• Title/Summary/Keyword: pH of solution

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pH changes by Streptococcus sobrinus on some commercial drinks (Streptococcus sobrinus에 의한 일부 시판음료의 pH 변화)

  • Youn, Hye-Jeong
    • Journal of Korean society of Dental Hygiene
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    • v.7 no.2
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    • pp.167-176
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    • 2007
  • Objectives: The purpose of this study was to investigate the dental caries activity of some commercial drinks. Methods : Acidity levels were recorded as pH values of original drinks and amount of 50%-sodium hydroxide(NaOH) required to neutralize by titration 50.00ml of the drink(It was called titratable acid). Acidity of the drinks with S. sobrinus was measured at an interval of one hour after incubating ($37^{\circ}C$) the test drinks and control solution which was composed 20.00ml of neutralized drinks as pH 7.0 with 0.2ml of a pooled suspension of S. sobrinus. Results : The drink with the highest pH value was the Cow's milk(pH $6.70{\pm}0.01$), and the most acidic was the Carbonated drink(pH $2.40{\pm}0.02$). The drink with the highest buffer effect was the Fruit juice($139.78{\pm}0.76$), and the lowest was the Glucose solution(control, $4.42{\pm}0.20$). The drinks with S. sobrinus during incubation at $37^{\circ}C$ for 24h were decreased to below critical pH 5.5. Spending times from pH 7.0 to pH 5.5~5.0 were Glucose solution(less than 1h). Carbonated drink(3h), Fruit juice(5h), Cow's milk(8h) and Mixed drink(21h). Conclusions: These results show that some commercial drinks with S. sorbrinus have the possibility of tooth decalcification. Thus, it is suggested that the people who have the low salivary secretion rate and the children who sleep without toothbrushing after drinking need the instruction for diet control and oral health education.

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Effect of pH on the Preparation of Spherical Fine Zirconia Powders Using Gas-Liquid Phase Reaction (기액반응법을 이용한 구형 지르코니아 미분체 제조시 pH의 영향)

  • 김창현;이대희;이창섭;이병교
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1009-1014
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    • 1997
  • Ammonia gas was blown into the solution of zirconium ion to induce precipitation of supersaturated zirconium ion at gas-liquid interface with increase in pH. The influence of pH on the phase and particle size of precipitate and calcined powders has been investigated. At pH 4.5 of zirconium solution, maximum yield of 98.7% was obtained. Above pH 4.5, there was no more increase of yield. Above pH 5.5, large aggregates consisting of primary particles were observed in precipitate and calcined powders. At pH 4.5, almost aggregate-free fine spherical zirconia powders were obtained.

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The Degradation of Indomethacin in Aqueous Solution (수용액에 있어서의 Indomethacin 분해)

  • 전인구;이민화;우종학
    • YAKHAK HOEJI
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    • v.20 no.1
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    • pp.76-82
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    • 1976
  • The base-catalyzed hydrolysis of indomethacin over a range of pH 8,2 to 10.0 was investigated, according to the first order kinetic equation. The energy of activation for the reaction was calculated 20, 18 kcal/mole from the Arrhenius plot. And the optimal pH of indomethacin in aqueous solution was estimated as pH 4.93 by the extrapolation of the log k-pH profiles in strong acidic and alkaline regions. And the influences of alkaline earth metals, heavy metals and some other compounds on the degradation of indomethacin were observed with no effect.

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Synthesis, Crystallization Behaviors and Conductivity of $\beta$-Alumina from Aluminum Isopropoxide and Sodium Hydroxide (Aluminum Isopropoxide와 Sodium Hydroxide로부터 $\beta$-Alumina의 합성과 결정화 과정 및 전도도)

  • 양유철;박용민;김형욱;손영국
    • Journal of the Korean Ceramic Society
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    • v.32 no.9
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    • pp.1076-1084
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    • 1995
  • A mixture of aluminum isopropoxide (Al(OC3H7i)3) solution and sodium hydroxide (NaOH) solution was hydrolyzed in the range between pH 1~14. the powder obtained from sol-gel process was calcined at several temperatures and crystallization behaviors of various samples were investigated. The hydrolyzed sols of pH 1~6 wre clear, or near clear. On the other hand, powder precipitated from sols of pH 7~14. The sample obtained from pH 3 solution crystallized via complicated route, and $\beta$-Al2O3 and $\beta$"-Al2O3 phases appeared at lower temperature than samples from other pH conditions. And the quantity of remained $\beta$"-Al2O3 phase after heat treatment at 150$0^{\circ}C$ was more than samples from other pH conditions. After sintering, ionic conductivities were 1.3$\times$10-4S.cm-1 to 0.76$\times$10-4S.cm-1.0-4S.cm-1.

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Effects of Electrodeposition Conditions on Properties of Ni Thin Films Electrodeposited from Baths Fabricated by Dissolving Metal Ni Powders (금속 Ni 분말을 용해한 도금용액으로부터 전기도금 된 Ni 박막 특성에 미치는 도금조건의 영향)

  • Yoon, Pilgeun;Park, Keun-Yong;Uhm, Young Rang;Choi, Sun Ju;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.3
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    • pp.73-81
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    • 2015
  • Chloride plating solution was fabricated by dissolving metal Ni powders in solution with HCl and deionized water. Effects of deposition conditions on the properties of Ni films electrodeposited from chloride baths were studied. Current efficiency of Ni films electrodeposited from the baths containing saccharin was decreased with increasing the current density. Residual stress of Ni thin films ware measured to be about 230 ~ 435 MPa in the range of current density of $10{\sim}25mA/cm^2$. Cathode current efficiency in baths without saccharin was initially increased with increasing pH, while it was decreased with increasing pH further. Cathode current efficiency in baths with saccharin (except at pH 2) exhibited less 10 ~ 20% than that in baths without saccharin. Residual stress of Ni films electrodeposited from baths without saccharin was measured to be 388 ~ 473 MPa in the range of pH 2 ~ pH 5 and then was increased to 551 MPa at pH 6. On the other hand, residual stress of Ni films electrodeposited from baths with saccharin was increased with increasing pH. Surface morphology was strongly affected by the change of current density, but slightly by solution pH and addition of saccharin.

Kinetics of pH Changes during Thermal Degradation of MSG under Model System (Model System 하에서 MSG 열분해 중 pH 변화의 속도론적 연구)

  • Cha, Bo-Sook;Han, Min-Soo;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.232-235
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    • 1992
  • Effect of temperature and initial pH were studied on the pH change of MSG solution during heating. The heating temperature and initial pH of 2% MSG solution were in the range of $100{\sim}120^{\circ}C$ and $pH\;2{\sim}9$, respectively. The results showed that the pH of MSG solution was more rapidly decreased as the temperature increased and the initial pH decreased due to pyroglutamic acid formation from MSG thermal degradation. A linear relationship was obtained between pH decreased and logarithmic value of heating time and the decreasing rate constant of pH were calculated from the slope. The pH decreased$({\Delta}pH)$ after 3 hrs of heating was 1.2 at the initial pH 4 and $120^{\circ}C$ and 0.33 at pH 5 and $120^{\circ}C$ while little pH change measured at the range of $pH\;6{\sim}9$. Activation energy calculated for pH decrease during heating was 11.77 and 22.26 kcal/mole at pH 4 and pH 5, respectively.

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Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution (황산철 도금액 중 Si 입자의 공석 특성)

  • Moon Sung-Mo;Lee Sang-Yeal;Lee Kyu-Hwan;Chang Do-Yon
    • Journal of the Korean institute of surface engineering
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    • v.37 no.6
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

Analysis of Matrine Alkaloids in Human Urine by Hollow Fiber Liquid-phase Microextraction with High-performance Liquid Chromatography (고성능 액체 크로마토그래피의 중공섬유 액상 미세추출에 의한 인간뇨의 Matrine Alkaloids의 분석)

  • Han, Dan-Dan;Row, Kyung-Ho
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.38-42
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    • 2010
  • A sensitive quantitative method for the determination of matrine alkaloids in human urine was developed based on hollow fiber liquid-phase microextraction (HF-LPME) combined with HPLC. The influence of the different factors on the HF-LPME efficiency including the pH and ion strength of the donar solution, the pH of the acceptor solution, stirring rate and extraction time were examined. The best HF-LPME conditions were as follows: 1-octanol impregnated in the pores of the hollow fiber, 100 mmol/L of $H_3PO_4$ at pH 1.50 as the acceptor solution injected into the lumen of the hollow fiber, 1 mol/L NaOH used to adjust the pH of the donor solution, stirring rate of 600 rpm and extraction time of 60 min. The LPME method was applied successfully to the analysis of matrine and sophocarpine in real urine samples.

Development of a Low-cost Metering Device for Automatic Mixing of Nutrient-Solution

  • Ryu, K.H.;Lee, K.C.;Lee, J.H.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.1117-1125
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    • 1996
  • A low-cost and precise metering device, which is suitable to automatic mixing of nutrient-solution for hydroponic culture, was developed for small-scale growers. The metering accuracy of the metering device developed was compared with commercial metering pumps. The mixing performance through the control of EC and pH was also evaluated. The accuracy of the metering device in terms of the full -scale error was $\pm$0.3% , which was much better compared to $\pm$2.45% and $\pm$1.38% for the two types of commercial metering pumps. The mixing system of nutrient-solution with the metering device showed a satisfactory control performance with the accuracies of $\pm$0.05mS/cm and$\pm$0.2pH for EC and pH, respectively.

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Development of Micro Wired pH Electrode for Real-Time Monitoring for Gastroesophageal Reflux (위식도 역류 실시간 모니터링 마이크로 와이어 pH 전극 개발)

  • Kim, Eung-Bo;Lee, Kyu-Jin;So, Sang-Kyun;Joung, Yeun-Ho;Park, Jung Ho;Kim, Nam Hee
    • Journal of Biomedical Engineering Research
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    • v.38 no.6
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    • pp.277-284
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    • 2017
  • This paper presents an implantable pH measurement electrode for wireless gastroesophageal reflux measurement. Usually, gastroesophageal reflux is diagnosed by a catheter-type wire connection between the esophagus and the diagnostic device which brings many side effects such as restriction of daily living, pain, and discomfort in the nasal cavity and pharynx of patients. In order to solve these issues, researchers have been studied a wireless measurement method and a micro-sized pH electrode for human body insertion is necessary. Commercial glass packaged pH meter is formed by a sensing and a reference electrodes in a KCl solution. However, if the glass meter is inserted into the human body, there are risks of leakage of the solution, breakage of the glass package, injury of the body elements. Therefore, the solution should be solidified on the micro-sized noble metal wire which has a characteristic of biocompatible. After solidified wire fabrication, the designed meter was tested for feasibility of measurement and the result was well agreed with pH values of commercial pH meter. Potentials in pH 1 to 12 solution was measured to obtain the sensitivity of the sensor with linearity. And we have designed a simulation of gastroesophageal reflux with symptom frequency, interval, and duration time in pH 2 solution. The proposed sensor has capable to get the same potential for 24 measurements in 3 days, and it has sensed same pH values of 2 for one hour with every 10 minutes. Furthermore, the sensor was survived for 48 hours with reasonable potentials in the acid solution.