• Title/Summary/Keyword: percolation effect

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Nondestructive Damage Sensitivity for Functionalized Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Acoustic Emission (전기저항 측정과 음향방출을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.42-45
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    • 2003
  • Nondestructive damage sensing and mechanical properties for acid-treated carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites were investigated using electro-micromechanical technique and acoustic emission (AE). Carbon black (CB) was used to compare to CNT and CNF. The results were compared to the untreated case. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity under double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. For surface treatment case, the damage sensitivity and reinforcing effect were higher than those of the untreated case. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Modeling of the Setting Characteristics of Early-age Concrete (초기재령 콘크리트의 응결특성 모델링)

  • 조호진;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.391-396
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    • 2002
  • The so called setting is defined as the onset of rigidity in fresh concrete. In the analysis of the early-age concrete behavior, we consider fresh concrete as a structural element immediately after mixing. But for the activation of real structural behavior of fresh concrete, it takes some time after the beginning of hydration reaction. So, the very early age deformations due to hydration heat and shrinkage which occur before the setting do not produce restraint stresses. In this paper, we propose a setting characteristic model based on the so called percolation theory. From the analysis using the model, the influence of curing temperature is investigated and analytical results are compared with experimental results. From the comparison, the validity of proposed model is verified. This model is also applied to evaluate stress development in a temperature-stress test machine (TSTM) specimen and then the effect of setting time on the stress development is discussed.

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Stress relaxation of ABS polymer melts. 1. Effect of weight fraction of rubber particle

  • Cho, Kwang-Soo;Park, Joong-Hwan;Kim, Sang-Yong;Youngdon Kwon
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.157-163
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    • 2000
  • We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

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Concentrations of the Pollutant in Unit Paddy with Different Fertilizer Application Rates (시비조건의 차이에 따른 단위논에서의 오염물질의 농도특성)

  • Cho, Jae-Won;Kim, Jin-Soo;Oh, Seung-Young;Yoon, Chun-Gyeong;Lee, Chul-Won
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.466-469
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    • 2001
  • The effect of fertiltzer application on ponded and percolation water in paddies were evaluated at the experimental plots during irrigation period. We laid out three experimental plots such as 150% Excessive, 100% Standard and 70% Reduced. The concentration of T-N and T-P in ponded water were increased rapidly after application. The concentration of T-N and COD in percolated water increased with fertilizer application rates, while T-P concentration were almost constant.

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Microstructural and Mechanical Characterization of Nanocomposite Ti-Al-Si-N Films Prepared by a Hybrid Deposition System (하이브리드 증착 시스템에 의해 합성된 나노복합체 Ti-Al-Si-N 박막의 미세구조와 기계적 특성)

  • 박인욱;최성룡;김광호
    • Journal of the Korean institute of surface engineering
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    • v.36 no.2
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    • pp.109-115
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    • 2003
  • Quaternary Ti-Al-Si-N films were deposited on WC-Co substrates by a hybrid deposition system of arc ion plating (AIP) method for Ti-Al source and DC magnetron sputtering technique for Si incorporation. The synthesized Ti-Al-Si-N films were revealed to be composites of solid-solution (Ti, Al, Si)N crystallites and amorphous Si3N4 by instrumental analyses. The Si addition in Ti-Al-N films affected the refinement and uniform distribution of crystallites by percolation phenomenon of amorphous silicon nitride, similarly to Si effect in TiN film. As the Si content increased up to about 9 at.%, the hardness of Ti-Al-N film steeply increased from 30 GPa to about 50 GPa. The highest microhardness value (~50 GPa) was obtained from the Ti-Al-Si-N film haying the Si content of 9 at.%, the microstructure of which was characterized by a nanocomposite of nc-(Ti,Al,Si) N/a$-Si_3$$N_4$.

Effect of exfoliated graphite nanoplatelets on the fracture surface morphology and the electrical resistivity of phenylethynyl-terminated polyimide

  • Cho, Dong-Hwan;Fukushima, Hiroyuki;Drzal, Lawrence T.
    • Carbon letters
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    • v.13 no.2
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    • pp.121-125
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    • 2012
  • In the present work, exfoliated graphite nanoplatelets (EGN) of 1 ${\mu}m$ in average particle size, which were prepared by heating at $900^{\circ}C$ and then subjected to ultrasonic, ball-milling, and vibratory ball-milling techniques, were uniformly incorporated into phenylethynyl-terminated polyimide (PETI-5) resin. The fracture surface morphology and the electrical resistivity of the EGN/PETI-5 composites were investigated. The results showed that the fracture surfaces and the electrical resistivity strongly depended on the EGN content. The fracture surfaces became more ductile and roughened with increasing EGN and the electrical resistivity was gradually decreased with increased EGN loading, indicating the percolation threshold at 5 wt% EGN.

A Theoretical Analysis on Volatile Matter Release from Different Coals Using CPD Model During a Coal Gasification (CPD 모델을 활용한 석탄 가스화 과정 중 탄종에 따른 휘발분 배출에 관한 이론해석연구)

  • Kim, Ryang-Gyoon;Lee, Byoung-Hwa;Jeon, Chung-Hwan;Chang, Young-June;Song, Ju-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.1000-1006
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    • 2009
  • Integrated Coal Gasification Combined Cycle (IGCC) power plants have been developed to reduce carbon dioxide emissions and to increase the efficiency of electricity generation. A devolatilization process of entrained coal gasification is predicted by CPD model which could describe the devolatilization behavior of rapidly heated coal based on the chemical structure of the coal. This paper is intended to compare the mass release behavior of char, tar and gas(CO, $CO_2,\;H_2O,\;CH_4$) for three different coals. The influence of coal structure on gas evolution is examined over the pressure range of 10${\sim}$30atm.

Effect of Korean Red Ginseng Component on Lipolytic Action of Toxohormone-L from Cancerous Ascites Fluid (고려홍삼 성분이 암독소 호르몬-L의 체지방 분해작용에 미치는 영향)

  • 이성동;황우익
    • The Korean Journal of Food And Nutrition
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    • v.8 no.2
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    • pp.105-109
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    • 1995
  • This study was devised to observe the inhibitory effects of 3 kinds of petroleum ether extracts (percolation by petroleum ether) from Korean red ginseng, Chinese red ginseng and American white ginseng on a lipolytic action of Toxohormone-L which has been known as lipolytic and anorexigenic factors. Toxohormone-L was obtained by partial purification of the ascites fluid from mice which had been Inoculated with sarcoma-180. The yields of petroleum ether extract from Korean red ginseng, Chinese red ginseng and American white ginseng were 0.64, 0.47 and 0.58 and respectively, indicating that the yield of Korean red ginseng was the highest. In vitro, at the concentration of 2 mg /ml, the inhibition rate of lipolysis by the petroleum ether extract of Korean red ginseng, Chinese red ginseng and American white ginseng were 55.1, 50.0 and 44.9% respectively, and the total inhibitory activity per gram of ginseng material were 18, 12 and 13 unit respectively, indicating that the Korean red ginseng was the most effective in the inhibition of the lipolysis.

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Changes of Electrical Properties of Graphene upon Introduction of Structural Defects and Gas Exposure

  • Kim, Kang-Hyun;Kang, Hae-Yong;Lee, Jae-Woo;Lee, Nam-Hee;Woo, Byung-Chill;Yun, Wan-Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.474-474
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    • 2011
  • Graphene is considered as a potential candidate for the key material in the ideal 2D nanoelectronics. Recently, it is reported that graphene has an interesting sensitivity to molecular adsorption on it. Such properties are believed to be enhanced by the existence of disorders and ripples inside graphene as well as by the interaction with the substrate underneath. Here, we report the effect of introducing structural disorders to the graphene on its electrical properties such as conductance, transconductance, low frequency noise, which can be successfully described by a simple model of the continuum percolation. In addition, the response of the graphene device to gaseous molecular adsorption was systematically investigated and the results were discussed along with the change in Raman spectra.

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Characteristics of Concentration of Nitrogen , Phosphorous and COD in a Paddy Field (단위논에서의 질소, 인 및 COD의 수질 특성)

  • 이종진;김진수;오승영
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.670-675
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    • 1999
  • The effect of fertilizer applicatioin on ponded and percolation water in paddies were evaluated at the field plots of the Chungbuk National University for irrigation period. The chemical fertilicers were applied to the study polts at an average application rate of 77, 110, 165kgN/ha, respectively. The concentration of T-N , T-P and COD in ponded water greatly depends on the amount and timing of fertilizer applied. Therefore, the decrease in the amount of fertilizer and proper water management may be needed to decrease in the amount of fertilizer and proper water management may be needed to reduce the runoff loading.

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