• Economic and Environmental Geology
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• v.39 no.3 s.178
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• pp.269-284
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• 2006

Aquifer responses to the river stage fluctuations were analyzed between the groundwater level and the river stage in an alluvial aquifer. The auto-correlation and cross-correlation as a time series analysis were applied. Study site is a floodplain in the Mangyeong river. Groundwater levels in each depth representing the silt and sand(SS), gravel and sand(GS), and weathered zone(WZ) layer were monitored. The groundwater levels were more sensitive to the river stage fluctuations than rainfall. Since the river stages are influenced by the gate operations downstream and tide, show periodic patterns, and the correlation coefficients with rainfall is low. Cross-correlation function between groundwater level in each depth do not show any delay time, then response time is very short to each depth. Cross-correlation analysis were performed to estimate the response time of groundwater levels to river stage fluctuations. Groundwater levels respond to the river stage within 30 minutes to 1 hour in wells near the stream. Short time lag between groundwater level and river stage indicates the quick response. A different response time imply the hydraulic inhomogeneity of the site, and a probable high permeability zone between river and aquifer can be inferred. Mangyeong-river in study site is a gaining stream normally, and river stage rising by gate operation or floods makes river water flow into groundwater. The auto-correlation and cross-correlation functions as a time series analysis can be a good tool to interpret the aquifer responses to stream stage fluctuation

• The Journal of Engineering Geology
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• v.15 no.2 s.42
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• pp.105-121
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• 2005

Most of the landslides triggered by intensive rainfall on natural slope occur serious damages of human beings and properties. There have been many landslides since 1991 in Gyeonggi province. The influential factors are rainfall, topography, geology and soil properties. There were 660 landslides occurred by intensive rainfall as much as 250mm at Yongin and Anseong area from Tuly 19th to luly 21st,1991 This study surveyed location, topography, geology, geometry of the landslide and rainfall at the area and analyzed occurrence characteristics of the landslides. Most of the landslides occurred on the soil layer above the bed rock. They showed changes of landslide types from translational slides at the head part to flow at the central part. The landslides have relatively small magnitude of which length is shorter than 50m. In order to identify characteristics of landslides dependent on soil conditions, geotechnical properties of soil were evaluated by laboratory tests using soil samples which were collected on slided area and not-slided area. Soil properties of the slided area show high percentage of coarse material such as gravel and sand. However, soil of the not-slided area is mainly composed of fine material such as silt and clay. Permeability coefficients of the slided area are higher than those of the not-slided area.

• Journal of the Korean Geotechnical Society
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• v.19 no.6
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• pp.217-225
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• 2003

An experimental study was conducted to evaluate the smeared effect due to mandrel penetration into soft ground for a vertical drain installation. Laboratory tests were performed to investigate the formation of a smear zone, the variations of strength, and the consolidation characteristics in the disturbed zone using two types(CL at Yangsan site and OH at Pohang site) of soft clayey soils. The smear zone effect was evaluated focusing on mandrel shape, mandrel size, penetration speed, and ground condition. Based on laboratory test results, the diameter of the smear zone$(d_s)$ ranged from 3.08 and 3.92 times that of mandrel$(d_m)$. It was also found that the $(d_s/d_m)$ value of the circular shape of the mandrel is smaller than those of square and rectangular shapes. The value of $(d_s/d_m)$ decreased with larger mandrel size, lower penetration speed in the CL soil, and higher penetration speed in the OH soil. However, natural water content was minimally affected by $(d_s/d_m)$. Respectively, the coefficients of horizontal consolidation$(C_{hs})$ and horizontal Permeability$(K_s)$ of smear zone ranged from 0.81 to 0.87 times, and 0.73 to 0.83 times those of the undisturbed zone. Based on this study, the values of $C_{hs}, K_s$ and unconfined compressive strength$(q_{us})$ in the smear zone were the lowest at close vicinity of the mandrel and increased linearly with distance from the mandrel. Further, the $(q_{us})$ varied from 0.5 to 0.9 times that of the undisturbed zone strength.

• Korean Journal of Food Science and Technology
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• v.20 no.3
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• pp.380-384
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• 1988

The coefficients of the hot-air and freeze dried garlic isotherms and the critical water activities of these were estimated to be 0.85-0.94 by the linear regression and 0.58-0.60 by the sensory evaluation and ${\Delta}E$ value. Water adsorption rate(K) of hot-air dried garlic packaged with $48{\mu}m$ low density polyethylene(LDPE) decreased from $0.12g\;H_2O/100g/day\;to\;0.093g\;H_2O$/100g/day with decreasing the package dimension from $0.051m^2\;to\;0.029m^2\;at\;40^{\circ}C$ and 75% RH, and that of freeze dried one decreased from $0.17g\;H_2O/100g/day\;to\;0.12g\;H_2O$/100g/day as the filling weight increased from 50g to 10g in the package of $0.051m^2$. Shelf-life of hot-air dried garlic packaged with $80{\mu}m$ LDPE were 99days at $40^{\circ}C,\;283day\;at\;30^{\circ}C\;and\;455\;days\;at\;15^{\circ}C$ in the 75% RH. The differences of water contents between predicted data with water vapor permeability of the conventional method and experimental data were 0-1.5% in the water content range of around 13-18%, but about 2 in the water content range of around 8-11%.

• Journal of the Korean Geotechnical Society
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• v.20 no.3
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• pp.23-31
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• 2004

Normally, coating is used for protecting reinforced concrete. For this purpose, both organic and inorganic coatings are used. The advantages of inorganic coatings are lower absorption of UV, non-burning etc. On the other hand, organic coatings have the advantage of low permeability of $CO_2, SO_2$ and water. Organic coatings provide better protection for reinforced concrete. However, organic coatings such as epoxy, urethane and acryl reduce long-term adhesive strength by the difference of their thermal expansion coefficients and elastic modules from those of concrete, and the formed coating cover of these is blistered by poor breathing. Also, when organic coatings are applied to the wet surface of concrete, they have a problem with adhesion. In this study, a new coating material for protecting concrete was hybridized with polymer and ceramics. And tests were carried out on its physical and durable characteristics, and safety characteristic on elution. All results were compared with organic coating materials and epoxies and showed that the performance of the developed coating material was not inferior to that of other organic coatings in protecting concrete. On the other hand, safety characteristic on elution was superior to epoxies which were used in this study. So, the developed coating material was considered as a suitable protecting coating material which have advantages of inorganic and organic coatings for protecting underground concrete structures, especially in contact with water.

• Journal of the Korean Geotechnical Society
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• v.37 no.12
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• pp.47-56
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• 2021

The cryosuction (negative pore pressure) in freezing soils causes groundwater migration from the frozen fringe to freezing front for ice lens formation. Frost heave and heaving pressure by ice lens cause damage to ground infrastructure. In order to prevent damage by the frost heave, various frost susceptibility criteria have been proposed. The SP (Segregation Potential) is the most widely used classification criterion for frost susceptibility in cold regions. The expansion of the ice lens by the migration of the groundwater is a key role in frost heave mechanism, and thus it is necessary to evaluate the hydraulic conductivity. In this paper, soil mixtures of coarse-fines (sand-silt) were prepared in various weight fractions and used for frost heave and column permeability test. For each case, the SP and the hydraulic conductivity were derived and correlations were analyzed. As a results, the transition threshold of the SP and the hydraulic conductivity were shown at 20% and 50% of the silt weight fraction, respectively. Although there are difference between these transition thresholds, these two coefficients show a specific correlation. In the future, additional study should be conducted for detailed analysis of the threshold transition values between SP and hydraulic conductivity.

• Proceedings of the Membrane Society of Korea Conference
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• 1999.07a
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• pp.39-42
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• 1999

Perfluoropolymers represent the ultimate resistance to hostile chemical environments and high service temperature, attributed to the presence of fluorine in the polymer backbone, i.e. to the high bond energy of C-F and C-C bonds of fluorocarbons. Copolymers of Tetrafluoroethylene (TEE) and 2, 2, 4Trifluoro-5Trifluorometoxy- 1, 3Dioxole (TTD), commercially known as HYFLON AD, are amorphous perfluoropolymers with glass transition temperature (Tg)higher than room temperature, showing a thermal decomposition temperature exceeding 40$0^{\circ}C$. These polymer systems are highly soluble in fluorinated solvents, with low solution viscosities. This property allows the preparation of self-supported and composite membranes with desired membrane thickness. Symmetric and asymmetric perfluoropolymer membranes, made with HYFLON AD, have been prepared and evaluated. Porous and not porous symmetric membranes have been obtained by solvent evaporation with various processing conditions. Asymmetric membranes have been prepared by th wet phase inversion method. Measure of contact angle to distilled water have been carried out. Figure 1 compares experimental results with those of other commercial membranes. Contact angles of about 120$^{\circ}$for our amorphous perfluoropolymer membranes demonstrate that they posses a high hydrophobic character. Measure of contact angles to hexandecane have been also carried out to evaluate the organophobic character. Rsults are reported in Figure 2. The observed strong organophobicity leads to excellent fouling resistance and inertness. Porous membranes with pore size between 30 and 80 nanometers have shown no permeation to water at pressures as high as 10 bars. However high permeation to gases, such as O2, N2 and CO2, and no selectivities were observed. Considering the porous structure of the membrane, this behavior was expected. In consideration of the above properties, possible useful uses in th field of gas- liquid separations are envisaged for these membranes. A particularly promising application is in the field of membrane contactors, equipments in which membranes are used to improve mass transfer coefficients in respect to traditional extraction and absorption processes. Gas permeation properties have been evaluated for asymmetric membranes and composite symmetric ones. Experimental permselectivity values, obtained at different pressure differences, to various single gases are reported in Tab. 1, 2 and 3. Experimental data have been compared with literature data obtained with membranes made with different amorphous perfluoropolymer systems, such as copolymers of Perfluoro2, 2dimethyl dioxole (PDD) and Tetrafluorethylene, commercialized by the Du Pont Company with the trade name of Teflon AF. An interesting linear relationship between permeability and the glass transition temperature of the polymer constituting the membrane has been observed. Results are descussed in terms of polymer chain structure, which affects the presence of voids at molecular scale and their size distribution. Molecular Dyanmics studies are in progress in order to support the understanding of these results. A modified Theodoru- Suter method provided by the Amorphous Cell module of InsightII/Discover was used to determine the chain packing. A completely amorphous polymer box of about 3.5 nm was considered. Last but not least the use of amorphous perfluoropolymer membranes appears to be ideal when separation processes have to be performed in hostile environments, i.e. high temperatures and aggressive non-aqueous media, such as chemicals and solvents. In these cases Hyflon AD membranes can exploit the outstanding resistance of perfluoropolymers.

• Analytical Science and Technology
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• v.31 no.6
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• pp.240-246
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• 2018

The present study analyzed standard samples of three types of aluminum matrix certified reference materials (CRM) using GD-MS. Calibration curves were constructed for 13 elements (Mg, Si, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Sn, and Pb), with the slope representing the relative sensitivity factor (RSF). The x- and y-axes of the calibration curve represented ion beam ratio (IBR) and the authenticated value of the standard sample, respectively. In order to evaluate precision and linearity of the calibration curve, RSD and the coefficient of determination were calculated. Curve RSD for every element reflected high precision (within 10 %). For most elements, the coefficient of determination was ${\geq}0.99$, indicating excellent linearity. However, vanadium, nickel, and gallium curves exhibited relatively low linearity (0.90~0.95), likely due to their narrow concentration ranges. Standard RSF was calculated using the slope of the curve generated for three types of CRM. Despite vanadium, nickel, and gallium exhibiting low coefficients of determination, their standard RSF resembled that of the three types of CRM. Therefore, the RSF method may be used for element quantitation. Standard iron matrix samples were analyzed to verify the applicability of the aluminum matrix standard RSF, as well as to calculate the RSD-estimated error of the measured value relative to the actual standard value. Six elements (Al, Si, V, Cr, Mn, and Ni) exhibited an RSD of approximately 30 %, while the RSD of Cu was 77 %. In general, Cu isotopes are subject to interference: $^{63}Cu$ to $^{54}Fe^{2+}-^{36}Ar$ and $^{65}Cu$ to $^{56}Fe-Al^{3+}$ interference. Thus, the influence of these impurities may have contributed to the high RSD value observed for Cu. To reliably identify copper, the resolution should be set at ${\geq}8000$. However, high resolutions are inappropriate for analyzing trace elements, as it lowers ion permeability. In conclusion, quantitation of even relatively low amounts of six elements (Al, Si, V, Cr, Mn, and Ni) is possible using this method.