• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.673-677
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• 2001

Pseudo-first-order rate constants have been measured spectrophotometrically for the reactions of 8-(5-nitroquinolyl) 3-furoate with alkali metal ethoxides in anhydrous ethanol. The plot of kobs vs the concentration of alkali metal ethox ides is linear for the reactions performed in the presence of a complexing agent, 18-crown-6 ether, but exhibits upward curvatures for the corresponding reactions performed in the absence of the complexing agent, indicating that the alkali metal ions in this study behave as catalysts. Second-order rate constants were determined for the reactions with dissociated free ethoxide (kEtO-) and with ion paired alkali metal ethoxides (kEtO-M + ) from ion pairing treatments. The magnitude of catalytic effect (kEtO-M + /kEtO-) was found to be 1.7, 3.4 and 2.5 for the reaction of 8-(5-nitroquinolyl) 3-furoate, while 1.4, 3.6 and 4.2 for that of 4-nitrophenyl 2-furoate, 1.8, 3.7 and 2.4 for that of 8-(5-nitroquinolyl) benzoate, and 2.0, 9.8 and 9.3 for that of 8-(5-nitroquinolyl) 2-furoate with EtO- Li+ , EtO- Na+ and EtO- K+ , respectively. A 5-membered chelation at the leaving group is suggested to be responsible for the catalytic effect shown by alkali metal ions.

• 한국추진공학회지
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• 제1권1호
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• pp.33-45
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• 1997

자유제트를 제어하는 방법중 하나는 분사제트 주위에 형성되는 와류를 조절하는 것이다. 이를 위하여 제트노즐 주위에 환형관을 설치하여 환형관으로부터 2차제트를 분사 또는 흡입함으로써 제트주위에 형성되는 전단류를 변화시켰다. 2차제트를 분사하는 경우(R<1.0) 주제트 주위에 형성되는 와류의 발달을 억제함으로써 제트포텐셜코어의 길이가 아주 길어지는 제트유동을 얻을 수 있었고 흡입하는 경우에는(R>1.0) 제트주위의 전단류가 흡입비 R=1.3～l.65에서 대류불안정성에서 절대불안정성으로 바뀜으로써 형성된 와류가 하류에서 제트중심부까지 발전, 결합되는 것을 방지하여 더 긴 포텐셜코어와 중심에서 낮은 난류강도를 얻었다. 위의 결과는 환형관 주위에 부착한 깃의 높이 변화에 따라서 변화하였는데, 이것은 깃이 환형관을 통한 흡입유동의 유로역할을 함으로써 출구 주위의 유체가 직접흡입되는 것을 방지하기 때문이다. 분사제트 벡터링을 위하여 제트노즐 주위의 환형관을 이등분하여 한쪽으로만 흡입함으로써 제트주위에 다른 전단류를 형성함과 동시에 코안다(Goanda)효과를 이용하여 분사제트를 편향시켰다. 편향되는 정도 및 난류성분은 흡입속도비에 따라서 크게 바뀌었다. 실험은 속도분포와 난류강도 측정이 수행되었으며 가시화를 이용하여 유동특성을 관찰하였다.

• 정보보호학회논문지
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• 제28권3호
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• pp.563-577
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• 2018

VANET(Vehicular Ad hoc Network)에서 안전한 통신을 지원하기 위해 차량 간 또는 차량과 기반 구조 사이에서 교환되는 메시지는 인증이 반드시 수행되어야 한다. 본 논문에서는 VANET 환경을 위한 계층적 구조의 익명 인증 시스템을 제안한다. 제안하는 시스템 모델은 계층적으로 비밀키를 발급하여 기존 시스템의 문제점인 PKG의 오버헤드를 줄여 실용성을 높인다. 또한 페어링을 사용하지 않고 설계된 효율적인 2레벨 계층적 ID 기반 서명(Two-Level Hierarchical Identity-Based Signature, TLHIBS) 기법을 제안한다. 제안하는 기법은 조건부 익명성을 만족하여 차량의 프라이버시를 보호하고, 일괄검증(batch verification)을 지원하여 다수의 서명을 효율적으로 검증할 수 있다. 마지막으로 기존의 VAENT 환경에서 ID 기반 서명 기법들의 안전성 증명이 잘못된 것과는 다르게 제안한 기법의 안전성은 이산 대수 문제(Discrete Logarithm Problem, DLP)에 리덕션되어 랜덤 오라클 모델(random oracle model)에서 증명된다.

• 대한기계학회논문집B
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• 제25권9호
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• pp.1253-1262
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• 2001

Experimental study is conducted to investigate the heat/mass transfer and flow characteristics for the flow over backward-facing step and cavities. A naphthalene sublimation method has been employed to measure the mass transfer coefficients on the duct wall and LDV system has been used to obtain mean velocity profiles and turbulence intensities. Reynolds number based on the step height and free stream velocity is 20,000 and St numbers of acoustic excitations given to separated flow are 0.2 to 0.4. The spectra of streamwise velocity fluctuation show a sharp peak forcing frequency for an acoustically excited flow. The results reveal that the vortex pairing and overall turbulence level are enhanced by the acoustic excitation and a significant decrease in the reattachment length and the increased turbulence intensity are observed with the excitation. A certain acoustic excitation increases considerably the heat/mass transfer coefficient at the reattachment point and in the recirculation region. For the cavities, heat/mass transfer is enhanced by the acoustic excitation due to the elevated turbulence intensity. For the 10H cavity, the flow pattern is significantly changed with the acoustic excitation. However, for the 5H cavity, the acoustic excitation has little effect on the flow pattern in the cavity.

• 대한기계학회논문집B
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• 제27권8호
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• pp.1023-1032
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• 2003

The effect of local forcing on the separated flow over a backward-facing step is investigated through hot-wire measurements and flow visualization with multi-smoke wires. The boundary layer upstream of the separation point is laminar and the Reynolds number based on the free stream velocity and the step height is 13800. The local forcing is given from a slit located at the step edge and the forcing signal is always defined when the wind tunnel is in operation. In case of single frequency forcing, the streamwise velocity and the reattachment length are measured under forcing with various forcing frequencies. For the range of 0.010〈S $t_{\theta}$〈0.013, the forcing frequency component of the streamwise velocity fluctuation grows exponentially and is saturated at x/h = 0.75 , while its subharmonic component grows following the fundamental and is saturated at x/h = 2.0. However, the saturated value of the subharmonic is much lower than that of the fundamental. It is observed that the vortex formation is inhibited by the forcing at S $t_{\theta}$ = 0.019 . For double frequency forcing, natural instability frequency is adopted as a fundamental frequency and its subharmonic is superposed on it. The fundamental frequency component of the streamwise velocity grows exponentially and is saturated at 0.5 < x/ｈ < 0.75, while its subharmonic component grows following the fundamental and is saturated at x/ｈ= 1.5 . Furthermore, the saturated value of the subharmonic component is much higher than that for the single frequency forcing and is nearly the same or higher than that of the fundamental. It is observed that the subharmonic component does not grow for the narrow range of the initial phase difference. This means that there is a range of the initial phase difference where the vortex parring cannot be enhanced or amplified by double frequency forcing. In addition, this effect of the initial phase difference on the development of the shear layer and the distribution of the reattachment length shows a similar trend. From these observations, it can be inferred that the development of the shear layer and the reattachment length are closely related to the vortex paring.