• Title/Summary/Keyword: permanent gas

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Diffusion-Selectivity Analysis of Permanent Gases through Carbon Molecular Sieve Membranes

  • Kang, Jong-Seok;Park, Ho-Bum;Lee, Young-Moo
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.43-53
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    • 2003
  • The selectivity of a gas in the carbon molecular sieve membrane (CMSM) can be expressed as the ratio of the product of the diffusivity and the solubility of two different gases. The diffusivity is also expressed as the product of the entropy and the total energy (kinetic and potential energy) in the nano-sized pore of the membrane. The present study calculates the entropic-energy and selectivity of penetrant gases such as H$_2$, O$_2$, N$_2$, and CO$_2$ from the gas-in-a box theory to physically analyze the diffusivity of penetrant gas in slit-shaped pore of CMSM focusing on the restriction of gas motion based on the size difference between penetrant gas pairs. The contribution of each energy term is converted to entropic term separately. By the conjugated calculation for each entropic-energy, the entropic effects on diffusivity-selectivity for gas pairs such as H$_2$/N$_2$, CO$_2$/N$_2$, and O$_2$/N$_2$ were analyzed within active pore of CMSM. In the activated diffusion domain, the calculated value of entropic-selectivity lies between 9.25 and 111.6 for H$_2$/N$_2$, between 3.36 and 6.0 for CO$_2$/N$_2$, and between 1.25 and 16.94 for O$_2$/N$_2$, respectively. The size decrement of active pore in CMSM had the direct effect on the reduction of translational entropic-energy and the contribution of vibrational entropic-energy for N$_2$, O$_2$, and H$_2$ was almost negligible. However, the vibrational entropic term of CO$_2$ might extravagantly affect on the entropic-selectivity.

Estimation of the Carbon Stock and Greenhouse Gas Removals by Tree Species and Forest Types in Gangwon Province (강원도 산림의 임상별, 수종별 탄소저장량 및 온실가스 흡수량 산정)

  • Lee, Sun Jeoung;Yim, Jong-Su;Son, Yeong Mo;Kim, Raehyun
    • Journal of Climate Change Research
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    • v.6 no.4
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    • pp.303-310
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    • 2015
  • This study was conducted to estimate of carbon stock and greenhouse gas (GHGs) removals by tree species and forest type at Gangwon province. We used a point sampling data with permanent sample plots in national forest inventory and national emission factors. GHGs emissions was caclulated using the stock change method related to K-MRV and IPCC guidance. Total carbon stock and greenhouse gas removals were high in deciduous forest and species than in coniferous. The range of annual net greenhouse gas emissions in other deciduous species was from $-11,564.83Gg\;CO_2\;yr^{-1}$ to $-13,500.60Gg\;CO_2\;yr^{-1}$ during 3 years (2011~2013). On the other hand, coniferous forest was temporally converted to source due to reducing of growing stock in 2012. It was that growing stocks and forest area were likely to reduce by the deforestation and clear cutting. This study did not consider other carbon pools (soil and dead organic matter) due to the lack of data. This study needs to complement the activity data and emission factors, and then will find the way to calculate the greenhouse gas emissions and removals in the near future.

Measurement of Ion Energy Distribution using QMS & Ionization Enhancement by usign Magnetic Field in Triod BARE (자장을 이용한 이온화율 증대형 삼극형 BARE에서 이온화율의 증대경향과 QMS를 이용한 이온의 에너지 분포 측정)

  • 김익현;주정훈;한봉희
    • Journal of the Korean institute of surface engineering
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    • v.24 no.3
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    • pp.119-124
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    • 1991
  • Recently, the trend of research in hard coating is concentrate on developing the process of ionization rate under low operating pressure, to get the thin film with high adhesion and dense microstructures. In this study ionization rate enhancement type PVD process using permanent magnet is developed, which enhances the ionization rate by confining the plasma suppressing the wall loss of electron. By the result to investigate the characteristic of glow discharge, the ionization rate of this process is enhanced about twice as high as that of triod BARE process (about 26%), and more dense TiN microstructures are obtained in this process. Cylindrical ion energy analyzer is made and attached in front of a quadrupole mass filter for the analysis of the energy distribution of reactive gas and activated gas ions from the plasma zone. To analyze the operation mechanism of ion energy analyzer, computer simulation is performed by calculation the electric field environment using finite element method. By these analyses of ion energy distribution of outcoming ions from the plasma zone, it is found that magnetic field enhances ion kinetic energy as well as ionization rate. The other results of this study is that the foundation of feed-back system is constructed, which automatically control the partial pressure of reactive gas. In can be possible by recording the data of mass spectrum and ion energy analysis using A-D converter.

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Structure of a Plasma Ion Source for a Cross-Section SEM Sample (SEM 단면 시료 제작을 위한 플라즈마 이온원의 구조)

  • Won, Jong-Han;Jang, Dong-Young;Park, Man-Jin
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.4
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    • pp.400-406
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    • 2015
  • This study researched the structure of the source of an ion milling machine used to fabricate a scanning electron microscope (SEM) sample. An ion source is used to mill out samples of over 1 mm dimension using a broad ion beam to generate plasma between the anode and cathode using a permanent magnet. To mill the sample in the vacuum chamber, the ion source should be greater than 6 kV for a positive ion current over $200{\mu}A$. To discover the optimum operating conditions for the ion miller, the diameter of the extractor, anode shape, and strength of the permanent magnet were varied in the experiments. A silicon wafer was used as the sample. The sputter yield was measured on the milled surface, which was analyzed using the SEM. The wafer was milled by injecting 1 sccm of argon gas into the 0.5 mTorr vacuum chamber.

A Study on the Analysis of Characteristics of Permanent Magnetic Actuator for $SF_6$ Gas Insulated Recloser ($SF_6$ 가스절연 Recloser용 PMA에 대한 특성해석에 관한 연구)

  • Kim, Han-Kyun;Jang, Jeong-Won;Lee, Chang-Hwan;Suh, Wang-Byuck;Hahn, Sung-Chin
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.713-714
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    • 2006
  • $SF_6$ 가스절연 Recloser는 선로에 일시적인 과전류가 발생하면 개방 후 자동 재투입 하면서 선로의 정상적인 운전상태를 회복하고, 영구 고장 시에는 정해진 Sequence에 따라 개방, 투입을 반복한 후 개방완료 상태에 이르게 하는 보호기기이며, 조작부는 주로 Solenoid Actuator 방식을 채택해왔었다. 그러나 Solenoid Actuator 방식은 구조가 복잡하고 부품수가 많은 단점이 있어 최근에는 사용 부품수를 획기적으로 감소 시키고 조작 신뢰성을 증대시킨 Magnetic Actuator 방식을 채택하여 사용하는 경향을 보이고 있다. 이 Magnetic Actuator 방식은 구조가 간단하고 부품수가 적어 높은 신뢰성을 확보할 수 있고 유지 보수가 거의 필요하지 않는 장점을 가지고 있다. 이에 본 논문에서는 $SF_6$ 가스절연 Recloser의 조작부에 Magnetic Actuator 방식(이하 PMA (Permanent Magnetic Actuator))을 채용 하였으며, 이를 적용하기위한 입력전원 및 투입, 개방 코일을 패러미터로 하여 PMA의 동적특성을 실험하였으며, 이 실험 자료에 근거하여 27[kV] $SF_6$ 가스절연 Recloser의 PMA 조작부를 설계 및 제작하였다.

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Novel process of rare-earth free magnet and thermochemical route for the fabrication of permanent magnet

  • Choi, Chul-Jin
    • Proceedings of the Korean Magnestics Society Conference
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    • 2013.12a
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    • pp.89-89
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    • 2013
  • Rare earth (RE) - transition metal based high energy density magnets are of immense significance in various engineering applications. $Nd_2Fe_{14}B$ magnets possess the highest energy product and are widely used in whole industries. Simultaneously, composite alloys that are cheap, cost effective and strong commercially available have drawn great attention, because rare-earth metals are costly, less abundant and strategic shortage. We designed rare-earth free alloys and fabrication process and developed novel route to prepare $Nd_2Fe_{14}B$ powders by wet process employing spray drying and reduction-diffusion (R-D) without the use of high purity metals as raw material. MnAl-base permanent magnetic powders are potentially important material for rare-earth free magnets. We have prepared the nano-sized MnAl powders by plasma arc discharge and micron-sized MnAl powders by gas atomization. They showed good magnetic property, compared with that from conventional processes. $Nd_2Fe_{14}B$ powders with high coercivity of more than 10 kOe were successfully synthesized by adjusting R-D step, followed by precise washing system. It is considered that this process can be applied for the recycling of RE-elements extracted from ewaste including motors.

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Study on the Optimization of Reduction Conditions for Samarium-Cobalt Nanofiber Preparation (사마륨-코발트 자성 섬유 제조를 위한 환원 거동 연구 및 환원-확산 공정의 최적화)

  • Lee, Jimin;Kim, Jongryoul;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.26 no.4
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    • pp.334-339
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    • 2019
  • To meet the current demand in the fields of permanent magnets for achieving a high energy density, it is imperative to prepare nano-to-microscale rare-earth-based magnets with well-defined microstructures, controlled homogeneity, and magnetic characteristics via a bottom-up approach. Here, on the basis of a microstructural study and qualitative magnetic measurements, optimized reduction conditions for the preparation of nanostructured Sm-Co magnets are proposed, and the elucidation of the reduction-diffusion behavior in the binary phase system is clearly manifested. In addition, we have investigated the microstructural, crystallographic, and magnetic properties of the Sm-Co magnets prepared under different reduction conditions, that is, $H_2$ gas, calcium, and calcium hydride. This work provides a potential approach to prepare high-quality Sm-Co-based nanofibers, and moreover, it can be extended to the experimental design of other magnetic alloys.

Development of Permanent Reference Electrode for Corrosion Monitoring of Underground Metallic Structures (지중 금속구조물 부식감시를 위한 영구매설용 기준전극 개발)

  • Ha, Y.C.;Bae, J.H.;Ha, T.H.;Lee, H.G.;Lee, J.D.;Kim, D.K.
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.532-534
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    • 2004
  • The advancement of electronics and telecommunication technologies has forced the risk management system for underground metallic structures to evolve into the remote monitoring and control system. Especially, facilities such as gas pipelines, oil pipelines and water distribution lines might make hazardous effect on human safety without continuous monitoring and control. As a result, pipeline engineers have applied cathodic protection system to prevent the degradation of their facilities by corrosion and carried out a periodic monitoring of the pipe-to-soil (P/S) potentials at numberous test boxes along their pipelines. The latter action on a road in downtowns, however, is so much dangerous that the inspectors should be ready to suffer the threatening of their lives and maintenance. In order to minimize these social costs and hazards, a stand-alone type corrosion monitoring equipment which can be installed in test box, store the P/S data for given Belied and send the data by wired/wireless telecommunications is under development. In order to obtain the exact P/S data, however, a reference electrode should be located as close to the pipeline as possible. Actually, the measured potential by a conventional portable reference electrode contain inevitably an IR drop portion caused by the current flow from the cathodic protection rectifier or the subway railroad. To minimize this error, it is recommended that the reference electrode should be buried within 10 cm from the pipeline. In this paper, we describe the design parameters for fabricating the permanent type reference electrode and the characteristics of the developed reference electrode.

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Assessment on Forest Resources Change using Permanent Plot Data in National Forest Inventory (국가산림자원조사 고정표본점 자료를 활용한 산림자원변화 평가에 관한 고찰)

  • Yim, Jong-Su;Kim, Eun Sook;Kim, Chel Min;Son, Yeong Mo
    • Journal of Korean Society of Forest Science
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    • v.104 no.2
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    • pp.239-247
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    • 2015
  • Since 2006, new national forest inventory in Korea has been restructured to assess current status and and monitor the changes in forest resources based on permanent sample plots. The objective of estimate this study is to assess changes in forest resources such as land use/cover categories and forest stand variables. For this study, permanent plot data were collected between 2006-2008 and 2011-2013 in Chungcheongbuk-do, respectively. In order to produce land use/cover change matrix which plays an important role as an activity data for estimating GreenHouse Gas inventory, permanent plots were classified into six land use/cover categories. Additionally, matrixes for assessing the changes in age class and dominant tree species can provide more detailed information. For forest stand variables(tree density, basal area, growing stock, mean diameter at breath height, and mean height), their growth and change were assessed. The periodic annual growth ratios for tree density and basal area were slightly declined whereas that of growing stock was estimated to be about 3.7%. The uncertainty of changes in forest stand variables is less than 5%, except for tree density (RSE: 58%). The variation of tree density is relatively high compared to the other variables.

Numerical and Experimental Analysis of Micro Gas Turbine Heat Transfer Effect (초소형 가스터빈엔진 열전달 현상의 수치적 및 실험적 연구)

  • Seo, Junhyuk;Kwon, Kilsung;Choi, Ju Chan;Baek, Jehyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.153-159
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    • 2015
  • In this study, a 2-W micro-gas turbine engine was designed using micro-electro-mechanical systems (MEMS) technology, and analytical and experimental investigations of its potential under actual combustion conditions were performed. An ultra-micro-gas turbine contains a turbo-charger, combustor, and generator. A compressor, turbine blade, and generator coil were manufactured using MEMS technology. The shaft was supported by a precision computer numerical control machined air bearing, and a permanent magnet was attached to the end of the shaft for generation. An analysis found that the cooling effect of the air bearing and compressor was sufficient to cover the combustor heat, which was verified in an actual experiment.