• Title/Summary/Keyword: pH measurement test

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Resistance of Cementitious Binders against a Fall in the pH at Corrosion Initiation

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.110-115
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    • 2009
  • At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

Detection of Gelation in Ultra-high Temperature Treated Milks During Storage (초고온 멸균유의 저장중 겔 형성의 추적)

  • Park, In-Duck;Hong, Youn-Ho
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.404-406
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    • 1993
  • In order to detect the gelation of ultrahigh temperature (UHT) treated market milks during storage at 20+1C, the free amino groups were quantified with 2,4,6-trinitrobenzene sulfonic acid, and the measurement of pH values and the alcohol test were monthly carried out. The average tree amino groups were $0.94{\sim}1.11{\mu}M$ at 1 month, $1.95{\sim}2.17{\mu}M\;at\;5{\sim}6$ month and $4.95{\sim}6.36{\mu}M$ at 12 month. The pH values at the same time as above were $6.72,\;6.49{\sim}6.55\;and\;6.14{\sim}6.16$, respectively. The alcohol test showed positive results at $5{\sim}6$ month, which could indicate the casein instability and beginning of gelation. These results suggest that the gelation of UHT market milks could he predicted through checking some chemical parameters weekly and be helpful for quality control.

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Implementation of 4-Channel Electrolyte Analyzer using ISFET Microsensors (ISFET 마이크로센서를 이용한 4-채널 전해질 분석기의 구현)

  • Bae, S.K.;Kim, K.Y.;Won, C.H.;Cho, B.W.;Kim, C.S.;Sohn, B.K.;Cho, J.H.
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.05
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    • pp.22-26
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    • 1996
  • In this paper, we designed 4-channel electrolyte analyzer that can measure simultaneousely the 4 electrolytes - pH, $pNa^{+}$, $pCa^{2+}$, and $pK^{+}-$ using 2-point calibration and implemented it. Developed electrolyte analyzer consists of singal processing part, actuator part and control unit for sample flow system. To implement reliable instrument, design considerations are emphasized on flow system and sample chamber that requires small sample volume and prevent air contact with sample solution. In addition to the hardware design, we developed system software which controls full measuring process. After system developed, we verified the system performance by the test measurement for pH, $pNa^{+}$, $pCa^{2+}$, and $pK^{+}$ value.

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A Study on Site Application Techniques for Insulation Reliability of Rotating Machine (고압회전기 절연열화진단의 현장적용기술연구)

  • Kim, K.Y.;Jo, K.H.;Kim, T.S.;Han, S.O.;Lee, H.S.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.286-291
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    • 1991
  • Most of the failures of rotating machine are stator coil insulation failures. The insulation diagnostic testing for high voltage motors and generators are only megger test and P. I Test which is applied DC voltage until now. But it was impossible to judge insulation deterioration status of high voltage rotating machinery by above testing. In other words, even though the megger measurement values are fairly high, they used to be failed from time to time. Therefore in order to excute reliable and detailed diagnosis of insulation deterioration for rotating machinery, the tangent delta test, the alternating current test and the partial discharge test shall be applied to the insulation diagnostic testing on site.

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Evaluation of Exposure Indicators for Plants by Silicon Tetrachloride Release (사염화규소 누출사고지점 주변 식물에 대한 노출지표 평가)

  • Park, Jae-Seon;Kim, Jee-Young;Kim, Myeong-Ock;Park, Hyun-Woo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Environmental Agriculture
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    • v.36 no.4
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    • pp.288-292
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    • 2017
  • BACKGROUND: Silicon tetrachloride reacts with moisture in the atmosphere to generate hydrogen chloride, which affects the environment. Since silicon tetrachloride and its by-products are dispersed in the atmosphere in a short time after the silicon tetrachloride release into the atmosphere, it is difficult to directly assess the extent of environmental impact. In the present study, the exposure test of silicon tetrachloride or hydrogen chloride was examined in order to establish the criterion of the range affected by the silicon tetrachloride release, and the actual crops in the area exposed to silicon tetrachloride leakage were analyzed. METHODS AND RESULTS: For the experiment of exposure to silicon tetrachloride or hydrogen chloride, the leaves of red-pepper and corn were used in glass sealed containers. In the actual accident area, 59 samples from 10 different kinds of crops were collected. The pretreatment of the sample was performed by freezing and grinding, and then extracted using distilled water. The pH and concentration of chloride ($Cl^-$) ion of the extracted solution were measured using pH meter and ion chromatograph, respectively. CONCLUSION: Exposure to silicon tetrachloride caused visible damage, increasing the concentration of chloride ion, and decreasing the pH as well as hydrochloric acid. In the actual crops of the affected area, the tendency was the same as the result of the laboratory test, and the range of influence could be estimated through the concentration of $Cl^-$ ion over 2,000 mg/kg, and the correlation evaluation between the concentration of $Cl^-$ and pH. Therefore, the concentration of $Cl^-$ ion and the correlation between $Cl^-$ and pH would be considered as the factors to estimate the influence range of silicon tetrachloride release.

A study of corrosion of welded bridge steel SWS400 in the acid-rain environment (산성비 분위기에서 교량용 강재 SWS400의 용접부 부식에 관한 연구)

  • 정원석;김정구;이병훈
    • Journal of Welding and Joining
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    • v.15 no.5
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    • pp.124-133
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    • 1997
  • Corrosion behavior of welded SWS400 steel used for bridges was studied in a range of the acid-rain environment using immersion, potentiodynamic polartization, polarization resistance, and galvanic corrosion tests. The SWS400 steel exhibited active corrosion behavior in the range of acid-rain environment, i.e. no passivation. As the results of immersion corrosion test, Tafel extrapolation method, and polarization resistance measurement, the average corrosion rats of the steels were 0.31-0.72 mm/year in the pH of 4-5, and 0.17 mm/yera in the pH 6, respectively. The steel showed a resistance to corrosion in the pH 6. The observed active behavior of SWS400 steel in chloride-containing environment indicated that the chloride ions exerts a detrimental influence on the formation of passive films. Galvanic corrosion was observed between the weld and the base metals because the weld is anodic to the base metal.

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Control of tendon driven one-link manipulator

  • Choi, H.R.;Lee, Y.T.;Kim, J.H.;Chung, W.K.;Youm, Y.
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10b
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    • pp.290-295
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    • 1992
  • Tendon driven method to drive one joint using two actuators is developed and implemented. While the method has advantages over conventional transmissions, it also has several drawbacks like tendon slack, elongation and endurability. In this paper, a compensation method of the intrinsic non-linearities of tendon is proposed to improve the performance of antagonistic tendon driven method. In this method, tendon tension measurement is prerequisite which is measured with strain gauge type tension sensor. The developed method is implemented on one link test bed with colocated and non-colocated position sensor.

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Dispersive Activity and Physical Properties of Exopolysaccharide (Cystan) produced by Cystobacter sp. MSL-9

  • Lee, Gang-Mo;Kim, Se-Gyeong;Lee, Mun-Won;Choe, Seon-Yeong;Lee, Un-Taek;Yun, Hyeon-Sik
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.719-723
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    • 2003
  • The dispersing activity and physical properties of exopolysaccharide (Cystan) produced by Cystobacter sp. MSL-9 was studied. Dispersing activity of Cystan was measured by using bentonite, calcium carbonate, and kaolin. Rheological properties of Cystan were investigated by using a rheometer MCR300. It was found that dispersing activity of Cystan was maintained under various pH and temperature conditions. A particle size analyzer BI-9000AT was used for the particle size measurement of Cystan in aqueous solution. The high dispersing activity and stability under various pH and temperature conditions showed the feasibility of Cystan as a industrial biodispersant.

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A Study on the Measurement of Small Partial Discharges in a Low-voltage Induction Motor (저압 유도전동기에서 미소 부분방전 측정에 관한 연구)

  • Kil, Gyung-Suk;Song, Jae-Yong;Seo, Hwang-Dong;Hwang, Don-Ha;Kang, Dong-Sik;Kim, Yong-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.10
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    • pp.960-964
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    • 2005
  • In this paper, we dealt with a partial discharge(PD) measurement method that has been accepted as an effective and non-destructive technique to estimate insulation performance of low-voltage electric and electronic devices. The PD measurement system Is composed of a coupling network, a low noise amplifier, and associated electronics. h shielded box Is adopted to make a better measurement environment against around noise. A low cut-off frequency of the coupling network estimated by a sinusoidal wave input was 125 kHz (-3 dB). Calibration tests on laboratory set-up have shown that the PD measurement system has a stable sensitivity of 10 mV/pC. In an application test oil a low-voltage three phase Induction motor (5 HP), we could detect 0.53 pC level of partial discharge at the applied voltage of AC 650 $V_{peak}$.

Development of Reinforcement Grout Materials Using Blast Furnace Slag Powder and Aramid Fiber (고로슬래그 미분말과 아라미드 섬유를 이용한 보강그라우트재 개발)

  • Seo, Hyeok;Park, Kyung-Ho;Kim, Chan-Jung;Kim, Ho-Chul;Kim, Daehyeon
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.67-77
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    • 2019
  • The grouting method is utilized to reinforce and waterproof poor grounds, enhance the bearing capacity of structures damaged resulting from settlement due to elevation and vibration or differential settlement, and for cutoff. The purpose of this research is to enhance the compressive strength of grout materials by using aramid fiber and develop a high-strength ground improvement method by using blast furnace slag powder. In this regard, this study has conducted a uniaxial compression test after checking the high charge (higher than 50%) of the ratio of blast furnace slag powder and cement at 100:0, 70:30 and 40:60%, adding the aramid mixture based on 0, 0.5 and 1.0% of the cement and furnace slag powder weight and creating sand gels based on surface oiling rate of 0.7 and 1.2%. For the environmental review evaluation, a heavy metal exudation test and a pH test measurement have been conducted. The experiment results showed that 1% increase of aramid fiber led to 1.3 times greater uniaxial compression intensity. As for the hexavalent chrome, a 30% increase in blast furnace slag powder led to approximately 50% decrease in heavy metal exudation. However, the pH test revealed that a 30% increase in blast furnace slag powder resulted in approximately 0.5 increase in pH. Further research on the pH part is needed in the future.