• Title/Summary/Keyword: partition coefficients

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A Study on the Interaction with Preservatives and UV-Filters, Packaging Materials for Sunscreen Preservation (자외선차단제품의 방부력 확보를 위한 방부제와 자외선 차단제, 제품 포장재의 상관성 연구)

  • Park, Tae-Hun;Kwack, Il-Young;Jeon, Gi-Boong;Kim, Hyun-Hee;Kim, Han-Kon;Shin, Kye-Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.4
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    • pp.259-263
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    • 2010
  • We measured and compared the partition coefficients and absorption levels of preservative phenoxyethanol (PE), antimicrobial ethylhexylglycerin (EG) and UV-filters widely used in cosmetic products and more specifically evaluated the relative absorption level of PE depending on various packaging materials. The resulting partition coefficients of 11 UV filters in relation to PE and EG displayed EG with a relatively higher partition coefficients. The partition coefficients of Tinsorb M and Solaveil CT434 were also high. Among the UV-filter ingredients with EG absorption levels exceeding 40 % were Gransil PSQ, UV Titan M 160 and Micro $TiO_2$ MT 100 TV, whereas Gransil PSQ and Scadder showed PE absorption levels above 40 %. In addition, we confirmed that PE had displayed an absorption level of 7 ~ 8 % as a result of 1 month-long exposure to packaging material polyoxymethylene. This extensive research illustrates the possibility of producing the most potent preservative contents based on studying the relative compatibility between UV-filters and preservatives and selecting the adequate preservatives to be used. Furthermore, preservative level can also decline with passage of time depending on the type of packaging material used.

A Study on the Partition Coefficients for Sulfur Compounds Related Composition of LPG (LPG 조성에 따른 황화합물의 분배계수에 관한 연구)

  • Kim, Yeong Gu
    • Journal of the Korean Chemical Society
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    • v.46 no.6
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    • pp.523-527
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    • 2002
  • Partition coefficient related composition of LPG are studied. Analysed sulfur compounds are ethyl mer-captan,n-propyl mercaptan and n-butyl mercaptan. The composition of liquid phase and gas phase in LPG are deter-mined by gas chromatography. The partition coefficient to related the boiling point of sulfur compounds, the temperature and the compositions of solvents, determined by using MLR(multiple linear regression) of SAS is follows; Kpc= $0.61222({\pm}0.6578)-0.04670({\pm}0.000959)Bp+0.26984(\pm0.06504)C4+0.003803(^{\circ}ae0.0019993)Tk,$ N=24, F=14.851, $R^2_{adj}$=0.6437. The boiling points of sulfur compounds at atmospheric pressure and the compositions of LPG effect mostly on partition coefficients. It is presumed that the gas odor elevating effects should be increased, where being on high tem-perature and larger amounts of n-butane.

An Enhanced Wavelet Packet Image Coder Using Coefficients Partitioning (계수분할을 이용한 개선된 워이블릿 패킷 영상 부호화 알고리듬)

  • 한수영;김홍렬;이기희
    • Journal of the Korea Society of Computer and Information
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    • v.7 no.1
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    • pp.112-119
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    • 2002
  • We propose an enhanced wavelet packet image coder algorithm which is based on the coefficients partition. The proposed wavelet packet image coder uses the first-order entropy to reduce the total compression time, and achieves low bit rates and rate-distortion performance by the zero-tree based coding using correlations between coefficients partition. This new algorithm represents new parent-children relationships for reducing image reconstruction error using the correlations between each frequency subbands and then the wavelet packet coefficients are Partitioned by a new order. The computer simulations demonstrate higher PSNR under the same bit rate and improved image compression time and enhanced rate control compare with conventional algorithms. From the simulation results, it is shown that the encoding and decoding process of proposed coder are much simple and accurate than present method against texture images , which include many mid-frequency elements.

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불포화 토양내 유류성분의 포화도 평가를 위한 분배추적자의 활용 방안

  • Park Gi-Ho;Park Min-Ho;Sin Hang-Sik;Go Seok-O
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.20-28
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    • 2006
  • Partitioning tracer tests were conducted to quantify the saturation degree of diesel and water in unsaturated soil, respectively. The use of partitioning tracers that partition into diesel, water, and air (i.e., three-phase partitioning), is in attractive alternative to traditional coring and analysis method. These gaseous partition tracers not global warming gas like CFC's are Butane, Acetylene, Ethylene, Methylene chloride, and Methane. The glass column packed with sandy soil was prepared, in which a three-phase system of air, water, and diesel was maintained. Conservative and partition gas tracers were injected into the columns and detected easily using a single GC detector(FID). For each tracer, a method of moments was used to estimate partition coefficient between water, diesel. and the air, respectively. The results from the column studies showed that the diesel/air tracer partition coefficient ranged from 8.2 to 868 and 9.2 for water/air. Saturation degree of diesel and water in the column, predicted by the partition coefficients obtained from tests, was underestimated up to 66% and 23% respectively.

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A Study on Error-Resilient, Scalable Video Codecs Based on the Set Partitioning in Hierarchical Trees(SPIHT) Algorithm (계층적 트리의 집합 분할 알고리즘(SPIHT)에 기반한 에러에 강하고 가변적인 웨이브렛 비디오 코덱에 관한 연구)

  • Inn-Ho, Jee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.1
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    • pp.37-43
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    • 2023
  • Compressed still image or video bitstreams require protection from channel errors in a wireless channel. Embedded Zerotree Coding(EZW), SPIHT could have provided unprecedented high performance in image compression with low complexity. If bit error is generated by dint of wireless channel transmission problem, the loss of synchronization on between encoder and decoder causes serious performance degradation. But wavelet zerotree coding algorithms are producing variable-length codewords, extremely sensitive to bit errors. The idea is to partition the lifting coefficients. A many partition of lifting transform coefficients distributes channel error from wireless channel to each partition. Therefore synchronization problem that caused quality deterioration in still image and video stream was improved.

Nickel and cobalt partition coefficients in pyrite-pyrrhotite as geothermometer. (지질온도계로써 황철석과 자류철석내의 Ni와 Co의 분배 계수)

  • Yoo, Jae-Shin
    • Journal of the Speleological Society of Korea
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    • v.24 no.25
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    • pp.69-80
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    • 1991
  • 광화시기가 같은 유화광물중에서 상접하는 황철석과 자류철석 내에 함유되어 있는 코발트와 니켈의 함량을 정량분석하여 이들 원소들의 Partition Coefficients로부터 Bezmen method를 이용하여 광물의 생성온도를 구하였다(217~395$^{\circ}$). 지질 연대가 같은 유화광물의 생성온도는 동시기에 생성된 인접한 석영내의 유체포유물의 filling temperature와 거의 일치한다(255~395$^{\circ}$). 따라서 이들 광산내의 광물의 생성온도는 지질온도계로 사용이 가능하며 광물의 생성환경을 규명하는데도 유용할 것이다.

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Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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Thermodynamics of Partitioning of Substance P in Isotropic Acidic Bicelles

  • Baek, Seung Bin;Lee, Hyeong Ju;Lee, Hee Cheon;Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.743-748
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    • 2013
  • The temperature dependence of the partition coefficients of a neuropeptide, substance P (SP), in isotropic acidic bicelles was investigated by using a pulsed field gradient nuclear magnetic resonance diffusion technique. The addition of negatively charged dimyristoylphosphatidylserine to the neutral bicelle changed the SP partitioning a little, which implies that the hydrophobic interaction between the hydrophobic residues of SP and the acyl chains of lipid molecules is the major interaction while the electrostatic interaction is minor in SP binding in a lipid membrane. From the temperature dependence of the partition coefficients, thermodynamic functions were calculated. The partitioning of SP into the acidic bicelles is enthalpy-driven, as it is for small unilamellar vesicles and dodecylphosphocholine micelles, while peptide partitioning into a large unilamellar vesicle is entropy-driven. This may mean that the size of lipid membranes is a more important factor for peptide binding than the surface curvature and surface charge density.

Butyltin Compounds Concentrations in Masan Bay

  • CHOI Hee Gu;KIM Pyoung Joong;LEE Won Chan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.6
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    • pp.923-928
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    • 1997
  • The occurrence of butyltin compounds in the seawater and sediment of Masan Bay was investigated. The concentrations were in the range of $ND-0.059{\mu}g/\ell$ for tributyltin (TBT), $ND-0.091{\mu}g/\ell$ for dibutyltin (DBT) and $ND-0.720{\mu}g/\ell$ for monobutyltin (MBT) in the seawater, and $ND-0.233{\mu}g\;TBT/g.dry$, $ND-0.197{\mu}g-DBT/g.dry$ and $ND-0.684{\mu}g-MBT/g.dry$ in the sediment. Among the butyltin compounds, the major component in the seawater was MBT, while the predominant species in the sediment changed with time. The tributyltin concentrations in the sediment are approximately three orders of magnitude greater than the associated water column levels. Sediment/water partition coefficients (K) of TBT were between $0.6\times10^3\;and\;5.0\times10^3$.

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Remediation of Groundwater Contaminated with Zinc Using Permeable Reactive Barriers Containing Foundry Sands (주물사가 포함된 투수반응벽체(PRB)를 이용한 아연으로 오염된 지하수 처리기법 연구)

  • ;Benson, Craig H
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.159-167
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    • 2002
  • Partition coefficients for zinc vary on a broad range depending on properties of the foundry sands (TOC, clay content, total iron content) and solution pH. Among these properties, solution pH was found to be the most important factor. Empirical equations were developed from batch tests to predict partition coefscients and rate constants as a function of foundry sand properties and solution pH. Rate constants obtained from batch (kinetic) tests and batch sorption tests were found to be comparable when the solution pHs were comparable.