIES). The lab-scale combined system was installed at Kori NPP #2 nuclear power plant and demonstration tests using actual liquid radioactive waste were carried out to verify the performance of the combined system. The submerged HMF membrane was adopted for removal of suspended solid in liquid radioactive waste and the SNF membrane was used for removal of particulate radioisotope such as, Ag-l10m and oily waste because ion exchange resin can not remove particulate radioisotopes. The liquid waste in Waste Holdup Tank (WHT) was processed with HMF and SNF membrane, and SIES. The initial SS concentration and total activity of actual waste were 38,000ppb and $1.534{\times}10_{-3}{\mu}Ci/cc$, respectively. The SS concentration and total activity of permeate were 30ppb and lower than LLD(Lower Limit of Detection), respectively.

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Fouling Characteristics in the Microfiltration of Mixed Particle Suspensions (혼합입자 용액의 정밀여과막 오염특성)

  • 정건용
    • Membrane Journal
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    • v.11 no.4
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    • pp.161-169
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    • 2001
  • Single and mixed particle suspensions of kaolin, bentonite, starch and PMMA were carried out using a dead-end Amicon fi1tration cell with microfilteration membranes. The experimental data of permeate fluxes were fitted by the constant pressure fi1tration models in order to investigate fouling steps. In 0.1 wt% mixed solution of equal amount of kaolin and starch, the permeation flux was about 30% lower than the average of each particle flux. However, the permeation flux for kaolin/PMMA mixed solution was about 10% higher than the average of each particle flux. In the cases of bentonite and PMMA or starch mired solution, the improvement effect on permeation flux was weaken than that of kaolin mixed solution. Also, the membrane fouling resistance for mixed particle solution of equal amount of kaolin and starch was minimum at 0.05 wt% particle concentration.

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