• Title/Summary/Keyword: pKa

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Transmitter Design for Earth Station Terminal Operating with Military Geostationary Satellites on Ka-band (Ka 대역 군위성통신 지상단말 송신기 설계)

  • Kim, Chun-Won;Park, Byung-Jun;Yoon, Won-Sang;Lee, Seong-Jae
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.4
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    • pp.393-400
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    • 2014
  • In this paper, we have designed the transmitter for earth station terminal operating with military geostationary satellite on Ka-band that is complied with MIL-STD-188-164A. The designed antenna of this terminal is dual-offset gregorian reflector which is consist of corrugated horn and iris polarizer, othermode transducer. This antenna meets radiation pattern and transmit EIRP spectral density requirements in this standard. The designed RF systems of this terminal are consist of Block Up Converter(BUC) converting frequency band from IF to Ka band and SSPA having low-power consumption and compact light-weight using the pHEMT MMIC compound devices. This RF systems applied with VSWR, spurious/harmonic suppression, output flatness and phase noise requirement in this standard.

The Study on Multi-band Mixer for Adaptive Radar (적응형 레이다를 위한 다중대역 혼합기에 관한 연구)

  • Go, Min-Ho;Kang, Se-Byeok
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.6
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    • pp.1053-1058
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    • 2021
  • This paper presents the multi-band mixer which converts a X-, K- and Ka-band adaptively by adjusting the gate-bias voltage of an active device. The proposed mixer presented a conversion loss of -10 dB at -0.8 V gate-bias voltage for X-band, a conversion loss of -9 dB at -0.3 V gate-bias voltage for K-band and for Ka-band, a conversion loss of -7 dB at -0.2 V gate-bias voltage under the LO power of +6.0 dBm. The 1dB compression point (P1dB) is +0.5 dBm for all band.

In situ measurement-based partitioning behavior of perfluoroalkyl acids in the atmosphere

  • Kim, Seung-Kyu;Li, Donghao;Kannan, Kurunthachalam
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.281-289
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    • 2020
  • Environmental fate of ionizable organic pollutants such as perfluoroalkyl acids (PFAAs) are of increasing interest but has not been well understood because of uncertain values for parameters related with atmospheric interphase partitioning behavior. In the present study, not only the values for air-water partition coefficient (KAW) and dissociation constant (pKa) of PFAAs were induced by adjusting to in situ measurements of air-water distribution coefficient between vapor phase and rainwater but also gas-particle partition coefficients were also estimated using three-phase partitioning model of ionizable organic pollutants, in situ measurements of PFAAs in aerosol and air vapor phase, and obtained parameter values. The pKa values of PFAAs we obtained were close to the minimum values suggested in literature except for perfluorooctane sulfonic acids, and COSMOtherm-modeled KAW values were assessed to more appropriate among suggested values. When applying parameter values we obtained, it was predicted that air particle-associated fate and transport of PFAAs could be negligible and PFAAs could distribute ubiquitously along the transection from urban to rural region by pH-dependent phase transfer in air. Our study is expected to have some implications in prediction of the environmental redistribution of other ionizable organic compounds.

Pharmaceutical Study on Clonixin Argininate (Clonixin Argininate의 약제학적 연구)

  • Jee, Ung-Kil;La, Sung-Bum
    • Journal of Pharmaceutical Investigation
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    • v.16 no.2
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    • pp.43-54
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    • 1986
  • To increase the bioavailability of clonixin, clonixin argininate was prepared and compared with clonixin by determining solubility, pKa, lipid-water partition coefficient, dissolution rate and in vivo tests. The results are summerized as followings; 1) The solubility of clonixin argininate was increased by 20 times in water, about 1.2 times in pH 1.2 and pH 8.0 buffer solution, and about 1.8 times in pH 6.8 buffer solution compared with that of clonixin. 2) pKa values of clonixin, clonixin lysinate and clonixin argininate were 6.32, 7.20 and 7.45, respectively. 3) The lipid-water partition coefficient of clonixin argininate was increased more than that of the clonixin in n-hexane, carbon tetrachloride, chloroform, methylene chloride, and n-butanol, but the partition coefficient of clonixin was increased more than that of clonixin argininate in benzene/pH 1.2 buffer solution, ether/pH 8.0 buffer solution, and 3-methylbutyl acetate/pH 1.2, pH 8.0 buffer solution. 4) The time required to dissolve 60% $(T_{60%},\;min.)$ of clonixin argininate was about 1.5 min. in water and pH 1.2 buffer solution, and about 5 min. in pH 6.8 buffer solution. $T_{60%}$ of clonixin lysinate was about 1.5 min. in water, about 1.8 min. in pH 6.8 buffer solution, and about 8 min. in pH 1.2 buffer solution. But $T_{60%}$ of clonixin was about 96 min. in pH 6.8 buffer solution, over 2 hours in water and pH 1.2 buffer solution. 5) Anti-inflammatory effect of clonixin argininate was increased more than that of clonixin over 6 hours, and that of clonixin lysinate was followed by lapse of time. 6) Analgesic effect of clonixin argininate was increased by 1.5 times more than that of clonixin and the effect of clonixin argininate was nearly identical with that of clonixin lysinate. 7) The absorption rates (Ka) of clonixin, clonixin lysinate and clonixin argininate were $0.169\;hr^{-1},\;0.652\;hr^{-1}$ and $0.723\;hr^{-1}$ in situ, respectively.

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Conservative treatment of Osteoporotic Compression Fractures in Thoracolumbar spine (골다공증성 흉요추부 압박 골절에서의 보존적 치료)

  • Kang, Kyu-Bok;Koh, Young-Do
    • Journal of Trauma and Injury
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    • v.18 no.2
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    • pp.107-111
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    • 2005
  • Backgrounds: To evaluate the effectiveness of conservative treatment in osteoporotic thoraco-lumbar compression fractures and to identify the factors influencing the progression of compression. Materials and Methods: From January 2003 to October 2004, Patients who were admitted to our hospital for osteoporotic thoraco-lumbar compression fractures were reviewed retrospectively with follow-up more than 12 months (ave. 14.6 months). With simple x-ray lateral view, we evaluate wedge compression ratio (WCR) and kyphotic angle (KA) at initial and final follow-up. We separate the patients into two groups baesed on the amount of progression of vertebral compression and evaluate a relation with BMD, vertebral fracture level, initial WCR, initial KA. All datas were statistically analyzed. Results: An average of T-score was -3.5 and the changes of KA between initial and final follow-up were average $3.5^{\circ}$. Compression of anterior column were progressed to 8.5%. The changes between initial and final WCR in Group I (N=24) was 17.8%, and Group II (N=18) was 3.3%. T-score in group I was -3.4 and group II was -3.8 (p=0.228). vertebral fracture level were 10 T12, 12 L1, 2 L2 in group I; 6 T12, 6 L1, 6 L2 in group II (p=0.156). Initail WCR was 0.74 in group I, 0.63 in group II, and there was statistical difference between two groups(p=0002). Initial kyphotic angle was $13.9^{\circ}$in group I, $16.2^{\circ}$in group II repectively (p=0.392). Conclusion: The conservative treatment with short-term bed rest and early embulation is effective and valuable method to patients who have osteoporotic thoraco-lumbar compression fractures. There was no statistical difference between two groups according to BMD, vertebral fracture level, KA. But in comparison with initail WCR between two groups, there was statistical difference. That means, in the case of small initial compression of anterior column, the progression of compression was bigger than else. In these patients, more strict use of appropriate brace and careful follow-up should be needed.

Characteristics of Glucose-6-phosphate Dehydrogenase from Leuconostoc mesenteroides (Leuconostoc mesenteroides에서 分離한 Glucose-6-phosphate Dehydrogenase의 特性)

  • Byun Si Myung;Yang Do Choi;Moon H. Han
    • Journal of the Korean Chemical Society
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    • v.23 no.4
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    • pp.248-258
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    • 1979
  • Glucose 6-phosphate dehydrogenase of Leuconostoc mesenteroides which was purifid by an affinity chromatography was studied on the characterization, kinetics and chemical modification. The apparent molecular weight of the enzyme was 112,000 by the gel filtration method of Sephadex G-200 column. The optimum temperature of $NAD^+$-linked reation was 50$^{circ}C$ and the activation energy and the heat of inactivation were 8.36 kcal/mole and -58.2kcal/mole, respectively. The steady state kinetic study showed KG6P, Kemp, and CX KNADP to be 76.9 PM, 7.46${\mu}M$ and 7.14 ${\mu}M$, respectively, and KGGP, KNAD,and aKNm to be 53.7${\mu}M$, 115.2${\mu}M$ and 702.2${\mu}M$ for the $NAD^+$-linked reaction at pH 7.8, optimum pH. The pH dependent kinetic constants suggested that the two ionizing groups whose pKa is 7.2 .and pKb is 9.0-9.6 were involved in the enzyme-substrate interaction. Evidence by photooxidation and carboxymethylation of the enzyme suggested that the imidazole group of histidine with pKa group may participate in the catalytic site.

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The Ages of Fault Activities of the Ilkwang Fault in Southeastern Korea, Revealed by Classification of Geomorphic Surfaces and Trench Survey

  • Ho, Chang;Ree, Jin-Han;Joo, Byung-Chan
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.1-2
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    • 2004
  • The Ilkwang Fault is NNE-striking, elongated 40 Km between Ulsan and Haendae-ku, Busan in southeastem part of the Korean Peninsula(Kim, D.H. et al., 1989; Kim, J.S. et al., 2003). This paper is mainly concemed about the ages of the fault activities especially in the Quatemary, infered from classification of geomorphic surface and trench excavation for the construction of Singori nuclear power plant. The geomorphi surfaces are classified into the Beach and the Alluvial plain, the 10 m a.s.l. Marine terrace, the 20 m a.s.l. Marine terrace, the Reworked surface of 45 m a.s.l. Marine terrace and the Low relief erosional surface, from lower to higher altitude. The Beach and the Alluvial plain are elongated to the Holocene terrace(ist terrace, choi, 2003). The 10 m a.s.l. Marine terrace is correlated to 2nd terrace (MIS 5em 125 Ka. y. B.P., Choi, 1998). The 45 m a.s.l. Marine terace is correlated to the Lower marine terrace (MIS 7,220 Ka. y. B.P., Choi, 2003 or MIS 9,320 y. B.P.) to the Gwanganri terrace(Penultimate interglacial age, 200-200 Ka. Y. B.P., Oh, 1981). The Low relief erosional surface is distributed coastal side, the Reworked surface of 45 m a.s.l. Marine terrace inland side by the Ilkwang Fault Line as the boundary line. But the former is above 10 m higher in relative height than the latter. The 20 m a.s.l. Marine terrace on the elongation line of the Ilkwang Fault reveals no dislocation. A site was trenched on the straight contract line with $N30^{\circ}$ E-striking between the 10 m a.s.l. Marine terrace and the 20 m a.s.l. Marine terrace. Fault line or dislocation was not observable in the trench excavation. Accordingly, the straight contact line is inferred as the ancient shoreline of the 10 m a.s.l. Marine terrace. The Ages of the Fault activities are inferred after the formation of the Ichonri Formation - before the formation of the 45 m a.s.l. Marine terrace (220 Ka. y. B.P. or 320 Ka. y. B.P.). The Low relief erosional surface was an island above the sea-level during the formation of the 45 m a.s.l. Marine terrace in the paleogeography.

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Younger Dryas Type Climatic Oscillation in the East Sea

  • Kim, Gil-Young;Kim, Dae-Choul;Shin, Im-Chul
    • Journal of the korean society of oceanography
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    • v.34 no.1
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    • pp.43-48
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    • 1999
  • The latest-Quaternary paleoceanographic history of the Ulleung Basin, the East Sea (the Sea of Japan) is reconstructed on the base of planktonic foraminifera, oxygen and carbon isotopes, and accelerator mass spectrometer radiocarbon (AMS-$^{14}$C) data from two cores. Sinistral populations of Neogloboquadrina pachyderma are dominant during the last glacial period while dextral forms of Neogloboquadrina pachydeyma are abundant in the Holocene. An abrupt increase in ${\delta}^{18}$O values in both cores that began about 11 ka B.P may indicate the Younger Dryas cooling episode. A low-salinity event, marked by light ${\delta}^{18}$O values (0-1 %), is observed before the Younger Dryas event. As previous works suggested, the low-salinity event is probably due to the freshening of surface water caused by fresh water input from Huang Ho river and/or the excess of precipitation over evaporation. The lowest salinity water in the Ulleung Basin was probably continued from approximately 18 ka B.P. to 15 ka B.P. The ${\delta}^{18}$O values have gradually decreased since the Younger Dryas as a result of the continuous inflow of the warm Tsushima Current into the East Sea.

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Four-channel GaAs multifunction chips with bottom RF interface for Ka-band SATCOM antennas

  • Jin-Cheol Jeong;Junhan Lim;Dong-Pil Chang
    • ETRI Journal
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    • v.46 no.2
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    • pp.323-332
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    • 2024
  • Receiver and transmitter monolithic microwave integrated circuit (MMIC) multifunction chips (MFCs) for active phased-array antennas for Ka-band satellite communication (SATCOM) terminals have been designed and fabricated using a 0.15-㎛ GaAs pseudomorphic high-electron mobility transistor (pHEMT) process. The MFCs consist of four-channel radio frequency (RF) paths and a 4:1 combiner. Each channel provides several functions such as signal amplification, 6-bit phase shifting, and 5-bit attenuation with a 44-bit serial-to-parallel converter (SPC). RF pads are implemented on the bottom side of the chip to remove the parasitic inductance induced by wire bonding. The area of the fabricated chips is 5.2 mm × 4.2 mm. The receiver chip exhibits a gain of 18 dB and a noise figure of 2.0 dB over a frequency range from 17 GHz to 21 GHz with a low direct current (DC) power of 0.36 W. The transmitter chip provides a gain of 20 dB and a 1-dB gain compression point (P1dB) of 18.4 dBm over a frequency range from 28 GHz to 31 GHz with a low DC power of 0.85 W. The P1dB can be increased to 20.6 dBm at a higher bias of +4.5 V.

Transmission Schemes for Ka band Satellite Broadcasting Signals by Rainfall Rate (Ka대역 위송방송 신호의 강우강도에 따른 전송기법)

  • Yoon, Ki-Chang;Kim, Seung-Chul;Sohn, Won
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2009.11a
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    • pp.101-104
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    • 2009
  • 이 연구는 Ka대역 위성 HDTV 방송 서비스를 제공하기 위해 강우강도에 따른 전송방안을 제안하였다. Ka대역은 Ku대역에 비하여 강우에 취약하기 때문에 이를 안정적으로 활용하기 위해서는 강우감쇠를 효과적으로 경감시키는 기술개발이 필수적이다. 유럽위성방송 표준인 DVB-S2에서는 강우감쇠에 대한 대처방안으로 채널상황에 따라 여러 변조방식과 채널 부호 율을 이용하는 적응형 변복조 방식을 지원하고 있으며, 이 논문에서는 DVB-S2기반의 전송방식과 Ka대역 중계기의 규격을 적용하여 강우강도에 따른 전송방안을 제안하였다. 이를 위하여 ITU-R P.618-9 강우감쇠 추정 모델과 기상청에서 측정한 1998년부터 2007년까지의 최근 10년간 국내 주요지역의 30분 누적강우량을 이용하여 지역별 강우 감쇠값을 도출하였고 강우강도와 시간 율 관계분석을 통하여 강우강도에 따른 강우감쇠 값을 획득하였다. 획득한 강우감쇠 값을 무궁화 위성 3호의 링크 설계에 적용하여 강우강도에 따른 적용 가능한 전송방안을 도출하였다. 이 연구를 바탕으로 강우의 지역적 편이가 높은 우리나라의 강우 특성을 유연하게 반영하여 각 지역에 맞는 적응적인 전송 방식을 고려할 수 있다.

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