• 제목/요약/키워드: particle site analysis

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오염원에 따른 토양 입경 별 비소의 오염특성 및 생물학적 접근성 평가 (Effects of Contamination Source and Particle Size on Arsenic Speciation and Bioaccessibility in Soils)

  • 권예슬;김은정
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제22권5호
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    • pp.89-97
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    • 2017
  • In this study, we evaluated effect of particle size on arsenic solid-state speciation and bioaccessibility in soils highly contaminated with arsenic from smelting and mining. Soils were partitioned into six particle size fractions ($2000-500{\mu}m$, $500-250{\mu}m$, $250-150{\mu}m$, $150-75{\mu}m$, $75-38{\mu}m$, <$38{\mu}m$), and arsenic solid-state speciation and bioaccessibility were characterized in each particle size fraction. Arsenic solid-state speciation was characterized via sequential extraction and XRD analysis, and arsenic bioaccessibility was evaluated by SBRC (Solubility Bioaccessibility Research Consortium) method. In smelter site soil, arsenic was mainly present as arsenic bound to amorphous iron oxides. Fine particle size fractions showed higher arsenic concentration, but lower arsenic bioaccessibility. On the other hand, arsenic in mine site soil showed highest concentration in largest particle size fraction ($2000-500{\mu}m$), while higher bioaccessibility was observed in smaller particle size fractions. Arsenic in mine site soil was mainly present as arsenolite ($As_2O_3$) phase, which seemed to affect the distribution of arsenic and arsenic bioaccessibility in different particle size fractions of the mine soil.

SEM/EDX 분석법을 이용한 침착먼지에 대한 분석사례 (Analysis of Deposited Dust Particles using SEM/EDX)

  • 하은지;박정호
    • 한국환경과학회지
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    • 제30권3호
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    • pp.279-287
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    • 2021
  • In this study, the composition and morphology of deposited dust particles with size ranging from a few to tens ㎛ were investigated using SEM/EDX (scanning electron microscopy with energy dispersive x-ray spectrometer). Then deposited dust particles were classified into 8 groups: quartz, aluminosilicates, ca-rich, Fe/Ti oxide, carbon-rich, industrial particle, Fe-rich, and biogenic particle. The sources of deposited dust were high in the order of aluminosilicates 41% > biogenic 18% > Fe-rich 11% > quartz and C-rich 8% > industrial 7% > Fe/Ti oxide 5% > Ca-rich 1%. In particular, the ratio of biogenic particles was relatively high due to influence of pollen. The ratio of carbon-rich was 11% at YM site, 10% at MD site, and 4% at MO site, and the site close to the large emission source was high.

USGA 공법으로 조성된 그린의 토앙물리성과 Bentgrass의 생육 (Turfgrass Establishment of USGA Putting Greens Related with Soil Physical Properties)

  • 권동영;이정호;이동익;주영규
    • 아시안잔디학회지
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    • 제19권2호
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    • pp.95-102
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    • 2005
  • USGA green specification is currently accepted in construction method of Korea. This study was carried out to find the factors influencing growth of turfgrass associated with soil physical properties of soil root-zone on golf green constructed with USGA method. Three putting greens in poor turfgrass and one in good turfgrass condition were selected for investigation on one golf course site at mid-South Korean peninsula. Soil hardness, moisture content, root length, and turf density were measured on-site greens, and soil physical properties and soil chemical properties also analyzed in laboratory. As a result of on-site surveys and soil physical tests in laboratory, soil physical properties were most important factors which influenced on turfgrass growth at tested greens. The results of soil particle analysis on green No. 2, in good turf condition, matched USGA sand particle recommendations. But those greens such as Nos. 1, 11 and 16, in poor putting greens, showed high soil compaction and improper soil particle distribution. Those factors created low leaf density, poor root depth, and higher moisture content compared with lower part of topsoil. Such phenomena caused inadequate turfgrass growth with soil hardening associated with poor drainage. Therefore, declines of soil physical properties associated with improper particle distribution caused a major factor influencing on turfgrass growth in golf green. Adequate test of soil particle analysis by USGA specification and proper construction method followed by adequate turf maintenance should be performed to obtain optimal turf quality on putting green.

발파진동에 대한 인접한 지상 저장탱크의 안정성 평가 (Stability Assessment of an Adjacent Ground Storage Tank by Blast-induced Vibration)

  • 정용훈;이정인;최용근
    • 한국소음진동공학회논문집
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    • 제16권1호
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    • pp.19-26
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    • 2006
  • The test blasts were carried out by detonating some single blastholes at two upper sites of the underground storage cavern for the crude oil. One was performed at the entrance site of the construction tunnel and the other at the middle area of the underground storage cavern. Based on the blast-induced nitration measured by the test blasts, we suggested the propagation equations of blasting vibration that were capable of estimating the peak particle velocity. In addition, in order to assess the stability of the adjacent ground storage tank, we did the frequency analysis and the response spectrum analysis with the particle velocity-time history and the particle acceleration-time history that were measured by the test blast carried out on the entrance site of the construction tunnel. In result, it was predicted that the displacement on the highest part of the tank shell was less than the allowable displacement.

발파진동에 대한 구조물 안정성 평가 - 지하비축기지 건설 사례 (A Case Study on the Stability Assessment of Structures by Blast-induced Vibration)

  • 이정인;최용근;정용훈
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 추계학술대회논문집
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    • pp.479-484
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    • 2005
  • The test blasts were carried out by detonating some single blastholes at two upper sites of the underground storage cavern the crude oil. One was performed at the entrance site of the construction tunnel and the other at the middle part of the underground storage cavern. Based on the blast-induced vibration measured by the test blasts, we suggested the propagation equations of blasting vibration that were capable of estimating the peak particle velocity. In addition, in order to assess the stability of the nearest ground storage tank, we did the frequency analysis and the response spectrum analysis with the particle velocity-time history and the particle acceleration-time history that were measured by the test blast carried out on the entrance site of the construction tunnel. In result, it was predicted that the displacement on the highest part of the tank shell was less than the allowable displacement.

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장항제련소 주변 비소오염토양의 특성분석에 따른 토양세척 처리효율 평가 (Assessment of Soil Washing Efficiency for Arsenic Contaminated Site Adjacent to Jang Hang Refinery)

  • 문소영;오민아;정준교;최상일;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권1호
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    • pp.71-81
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    • 2011
  • Cause of contamination in the study area nearby Jang Hang Refinery is dust scattering in refinery stack, and soil washing treatment is one of the proper technologies for soil remediation in this area. Site conditions frequently limit the selection of a treatment process. A treatment technology may be eliminated based on the soil classification or physicochemical characteristics of soil. This study was assessed the soil washing efficiency by conducting of soil characteristic analysis in the vicinity of Jang Hang Refinery Stack within a 2 km radius. Also, it was decided about remedial range with comparative analysis of As in soil by Korean Standard Test Method before/after revision, whereupon As concentration in soil showed a increasing tendency after revision. As a result, the soil washing using the size separation of soil was determined through identifying of As species in the soil. In this site, only particle size distribution and water content of soil can provide the initial means of screening for the potential use of soil washing.

Low-Z Particle Electron Probe X-ray Microanalysis법을 이용한 2001년 ACE-Asia 집중 측정 기간 중 제주도 고산에서의 입자상 물질의 특성분석 (Single Particle Characterization of Aerosol Particles Collected at Jeju Island, Korea, During 'ACE-Asia' Intensive Observation Period, Using Low-Z Particle Electron Probe X-ray Microanalysis)

  • 안용훈;김혜경;노철언
    • 한국대기환경학회지
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    • 제20권6호
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    • pp.811-821
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    • 2004
  • Low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA) was applied to characterize aerosol particles collected at Gosan in Jeju island during an IOP (intensive observation period) for an international ACE-Asia project in April, 2001. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, sodium nitrate, sodium chloride, and ammonium sulfate were observed. The reacted sea salt particles such as sodium nitrate were the most abundantly encountered, but original sea salt particles were rarely observed. Since the Low-Z particle EPMA can provide quantitative information on the chemical composition of aerosol particles, many different particle types on the basis of their chemical compositions were observed and identified. In this study, it is demonstrated that the Low-Z particle EPMA can provide detailed information on the chemical compositions for the aerosol particles collected for six consecutive days in April, 2001, at Gosan super-site.

Ionic Compositions of PM10 and PM2.5 Related to Meteorological Conditions at the Gosan Site, Jeju Island from 2013 to 2015

  • Song, Jung-Min;Bu, Jun-Oh;Lee, Jae-Yun;Kim, Won-Hyung;Kang, Chang-Hee
    • Asian Journal of Atmospheric Environment
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    • 제11권4호
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    • pp.313-321
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    • 2017
  • $PM_{10}$ and $PM_{2.5}$ were collected at the Gosan Site on Jeju Island from 2013 to 2015, and their ionic and elemental species were analyzed to examine the variations in their chemical compositional characteristics related to different meteorological conditions. Concentrations of nss-$SO_4{^{2-}}$ and $NH_4{^+}$ were respectively 6.5 and 4.7 times higher in the fine particle mode ($PM_{2.5}$) compared to the coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentrations were 2.4 times higher in the coarse mode compared to the fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased to 8.2 and 5.0 times higher in $PM_{10}$, and 3.5 and 6.0 times higher in $PM_{2.5}$, respectively. During haze days, the concentrations of secondary pollutants increased by 3.1-4.7 and 3.2-7.9 in $PM_{10}$ and $PM_{2.5}$, respectively, and they were, respectively, 1.2-2.1 and 0.9-2.1 times higher on mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in the fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. Clustered back trajectory analysis showed that concentrations of nss-$SO_4{^{2-}}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when air masses travelled from China.

이차원 개별요소 수치해석을 통한 화강풍화토의 평균입자크기와 전단강도의 관계 규명 (Examination of the Relationship between Average Particle Size and Shear Strength of Granite-derived Weathered Soils through 2-D Distinct-element Method)

  • 김선욱;임희대
    • 한국지반공학회논문집
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    • 제28권12호
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    • pp.77-86
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    • 2012
  • 본 연구에서는 개별요소법을 적용하여 화강암 기원의 풍화토에서 입자 크기와 입자크기 분포 특성 중 최대입경/최소입경의 비가 강도정수에 미치는 영향을 살펴보았다. 입자크기와 입도분포가 변화할 때의 전단강도 특성 변화를 규명하기 위하여 개별요소법 수치해석을 실시하였다. 점착력이 0.25MPa, 내부마찰각이 $29^{\circ}$인 강도특성을 갖는 기준시료를 수치해석적으로 구현한 후, 간극률을 기준시료와 동일하게 유지하면서 입자의 크기와 입도분포를 바꾸어 가며 점착력과 내부마찰각의 변화를 살펴보았다. 수치해석결과 평균입자의 크기가 커질수록 점착력의 현저한 감소가 관찰되었으며, 내부마찰각의 변화는 미미하지만 증가하는 경향을 보였다. 이러한 연구결과는 입도만을 이용하여 간편하게 화강풍화토의 강도정수 산정 시 활용될 수 있을 것으로 판단된다. 특히 풍화상태가 점이적으로 변화하는 화강풍화토의 경우, 현장시험과 실내시험을 통하여 일부 구간에서 측정된 입도-강도 자료가 있을 때, 이러한 시험들이 수행되지 않은 구간에 대해서도 입도분포를 통해 간편하게 강도특성을 규명할 수 있을 것으로 여겨진다.

강하분진의 침적 특성파악을 위한 통계학적 해석과 공간분포 분석 (A Statistical Analysis and Spatial Distribution Analysis for Deposition Characteristics of Fall-out Particles)

  • 주재희;황인조
    • 한국대기환경학회지
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    • 제28권3호
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    • pp.294-305
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    • 2012
  • The objective of this study is to estimate the chemical compositions and to identify qualitative sources of fall-out particles in study area. Also, this study used a spatial analysis to estimate spatial distributions and average deposition flux. In this study, the chemical compositions of fall-out particle samples collected at Muncheon lake from May 2010 to January 2011 were analyzed by ICP and IC. The monthly trend of deposition fluxes for fall-out particles showed highest in June ($107.61kg/km^2/day$) and lowest in October ($22.22kg/km^2/day$). The average fluxes of Fe, Si, Al, Zn and Ba are 0.44, 0.24, 0.20, 0.17, $0.09kg/km^2/day$, respectively. Also, the average fluxes of $NO_3^-$, $SO_4^{2-}$, $NH_4^+$, $Ca^{2+}$, and $Na^+$ are 6.48, 5.01, 4.96, 1.75, $1.37kg/km^2/day$, respectively. A Factor analysis identified four sources such as 1) nonferrous metal, motor vehicle, and agriculture, 2) soil, 3) field burning, incineration, and 4) road dust and oil burning. The IDW (inverse distance weighting) spatial analysis method was used to estimate spatial distribution and average deposition flux for fall-out particles. A total average deposition fluxes estimated in Muncheon lake were 936.15 kg/month. The spatial distribution trend of deposition flux showed higher at site 1 and 2 than at site 3, 4 because local road is adjacent to the site 1 and 2.