• Macromolecular Research
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• v.17 no.5
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• pp.319-324
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• 2009

A new $\pi$-conjugated polymer, poly[(2-methoxy-(5-(2-(4-oxyphenyl)-5-phenyl-1,3,4-oxadiazole)-hexyloxy))-1,4-pheny1ene-1,2-etheny1ene-alt-(10-hexyl-3,7-phenothiazine )-1,2-ethenylene] (PTOXDPPV), was synthesized by the Heck coupling reaction. The electron transporting unit, conjugated 1,3,4-oxadiazo1e (OXD), is attached on the main chain via linear 1,6-hexamethylenedioxy chain. The band gap and photoluminescence (PL) maximum of PTOXDPPV are 2.35 eV and 565 nm, respectively. These values are very close to those of po1y[(2,5-didecyloxy-1,4-phenylene-1,2-etheny1ene )-alt-(l0-hexyl-3,7-phenothiazine)-1,2-ethenylene] (PTPPV), which does not have OXD pendant. The estimated HOMO energy level of PTOXDPPV was -4.98 eV, which is very close to that of PTPPV (-4.91 eV). The maximum wavelength of EL device based on PTOXDPPV and PTPPV appeared at 587 and 577 nm, respectively. In the PL and EL spectrum, the emission from OXD pendant was not observed. This indicates that the energy transfer from OXD pendants to main chain is occurred completely. The EL device based on PTOXD-PPV (ITO/PEDOT/PTOXDPPV/AI) has an efficiency of 0.033 cd/A, which is significantly higher than the device based on PTPPV (ITO/PEDOT/PTPPV/AI) ($4.28{\times}10^{-3}\;cd/A$). From the results, we confirm that the OXD pendants in PTOXDPPV facilitate hole-electron recombination processes in the emissive layer effectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.5
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• pp.2550-2558
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• 2013

Poly(o-hydroxyamides)(PHAs) copolymers having oligo(oxy ethylene) pendant in the main chain were synthesized by solution polycondensation reaction at low temperature. Copolymer precursors were studied by fourier transform infrared(FT-IR), differential scanning calorimeter(DSC), thermogravimetric analyzer(TGA), universal testing machine(UTM) and limited oxygen index(LOI). The inherent viscosities of the PHAs measured at $35^{\circ}C$ in DMAc or DMAc/LiCl solution were in the range of 0.74~1.42 dL/g. Solubility of the precursors with higher oligo(oxy ethylene) unit was increased, but the PBOs were nearly insoluble in a variety of solvents. The degradation temperature of the copolymer precursors was recorded in the ranges of $408{\sim}664^{\circ}C$ in nitrogen and char yields showed 13~59% values at $900^{\circ}C$. The mechanical properties and flame retardancy of copolymer precursors decreased with higher oligo(oxy ethylene) unit.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.46-55
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• 2016

This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.32 no.1
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• pp.7-15
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• 1996

Full scale experiment was carried out in the southern sea of Korea to compare some important factors tested in the model experiment. The results obtained can be summarized as follows ; 1. The changing aspect of mouth performance of the full scale net was almost coincided with the results obtained by the model experiment. The vertical opening(H) and the opening area(S) can be expressed as a function of the towing velocity(V) as H=48.78. $e^0.38V$(unit: m, k't) S= 1,443 .$e^-0.25V$(unit: $m^2V$, k't) 2. The changing aspect of working depth of the full scale net was almost coincided with the results obtained by the model experiment. The depth(D) can be expressed as a function of the towing velocity(V) and the warp length(L) as D=92.49.$V^1.37$(unit: m, k't, L= 150m) D= 12.07+0.32. L (unit: m, V=2k't) [)= - 7.90+0.22 . L (unit: m, V=3k't) 3. Some problems were found to operate A - type full scale net by common bottom pair trawlers. The problems can be summarized as follows; (1) Entangling of wing and square head ropes while net casting.(2) Man power needed and time spent for net hauling by common bottom trawlers increased considerably.( 3) Tearing of nettings caused by over -load of tension and entangling of net pendant while net hauling. To solve these problems, the trawlers are favorable to be equipped with variable pitch propeller and llet drum. While the net is favorable to be constructed with trifurcated net pendant in stead of quadrifurcated net pendant used at present.

• Journal of the Korean Ceramic Society
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• v.33 no.12
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• pp.1325-1330
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• 1996

A new numerical method for determining the surface tension of a liquid drop by experimental measurement of the contour of the sessile drop is explained. in the present method a very simple and short computer program enables the calculation of surface tension in a few seconds even by a low speed personal computer. It need not the use of any other numerical tables or complex techniques. X and Z-corrdinates at one point on the contour of a sessile drop and the tangential angle at that point are all the data needed when the density of the drop is known. The results were compared with the values derived by a conventional method. This method can be used for the confirmation of measuring accuracy. Also the same concepts can be applied for the pendant drop method by changing only the sign of Z-coordinate from "+" to "-"ot; to "-"ot;-"quot.

• Kyungpook Mathematical Journal
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• v.49 no.1
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• pp.123-131
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• 2009

In this paper, we study the signless Laplacian spectral radius of unicyclic graphs with prescribed number of pendant vertices or independence number. We also characterize the extremal graphs completely.

• Bulletin of the Korean Chemical Society
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• v.35 no.11
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• pp.3357-3359
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• 2014

• Bulletin of the Korean Chemical Society
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• v.23 no.3
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• pp.528-530
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• 2002

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.117-117
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• 2005

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2431-2434
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• 2012