• Title/Summary/Keyword: partial melting

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Texturing of YBa$_2Cu_3O_x$ thick film on MgO(001) single crystal (YBa$_2Cu_3O_x$ 후막의 단결정 MgO(001) 위에서의 배향화)

  • Kim, Eu-Gene;Kim, Myeong-Hui;Han, Young-Hee;Sung, Tae-Hyun;Kim, Sang-Joon;No, Kwang-Soo
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.271-274
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    • 1999
  • We are investigating epitaxially grown YBa$_2Cu_3O_x$(123) on MgO single crystal by partial melting process for high power application. After fabricating of BaCuO$_2$(011), Y$_2BaCuO_5$(211) powder, we made YBa$_2Cu_3O_x$(123) Paste with just mixing of (211), (011) and CuO(001) powders. Screen printing method was used to coat YBa$_2Cu_3O_x$(123) paste on MgO single crystal. To reduce the reaction in low temperature, rapid heating was conducted at partial melting temperature. The film was analysed with the difference of cooling-rate, thickness, reaction temperature by XRD, SEM, in-plane alignment, out-of-plane alignment, temperature-resistivity characteristics.

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Petrochemical Characteristics and Review on Petrogenesis on Cretaceous to Tertiary Volcanic Rocks in the Kyongsang Basin (경상분지 백악기~제3기 화산암류의 암석화학적 특징과 암석 성인 고찰)

  • Sung, Jong-Gyu;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.217-233
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    • 2012
  • Major elements abundances of Cretaceous to Tertiary volcanic rocks in Kyongsang basin are similar with Southern Volcanic Zone (SVZ) in Andes. Sr, K, Rb, $Ba{\pm}Th$ abundances, which have low ionic charge, are selectively fertile, on the other hand Ta, Nb, Ce, P, Zr, Hf, Sm, Ti, Y, Yb, Sc, Cr abundances are low. K, Sr, Th show characteristic spikes and Nb show remarkable trough on trace elements spider diagram. Trace elements abundances are higher than that of Andes which is supposed to mantle sources of Kyongsang basin volcanic rocks are produced lower degree of partial melting than SVZ in Andes.

Technique development of Bi-2212/2223 superconductor thick film manufacturing by plasma spraying and heat treatment (플라즈마 용사 및 열처리 공정을 통한 Bi-2212/2223 초전도체 thick film 제조의 기술 개발)

  • Lee, Seon-Hong;Cho, Sang-Hum;Ko, Young-Bong;Park, Kyeung-Chae
    • Proceedings of the KWS Conference
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    • 2005.11a
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    • pp.262-264
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    • 2005
  • $Bi_{2}Sr_{2}CaCu_{2}O_{x}$(Bi-2212) and $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{y}$(Bi-2223) high-$T_{c}$ superconductor(HTS) coating have been prepared by plasma spraying and heaat treatment. The Bi-2212 HTS coating later is synthesized through the peritectic reaction between Sr-Ca-Cu oxide coating layer and Bi-Cu oxide coating later, and $Bi_{2}Sr_{2}CaCu_{2}O_{y}$(Bi-2212) superconducting phase grow by partial melting process. The superconducting characteristic depends strongly on the conditions of the partial melting process. the Bi-2212 HTS layer consists of the whiskers grown in the diffusion direction. Above the 2212 layer, Bi-2223 phase and secondary phase was observed. The secondary phase is distributed uniformly over the whole surface. This is caused to the microcrack on the coatings surface. Despite everything, the film shows superconducting with an onset $T_{c}$ of about 115K. There are two changes steps. One changes (1step) at 115K is due to the diamagnetism of the Bi-2223 phase and the other changes (2step) at 78K is due to the diamagnetism of the Bi-2212 phase.

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Rapid Fabrication of Bi2212 Superconducting Films on Cu Tape with Cu-free Precursor (Cu-free 전구체를 이용한 동 테이프 위의 Bi2212 초전도 후막의 급속 제조)

  • 한상철;성태현;한영희;이준성;김상준
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.69-72
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    • 1999
  • A Well oriented Bi$_2$re$_2$CaCu$_2$O$\sub$8/(Bi2212) superconductor thick films were formed successfully on a copper substrate by liquid reaction between a Cu-free precursor and Cu tape using method in which Cu-free BSCO powder mixture was printed on copper plate and heat-treated. And we examined the mechanism for the rapid formation of Bi2212 superconducting films from observing the surface microstructure with heat-treatment time. At heat-treatment temperature, the printing layer partially melt by reacting with CuO of the oxidizing copper plate, and the nonsuperconducting phases present in the melt are typically Bi-free phases and Cu-free phases. Following the partial melting, the Bi$_2$Sr$_2$CaCu$_2$O$\sub$8/ superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows. It was confirmed that the phase colony from the phase diagram of Bi$_2$O$_3$-(SrO+CaO)/2-CuO system is similar to the observed result.

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Volcanism and Petrogenesis of Dodong Basaltic Rocks in the Ulleung Island, East Sea (울릉도 도동현무암질암류의 화산작용과 암석성인)

  • Hwang, Sang Koo;Kim, Jae Ho;Jang, Yundeuk
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.361-371
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    • 2017
  • We investigated geochemical characteristics of the Dodong Basaltic Rocks in the lower part of the Ulleung Island. They have lithological range of alkali basalt to trachybasalt, belonging to Na and K subseries of alkaline series. They mostly fall within the field of alkalline within-plate basalts on tectonic discrimination diagrams, and then plot in the field of oceanic island basalt (OIB). Geochemically, extension of lithospheric mantle and asthenospheric upwelling after East Sea under an Cenozoic extensional tectonic setting might be a heat source for partial melting of the enriched lithospheric mantle, which might generate the basaltic magma. But we cannot exclude that mantle plume might also be a heat source for melting of the lithospheric mantle.

Geochemistry and Petrogenesis of Pan-african Granitoids in Kaiama, North Central, Nigeria

  • Aliyu Ohiani Umaru;Olugbenga Okunlola;Umaru Adamu Danbatta;Olusegun G. Olisa
    • Economic and Environmental Geology
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    • v.56 no.3
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    • pp.259-275
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    • 2023
  • Pan African granitoids of Kaiama is comprised of K-feldspar rich granites, porphyritic granites, and granitic gneiss that are intruded by quartz veins and aplitic veins and dykes which trend NE-SW. In order to establish the geochemical signatures, petrogenesis, and tectonic settings of the lithological units, petrological, petrographical, and geochemical studies was carried out. Petrographic analysis reveals that the granitoids are dominantly composed of quartz, plagioclase feldspar, biotite, and k-feldspar with occasional muscovites, sericite, and opaque minerals that constitute very low proportion. Major, trace, and rare earth elements geochemical data reveal that the rocks have moderate to high silica (SiO2=63-79.7%) and alumina (Al2O3=11.85-16.15) contents that correlate with the abundance of quartz, feldspars, and biotite. The rocks are calc-alkaline, peraluminous (ASI=1.0-<1.2), and S-type granitoids sourced by melting of pre-existing metasedimentary or sedimentary rocks containing Al, Na, and K oxides. They plot dominantly in the WPG and VAG fields suggesting emplacement in a post-collisional tectonic setting. On a multi-element variation diagram, the granitoids show depletion in Ba, K, P, Rb, and Ti while enrichment was observed for Th, U, Nd, Pb and Sm. Their rare-earth elements pattern is characterized by moderate fractionation ((La/Yb)N=0.52-38.24) and pronounced negative Eu-anomaly (Eu/Eu*=0.02-1.22) that points to the preservation of plagioclase from the source magma. Generally, the geochemical features of the granitoids show that they were derived by the partial melting of crustal rocks with some input from greywacke and pelitic materials in a typical post-collisional tectonic setting.

Nd1+XBa2-XCu3O7-δ Bulk Superconductor by Zone-melt Process

  • Soh, Dea-Wha;Guo, Fan-Zhan
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.3
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    • pp.21-24
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    • 2002
  • Two kinds of $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$, the sintering samples and zone melting samples, were heat-treated under pure Ar at 950$^{circ}C$. The substitution of Nd ion for Ba ion in the $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$ before and after the heat treatment was investigated by XRD. In order to confirm the effects of the heat treatment, the Tc and Jc of samples with/without the heat treatment under Ar were comparatively studied. $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$ samples were oxygenated under pure oxygen at $300^{circ}C$. From the XRD pattern it was found that the sample with x<0.4 was transferred from tetragonal phase to orthorhombic phase after the oxygenation, while the sample with x>0.4 did not show the phase transition even after a long time oxygenation. Therefore, the low oxygen partial pressure (Ar+1 % O$_2$) was used for the ambient atmosphere of the zone-melting samples, which could reduce the melting temperature and depress the substitution of Nd for Ba. After the improvement in the zone-melting process, the Jc value was increased to 2 x $10^4$A/$cm^2$ (0 T, 78 K). The particle orientation and the structure of zone-melted NdBaCuO were studied by the XRD and SEM analysis.

Evaluation on Liquid Formability of Bulk Amorphous Alloys (벌크비정질합금의 액상 성형성 평가)

  • Joo, Hye-Sook;Kang, Bok-Hyun;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.26 no.5
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    • pp.227-231
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    • 2006
  • Liquid formability of bulk amorphous alloys is known to be very poor due to their high viscosity comparing with conventional metallic materials. It is important to have the fabricating technology of bulk amorphous alloys in order to make the components with complicated shape. Liquid formability includes the mold cavity filling ability and the hot tear(crack) resistance during solidification. A mold made of a commercial tool steel for the formability test was designed. Melting was performed by the arc melting furnace with melting capacity of 200 g in an argon atmosphere. Liquid formability and glass forming ability of Cu base and Ni base bulk amorphous alloys were measured and evaluated. Mold filling ability of Ni-Zr-Ti-Si-Sn alloy was better than that of Cu-Ni-Zr-Ti alloy, however the reverse is the hot tear resistance. Bulk amorphous alloy is very susceptible to crack if partial crystallization occurs during solidification. Crack resistance was thought to be closely related with the glass forming ability.

High $T_c$ Superconducting Thick Film for Applications

  • Soh, Deawha;Park, Seongbeom;Wang, Jue;Li, Fenghua;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05b
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    • pp.12-15
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    • 2003
  • The YBaCuO thick film was deposited by the electrophoresis in the solution with different dimension particles. The morphology of the films deposited from different particles size was compared. The powder made by sol-gel method has the submicron particles, which deposit the most smooth film, and without microcracks after sintering. After sintering of the deposited film, the zone-melting process was carried out in low oxygen partial pressure (100 Pa) and Ag was used as substrate. And the zone-melted YBaCuO was studied by XRD.

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Preliminary Study on the Ultramafic Rocks from the Chungnam Province, Korea (충남지역에 분포하는 초염기성암의 기원규명을 위한 기초연구)

  • Wee, Soo-Meen;Choi, Seon-Gyu;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.27 no.2
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    • pp.171-180
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    • 1994
  • Several ultramafic bodies and ultramafic origin talc deposits are distributed in Chungnam province near the contact zone with Ogchun fold belt They occur as discontinued belt form with northeast trending, and most of them are more or less sepentinized. Major, trace, and rare earth elements analyses were made of the ultramafics from the study area to constrain their origin and genetic relationships. Compared to the primitive mantle estimates of privious workers, the correlations defined by the studied rock samples indicate similar Ni but very lower $Al_{2}O_{3}$, CaO and $TiO_{2}$ contents. It is inferred that source material of the studied rocks might be residual mantle which had undergone a large degree of partial melting event. The REE patterns show relatively flat to enriched in LREE (chondrite normalized La/Yb and Sm/Yb ratios are 1.1-5.2 and 1.2-1.6). Several alternative explaination are possible for LREE enrichment patterns in the studied ultramafic rocks such as 1) enrichment due to late stage alteration, 2) enriched pre-melting composition, and 3) mixing of two components. Based on the result, the LREE enrichment characteristic of the studied rocks might be result from the mixture of two geochemically distinct components; one is depleted residual mantle and the other component which determine the abundances of incompatible elements and responsible for the LREE enrichment.

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