• Progress in Superconductivity and Cryogenics
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• v.24 no.3
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• pp.19-23
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• 2022

We have been developing a magnetic separation device that can be used in low magnetic fields for paramagnetic materials. Magnetic separation of paramagnetic particles with a small particle size is desired for volume reduction of contaminated soil in Fukushima or separation of iron scale from water supply system in power plants. However, the implementation of the system has been difficult due to the needed magnetic fields is high for paramagnetic materials. This is because there was a problem in installing such a magnet in the site. Therefore, we have developed a magnetic separation system that combines a selection tube and magnetic separation that can separate small sized paramagnetic particles in a low magnetic field. The selection tube is a technique for classifying the suspended particles by utilizing the phenomenon that the suspended particles come to rest when the gravity acting on the particles and the drag force are balanced when the suspension is flowed upward. In the balanced condition, they can be captured with even small magnetic forces. In this study, we calculated the particle size of paramagnetic particles trapped in a selection tube in a high gradient magnetic field. As a result, the combination of the selection tube and HGMS (High Gradient Magnetic Separation-system) can separate small sized paramagnetic particles under low magnetic field with high efficiency, and this paper shows its potential application.

• Progress in Superconductivity and Cryogenics
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• v.25 no.3
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• pp.13-17
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• 2023

Magnetic separation technology for small paramagnetic particles has been desired for the volume reduction of contaminated soil from the Fukushima nuclear power plant accident and for the separation of scale and crud from nuclear power plants. However, the magnetic separation for paramagnetic particles requires a superconducting high gradient magnetic separation system applied, hence expanding the bore diameter of the magnets is necessary for mass processing and the initial and running costs would be enormous. The use of high magnetic fields makes safe onsite operation difficult, and there is an industrial need to increase the magnetic separation efficiency for paramagnetic particles in as low a magnetic field as possible. Therefore, we have been developing a magnetic separation system combined with a selection tube, which can separate small paramagnetic particles in a low magnetic field. In the previous technique we developed, a certain range of particle size was classified, and the classified particles were captured by magnetic separation. In this new approach, the fluid control method has been improved in order to the selectively classify particles of various diameters by using a multi-stage selection tube. The soil classification using a multi-stage selection tube was studied by calculation and experiment, and good results were obtained. In this paper, we report the effectiveness of the multi-stage selection tube was examined.

• Proceedings of the Korean Magnestics Society Conference
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• 2003.12a
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• pp.255-255
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• 2003

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.1
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• pp.11-17
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• 2007

The spherical NiZn ferrite particles were prepared by ultrasonic spray pyrolysis with mixed solution of aqueous metal nitrates. The NiZn ferrite particle was observed with nano-sized primary particles of about 10 nm or less before annealing which represented as paramagnetic behavior measured at 77 K and room temperature. The typical abnormal growth of primary particles like polyhedral primary particles was observed by annealing at 1273 K with Zn-concentration dependency. The XRD patterns showed good crystallinity of NiZn ferrite powder after annealing. In annealing process, the intra-particle sintering phenomenon was observed and the spherical particle morphology was collapsed at 1673 K. The saturation magnetization of NiZn ferrite powder for each annealing temperature was decreased with measuring temperature of $77{\sim}$300K.

• Progress in Superconductivity and Cryogenics
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• v.24 no.3
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• pp.7-11
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• 2022

We are conducting research and development of magnetic filters for magnetic separation targeting paramagnetic materials. In order to develop a new magnetic filter with a large magnetic gradient, stainless fiber (SUS430, 120 mm × 3 mm) with a triangular cross section was sintered with a high void ratio (~ 70%) and the magnetic filter (20 mm × 2 mm) was created. When this magnetic filter was used to perform magnetic separation of hematite (particle size 50 ㎛) under a maximum magnetic flux density of 1.49 T, high separation rates were obtained.

• Progress in Superconductivity and Cryogenics
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• v.18 no.1
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• pp.10-13
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• 2016

In this study, we developed a new volume reduction technique for cesium contaminated soil by magnetic separation. Cs in soil is mainly adsorbed on clay which is the smallest particle constituent in the soil, especially on paramagnetic 2:1 type clay minerals which strongly adsorb and fix Cs. Thus selective separation of 2:1 type clay with a superconducting magnet could enable to reduce the volume of Cs contaminated soil. The 2:1 type clay particles exist in various particle sizes in the soil, which leads that magnetic force and Cs adsorption quantity depend on their particle size. Accordingly, we examined magnetic separation conditions for efficient separation of 2:1 type clay considering their particle size distribution. First, the separation rate of 2:1 type clay for each particle size was calculated by particle trajectory simulation, because magnetic separation rate largely depends on the objective size. According to the calculation, 73 and 89 % of 2:1 type clay could be separated at 2 and 7 T, respectively. Moreover we calculated dose reduction rate on the basis of the result of particle trajectory simulation. It was indicated that 17 and 51 % of dose reduction would be possible at 2 and 7 T, respectively. The difference of dose reduction rate at 2 T and 7 T was found to be separated a fine particle. It was shown that magnetic separation considering particle size distribution would contribute to the volume reduction of contaminated soil.

• Transactions on Electrical and Electronic Materials
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• v.18 no.1
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• pp.46-50
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• 2017

The Zn1-xMnxO ($0.00{\leq}x{\leq}0.06$) samples have been synthesized in the form of powder by the coprecipitation method at low temperature using $Zn(CH_3COO)_2$. $2H_2O$ and $Mn(CH_3COO)_2$. $4H_2O$ powders, as well as HCl and $NH_4OH$ solutions as starting materials. Characterization was conducted using XRD, TEM, XRF, FTIR and VSM. The result shows that the $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles have the wurtzite phase with a hexagonal structure and particle sizes ranging from 17.48 to 118.83 nm. In a qualitative analysis of XRF, the peaks that confirm the existence of the manganese element in Mn-doped ZnO samples were observed. Meanwhile, FTIR test result shows that there are peaks at around $500cm^{-1}$ and $400cm^{-1}$ in the FTIR spectra for Mn doped ZnO samples which clearly reveal the existence of the (Zn, Mn)-O strain mode. The (Zn, Mn)-O absorption peak positions have shifted to a lower wave number with increasing Mn doping content. The peak intensity is also lower if compared to that of the ZnO sample without doping. From the VSM test, it is shown that $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles are all paramagnetic having monotonically increased susceptibility as increasing Mn content.

• 한국전산유체공학회:학술대회논문집
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• 2009.11a
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• pp.88-92
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• 2009

When exposed to uniform magnetic fields externally applied, paramagnetic particles acquire dipole moments and the induced moments interacting with each other lead to the formation of chainlike structures or clusters of particles aligned with the field direction. A direct simulation method, based on the Maxwell stress tensor and a fictitious domain method, is applied to solve flows with magnetic chains in simple shear flow. We assumed that the particles constituting the chains are paramagnetic, and inertia of both flow and magnetic particles is negligible. The numerical scheme enables us to take into account both hydrodynamic and magnetic interactions between particles in a fully coupled manner, enabling us to numerically visualize breakup and reformation of the chains by the combined effect of the external field and the shear flow. Simple shear flow with suspended magnetic chains is solved in a periodic domain for a given magnetic field. Dynamics of interacting magnetic chains is found to be significantly affected by a dimensionless parameter called the Mason number, the ratio of the viscous force to the magnetic force in the shear flow. The effect of particle area fraction on the chain dynamics is investigated as well.

• Journal of the Korean Magnetics Society
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• v.4 no.3
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• pp.282-284
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• 1994

A theoretical expression for determining the effective magnetic moment of hematite(${\alpha}-Fe_{2}O_{3}$) particle of the parasitic ferromagnetism by the proton relaxation in water is derived. In deriving the expression it is found that the mathematical procedures are exactly the same as those applied for aqueous solutions containing free paramagnetic ions, except that the distance between the proton spin of water molecule and the corresponding electronic spin of the particle must be considered to be a radius vector rather than a relative distance. And it is also found that the average effective magnetic moment of the particle calculated by the expression is in good agreement with the experimental value determined by Hirai.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.7
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• pp.455-462
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• 2017

The magnetic interaction between elliptic Janus magnetic particles are investigated using a direct simulation method. Each particle is a one-to-one mixture of paramagnetic and nonmagnetic materials. The fluid is assumed to be incompressible Newtonian and nonmagnetic. A uniform magnetic field is applied externally in a horizontal direction. A finite-element-based fictitious domain method is employed to solve the magnetic particulate flow in the creeping flow regime. In the magnetic problem, the magnetic field in the entire domain, including the particles and the fluid, is obtained by solving the governing equation for the magnetic potential. Then, the magnetic forces acting on the particles are calculated via a Maxwell stress tensor formulation. In a single particle problem, it is found that the orientation angle at equilibrium is affected by the aspect ratio of the particle. As for the two-particle interaction, the dynamics and the final conformation of the particles are significantly influenced by the aspect ratio, the orientation, and the spatial positions of the particles. For the given positions of the particles, the fluid flow is also influenced by the orientation of each particle. The self-assembly structure of the particles is not a fixed one, but it varies with the above-mentioned factors.