• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.653-660
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• 2006

Due to the stronger exhaust emission regulations and the introduction of advanced technology in Diesel engine, the specific Diesel particulate matters have decreased by about one order of magnitude since the 1980's. In recent years, particle number emissions rather than particulate mass emissions have become the subject of controversial discussions. Recent results from health studies imply that it is possible that particulate mass does not properly correlated with the variety of health effects attributed to Diesel exhaust. Concern is instead now focusing on nano-sized particles. This study has been performed for the better understanding about the Diesel nano-particle measurement and size distribution characteristics in the exhaust system of a turbo charged Diesel engine. A scanning mobility particle sizer(SMPS) system was applied to measure the particle number and size concentration of Diesel exhaust particles. As the experimental results, the number concentrations in the particle size (Dp<200 nm) were very sensitive to dilution conditions. Specially the changes in nano-particle number concentrations(Dp<50 nm) increased along the downstream of exhaust flow. Also we found the dilution conditions were influencing the condensation of SOF and $H_2O$ during dilution and cooling of hot exhaust.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.10a
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• pp.169-170
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• 2006

• Journal of Environmental Science International
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• v.13 no.12
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• pp.1067-1078
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• 2004

Atmospheric particulate matters were collected by 8-stage non viable cascade impactor from October 2002 to August at Jeju City. Eight water-soluble ionic components $(Na^+,\;NH_{4}_{+},\;K^+,\;Ca{2+},\;Mg^{2+},\;CI^-,\;NO_{3}^-\;and\;SO_{4}^{2-})$ were analyzed by Ion Chromatography. The concentration of particulate matters and eight water-soluble ionic components were determined to investigate their size distributions. Particulate matters exhibited a tri-modal distribution with peak value around $0.9,\;4.0{\mu}m\;and\;9.5{\mu}m.$ In summer, the last peak value was lower than other season values likely due to particulate matter scavenged by rain water. Four ionic components $(Na^+,\;Ca^{2+},\;Mg^{2+}\;and\;CI^-)$ exhibited a bi-modal distribution in the coarse mode whereas three ionic components $(NH_{4}^+,\;K^+\;and\;SO_{4}^{2-})$ in the fine mode, with maximum peak value around $0.9{\mu}m.\;NO_{3}^-$ was found in both the coarse and the fine mode. The enrichment factor (E.F.) of each ionic components was calculated. Based upon E.F., it is considered that $Na^+,\;CI^-,\;and\;K^+$ in coarse paricle mode were delivered form oceanic source, but other components might have other source origins.

• Journal of environmental and Sanitary engineering
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• v.9 no.1
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• pp.53-61
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• 1994

Sungnam city, as a major satellite town, is located in the southeast of Seoul. Atmospheric conditions are so stable that air pollutants from various emissions are tend to resist change because Sungnam city is located in the Namhansansung valley. The industrial distribution of Sungnam city are composed of various manufactories such as foods, fibers, chemicals, machinery and electronics etc. The heavy metal concentrations and size distribution are the most important parameters influencing among the way in which respirable suspended particulate matter interact with the human respiratory system. Respirable suspended particulate matter was collected on glass fiber filters from April 1993 to February 1994 according to particle size using Anderson sampler during 10 days per month at Sungnam city. 6 heavy metals, Fe, Zn, Pb Mn, Cu and Cd, were analyzed by particle size with atomic absorption spectrophotometry . The results could be summarized as follows: 1. The annual arithmetic mean concentration of total suspended particulate was 116.3$\mu $g/m$^{3}$ m', seasonal variation was the highest in spring season(196.5$\mu $g/m$^{3}$) and the lowest in Summer Season(72.9$\mu $g/m$^{3}$). 2. The ratio of airborne particulate concentrations respirable to nonrepairable( Res/Non- Res) of annual arithmetic mean value was 5.8'1, seasonal variation was highest in the spring season(6.3 : 1) and lowest in the summer season(4.6 : 1). 3. During the spring season the shape of the size distribution was trimodal which showed peaks at 3 size groups, which were below of 0.43$\mu $m, 3.3∼4.7$\mu $m and above of 11.0$\mu $g/m$^{3}$ respectively. 4. Respirable suspended particulate matter concentrations of Zn, Pb Cu and Cd were the highest in below of 0.43$\mu $m as follows; 0.517$\mu $g/m$^{3}$, 0.411 $\mu $g/m$^{3}$, 0.062$\mu $g/m$^{3}$ and 0.0310$\mu $g/m$^{3}$ , respectively, Fe and Mn were the highest in the particle size range of 4.7 ∼ 7.0$\mu $m as follows; 2.504$\mu $g/m$^{3}$ and 0.095$\mu $g/m$^{3}$, respectively. 5. The Pt Cd, Zn, Cu, Fe and Mn concentrations of annual arithmetic mean value respirable to non- respirable( Res/Non- Res ) were 33.65, 19.27, 17.74, 10.54, 3.20 and 5.20, respectively.

• Archives of Pharmacal Research
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• v.12 no.3
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• pp.214-218
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• 1989

Atmospheric particulate matters (A. P. M. ) were collected on quartz-fiber filters from March 1985 to May 1986, using the Andersen high-volume air sampler and contents of six heavy metals (Fe, Mn, Cu, Zn, Pb Ni) in the A. P. M. were determined by atomic absorption spectrophotometry. These heavy metals were divided into the three groups with respect to their particle size distribution. Fe and Mn were mainly associated with coarse particles (diameter > 2.0 $\mu$m), but Pb and Ni were related fine particles (diameter < 2.0 $\mu$m). Cu and Zn had mized size distributions in both of them. In the seasonal variation of heavy metals, the contents of Fe and Mn in spring and Ni and Pb in winter were higher than any other season. There were high mutual correlation between Fe and Mn coarse particles, and between Pb and Ni in fine particles.

• Journal of Preventive Medicine and Public Health
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• v.16 no.1
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• pp.67-77
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• 1983

To investigate the an air pollution by particulate matter and its dispersion, a cement plant produceing portland cement 600,000 ton/year and its vicinity were surveyed from Obtober, 1980 to April, 1983. The survey was mainly focused on main stack emmission rate of the cement plant and particle size distribution in the dust, dustfall and total suspended particulate concentration in the area by month and distance from the stack. The results of the study were as follows; 1. The main stack emission rate was surveyed before and after the spray tower was additionally installed to the original E.P bag filter. Before the spray tower installed, the main stack emission rate was higher ($0.64g/Nm^3$) than the emission standard of Korean Environmental Preservation Law's ($0.59g/Nm^3$, amended to $0.4g/Nm^3$ on April 1983), but after the spray tower was installed, its main stack emission rate was markedly decreased to the standard ($0.43g/Nm^3$). 2. $2{\sim}3{\mu}m$ of the particle size was the largest portion (20.8%) of the dust particulate from the main stack and 50% of the frequency distribution was $1.5{\mu}m$ of the size. Most particle size was below $10{\mu}m$. 3. The spray tower reduced the dustfall to $37.81{\sim}9.76\;ton/km^2/month$ while dustfall appeared at $45.29-15.45ton/km^2/month$, in the vicinity of plant before spray tower installed 4. Mean concentrations of total suspended particulate for 24 hours of the various stations were determined in $20.6-200.0{\mu}g/m^3$, 3 stations of tham were higher than the value of Harry and William's arthmetic average standard $130{\mu}g/m^3$. 5. Linear regression between dustfall [X] and total suspended particulate[Y] concentration was an equation, Y=4.024X+11.479.[r=0.91] 6. During the whole seasons in the opposite area 100m apart from the omission source the prevailing wind direction was with estimated more than $30ton/km^2/month$, and the concentration of total suspended particulate for 24 hours averaging time was more than $140{\mu}g/m^3$ in the same area and direction. 7. Assuming the wind direction were constant through the day dustfalls for a day were estimated at $13.40ton/km^2/day,\;10.79ton/km^2/day$ and $4.55ton/km^2/day$ at various distances of 100m, 500m and 1,500m from the emission source respectively. 8. In the simutalion of dustfall and suspended dust by area, Gaussian dispersion model modified by size distribution of particulate matter was not applicated since the emission of dust were from multi sources other them stack. From the above results, it could be applied that the dispersion of dust from the cement plant is estimated and regulated for the purpose of environmental protection.

• Journal of Environmental Health Sciences
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• v.30 no.2
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• pp.154-160
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• 2004

The purpose of this study was to evaluate airborne concentrations and characteristics of TSP, IPM, TPM and RPM in Seoul subway stations. Sampling was performed at 14 stations from April 11 to 29, 2002. Size-selective dust concentrations and metal concentrations were measured by gravimetric method and ICP-AES, respectively. The geometric mean of TSP, IPM, TPM and RPM concentrations in Seoul subway stations were 176$\mu\textrm{g}$/㎥, 348$\mu\textrm{g}$/㎥, 158$\mu\textrm{g}$/㎥ and 104$\mu\textrm{g}$/㎥, respectively. Dust concentrations in pathway were the highest and those in lobby were the lowest. The size distribution of dusts was significantly different by location of collection. When the deposition rate into pulmonary gas exchange region was estimated by size distribution, the deposition rate of dust collected from platform was higher than those of dust collected from lobby and pathway. The lower the basement levels were, the higher the deposition rates of dusts into tracheobronchial region and gas exchange region were. Copper and iron concentrations measured in platform higher were than those in other areas.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.2
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• pp.57-66
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• 1988

Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul and suspended particulate was collected by Andersen air sampler during this period. The samples were analyzed for 16 components $(SO_n^{2-}, NO_3^-, Cl^-, PO_4^{3-}, NH_4^+, F^-, Al, Fe, K, Cu, Mn, Na, Pb, Mg, Ca, Cd)$. The conclusions are as follwes: 1. Total suspended particulate concentation during the period of sandy dust phenomena was 489 $\mug/m^3$ (ordinary times: 140-125 $mug/m^3$) 2. The water - soluble ion component concentration of suspended particulate during the period of sandy dust phenomena was few and the metal concentration of that was more than that of ordinary times. 3. The cumulative frequency distribution of suspended particulates in logarithmic diagram did not show similar to normal log distribution during the period of sandy dust phenomena. 4. $SO_4^{2-}, NO_3^-, Cl^-, and PO_4^{3-}$ was onsided to coarse particle, and $NH_4^+$ and F to fine particle in the size distribution of water - soluble ion components during the period of sandy dust phenomena. 5. Metal concentration was high and Al, Fe, Cu, Mn, Na, Mg, and Ca was onsided to coarse particle, and K, Pb, and Cd to fine particle in the size distribution of metal components. 6. During the period of sandy dust phenomena the quantity of respirable particle (< 1 $\mum$) was about 3 times and that of metal components were about 2 - 11 times than that of ordinary times. 7. The concentrations of $NO_3^-, Cl^-, NH_4^+$ at ordinary times were 1.1 - 4 time than that of the period of sandy dust phenomena.

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.1
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• pp.20-28
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• 1992

The x-ray fluorescence(XRF) is one of the most convenient and widely used techniques for analyzing trace elements in ambient particulate matters. The objects of the study were to estimate the optimum exposure time using the XRF, to investigate the distributions of heavy metal levels in particulate matters, and finally to study seasonal variation for the concentrations of total suspended particulate matters(TSP) and size fractionated particulate matters. The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 3 years(Dec. 1988 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentrations were determined by the XRF system. Thus, seasonal variations and relationship between concentration and particle size could be investigated. Resulting distribution was bimodal with the coarse and the fine particle groups minimum occurring around 2.1 to 3.3 $\mu$m as an aerodynamic diameter. To determine optimum exposure time of the XRF for various trace inorganic elements, membrane filters and the NIST standard filters were extensively studied. Using a statistical technique, optimum exposure time was estimated for each trace element and overall elements. The time was then determined as 20 seconds for the XRF system. The concentration of TSP was 123.9$\mum/m^3$ on an arithmatic average. The levels of each inorganic metal were Si 2420.0ng/$m^3$, Fe 977.1ng/$m^3$, and so on. The Pb. Zn, and Cu abounded in the fine mode group, while Ca, Fe, Si, Al, and K in the coarse group. Marked seasonal variation of TSP and metal concentrations was observed. The concentration of heavy metals in the fine mode was highest in winter : on the other hand, that in the coarse mode was highest in spring.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.18 no.3
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• pp.177-184
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• 2008

The purpose of this study was to compare the performance characteristics of Andersen and total suspended particulate (TSP) samplers in terms of particle size distribution (PSD) and mass sampling efficiency. In the present study, two Andersen and four TSP samplers were selected and tested to quantitatively estimate human exposure to fly ash representing industrial particulate matter (PM) in a carefully controlled chamber. The PSD characteristics, a mass median aerodynamic diameter and a geometric standard deviation, were found from the sampled PM of airborne samplers in the chamber. An Andersen sampler was compared with a TSP sampler quantified by a coulter counter multisizer, as a reference sampler, to describe the correlation of mass sampling efficiencies between two types of samplers. Overall results indicate that Andersen samplers overestimated small PM due to particle bounce phenomena between impaction stages. There was reasonably good correlation ($R^2$ = 0.89 and 0.91) between the mass sampling efficiencies of Andersen and TSP samplers during the two tests. However, the lower values of slope (0.71 and 0.72) in two tests showed that the Andersen sampler underestimated PM (> AD $10.1\;{\mu}m$) with sufficient inertia due to a relatively lower Andersen inlet velocity at 0.8 m/s comparing with the operating air velocity at 2.1 m/s in the sampling zone of a chamber.