• Title/Summary/Keyword: pH change

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Analysis of Pipe Wall-thinning Caused by Water Chemistry Change in Secondary System of Nuclear Power Plant (원전 2차계통의 수화학 변화가 배관감육에 미치는 영향 분석)

  • Yun, Hun;Hwang, Kyeongmo;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.325-330
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    • 2015
  • Pipe wall-thinning by flow-accelerated corrosion (FAC) is a significant and costly damage of secondary system piping in nuclear power plants (NPPs). All NPPs have their management programs to ensure pipe integrity from wall-thinning. This study analyzed the pipe wall-thinning caused by changing the amine, which is used for adjusting the water chemistry in the secondary system of NPPs. The pH change was analyzed according to the addition of amine. Then, the wear rate calculated in two different amines was compared at the steam cycle in NPPs. As a result, increasing the pH at operating temperature (Hot pH) can reduce the rate of FAC damage significantly. Wall-thinning is affected by amine characteristics depending on temperature and quality of water.

A Study on Geosmin Removal of Algae Byproducts by Ozonation and Photocatalysis (오존과 광촉매를 이용한 조류 부산물중 Geosmin 제거에 관한 연구)

  • 김은호;성낙창;최용락
    • Journal of Life Science
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    • v.9 no.5
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    • pp.581-589
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    • 1999
  • This study was carried out to compare ozonation with photocatalysis degradation for removal Geosmin of algae byproduct. The change of pH was decresed from 7.02 to 2.8 after contact time 480 minute for ozonation. In case of UV-germicidal lamp, pH was very quickly increased from 7.02 to 7.5, but Halogen lamp did very slowly change pH. Geosmin degradation ratio was as following, UV-germicidal lamp/TiO2(100mg/L) O3>UV-germicidal lamp/TiO2(50mg/L)>UV-germicidal lamp(10W)>halogen lamp(50W). Instead of TiO2 suspension solution, Geosmin degradation ratio was very low using hollow bead and pellet as coated TiO2. As a result of identifing byproducts, ozonation generated three species of aldehyde such as 3-Heptanone and three species of alcohol such as Heptanal, but photocatalysis formed 1, 14-Tetradecanediol infinitesimally.

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A Study on the Prediction of Quality Chanties of Citrus unshiu during Short-term Storage and Marketing (조생온주 밀감의 단기 저장 및 유통 중 품질변화 예측을 위한 연구)

  • 정신교;이재호
    • Food Science and Preservation
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    • v.4 no.2
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    • pp.123-130
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    • 1997
  • To develop the prediction program for quality change of Citrus unshiu during marketing, we examined the quality characteristics of Citrus unshiu stored at experimental refrigerator set to 4, 8, 12 and 16$^{\circ}C$ for 2 months. According to the storage temperature the changes of quality characteristics were different respectively, but it was most severe during 16$^{\circ}C$ storage. Activation energy and Q10 value were 6683.16 cal/mol K and 1.53 respectively. The determination coefficient of regression equation of pH, acidity and vitamin C by surface response analysis were over 0.85. Using these regression equation, we developed the prediction program for the change of pH, acidity and vitamin C contents. The calculated values and experimental values of pH, acidity and vitamin C contents for short-term storage of Citrus unshiu were coincided well.

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Drug-biomacromolecule interaction 1

  • Kim, Chong-Kook;Ahn, Hae-Young
    • Archives of Pharmacal Research
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    • v.4 no.2
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    • pp.99-107
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    • 1981
  • To investigate the protein binding characteristics of ibuprofenlysine, the effects of drub conentration, pH, ionic strength and protein concentration on the binding of drug to protein concentration on the binding of drug to protein were studied by fluorescence probe method. The conformational change of protein was investigated by circular dichroism (CD) measurement. As the concentration of drug increases, the association constant decreases. These may be due to complex formation of the probe and drug, or the interaction of the protein-probe complex and drug. The association constant for ibuprofenlysine increased with increasing protein concentration. These finding suggest a sharing of one ibuprofenlysine molecule by more than one protein molecule in the binding. The binding between ibuprofenlysine and protein was dependent on pH and ionic strength. It seems that both hydrophobic binding and some electrostatic forces are involved in the binding of ibuprofenlysing to protein.

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Colour change functional dyes based on cross-conjugated donor-acceptor chromophores

  • Park, Soo-Youl;Oh, Sea-Wha;J. Griffiths
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2000.04a
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    • pp.150-151
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    • 2000
  • Some chromophores that can undergo a pronouncend colour change when acted upon an extenal agency, such as light, heat, pH, or chemical agents, have many potential applicationa as functional dyes. They may be used as indicators, optical sensors, biochemical probes, optical and thermal recording materials. The results will investigate donor-acceptor chromophores which have the potential for such colour change processes. In particular, cross-conjugated donor-acceptor chormophores, analogous to indigo and squarylium-type chromophores, will be examined for pH sensitizing and for their oxidation-reduction colour change behaviour.

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Effect of Soil Water on the Change in Soil pH and Nutrients Movement under Rainfed Condition in Bare Soil (토양수분(土壤水分) 조건(條件)에 따른 pH 변화(變化)와 무관수(無灌水) 나지구(裸地區)에서의 양분이동(養分移動))

  • Ryu, Kwan-Shig
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.263-268
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    • 1994
  • Field microplot(D 20cm, L 85cm) experiment filled with Bonryang sandy loam soil(Typic Udifluvents) was conducted to obtain quantitative information on the change of soil pH under different soil moisture regime and ladino clover cultivation, and the movement of applied nutrient under the rainfed bare soil condition. Slaked lime increased soil pH of the applied layer. $NH_4-N$ evolved from urea hydrolysis was more effective in raising the subsoil pH rather than the exchangeable Mg and Ca. Under the different soil miosture condition downward movement of Cl and $NO_3-N$ lowered subsoil pH during the middle of ladino clover growth. Leaching of CI and $NO_3-N$ down to the out of the soil microplot and increasing movement of Ca and Mg into the subsoil produced. a slight increase of subsoil pH during the late crop growth. The mean downward movement of applied nutrient 5.5 months after field installation of microplot in the bare soil under rainfed condition(1207mm) was in the order : Cl= more than 80.0>Inorganic nitrogen= 75.8>K= 67.3>Mg=62.7>Ca=18.1>P=2.3cm respectively.

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Variation of Rock Properties in Acidic Solution and Loading Condition (산성수 침수 및 하중 조건에서의 암석물성변화 연구)

  • Chung, Jae Hong;Park, Seung Hun;Lee, Seung Jun;Yu, Seungwon;Lee, Woo Hee;Kwon, Sangki
    • Tunnel and Underground Space
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    • v.26 no.3
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    • pp.154-165
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    • 2016
  • This paper presents experimental results to investigate the affects of acidic solution under loading condition on rock properties. In the experiment, the variations of various rock properties including effective porosity, thermal conductivity, and etc were investigated with different pHs of solution and magnitudes of loading. The results show that the rock property change was increased with low pH under loading. It was predicted that chemical reaction rate would be increased in low pH. Below the crack initiation stress of the rock specimen, the variation of rock property change was reduced with increased loading. It could be explained with the reduced chemical reaction area by the compressional loading if there is no crack generation.

Early Hydration Properties of BFS by a Change of pH (pH 변화에 따른 고로수쇄 BFS의 초기 수화 특성)

  • Kang, Hyun Ju;Lee, Woong Geol;Song, Myong Shin;Kang, Seung Min;Kim, Kyeng Nam
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.442-447
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    • 2012
  • This study investigated on the early hydration and physical characteristics of BFS by pH variation. NaOH solution was used as a pH activator. In the range from pH 12 to pH 14, Experiment was compared the hydration propertied of OPC(Ordinary Portland Cement) and BFS(Blast Furnace BFS) and BFS containing 2 wt% of gypsum. It was found that CAH(Calcium Aluminate Hydrates) phases and CSH(Calcium Silicate Hydrates) phases were formed during the early hydration of BFS, and that CAH phases, CSH phases and ettringites were formed during the early hydration of BFS containing 2 wt% of gypsum. Furthermore, early hydration of BFS and BFS containing 2 wt% of gypsum were faster then OPC at pH 14, and the 1 day compressive strength of BFS increased by approximately 30% compared to OPC, and BFS containing 2 wt% of gypsum also increased by approximately 40% compared to OPC.

Analysis of the Structure and Stability of Erythropoietin by pH and Temperature Changes using Various LC/MS

  • Chang, Seong-Hun;Kim, Hyun-Jung;Kim, Chan-Wha
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2663-2670
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    • 2013
  • The purpose of stability testing is to provide evidence about how the quality of a drug varies with time under the influence of a variety of environmental factors. In this study, erythropoietin (EPO) was analyzed under different pH (pH 3 and pH 9) and temperature ($25^{\circ}C$ and $40^{\circ}C$) conditions according to current Good Manufacturing Practice (cGMP) and International Conference on Harmonisation (ICH) guidelines. The molecular weight difference between intact EPO and deglycosylated EPO was determined by SDS-PAGE, and aggregated forms of EPO under thermal stress and high-pH conditions were investigated by size exclusion chromatography. High pH and high temperature induced increases in dimer and high molecular weight aggregate forms of EPO. UPLC-ESI-TOF-MS was applied to analyze the changed modification sites on EPO. Further, normal-phase high-performance liquid chromatography was performed to identify proposed glycan structures and high pH anion exchange chromatography was carried out to investigate any change in carbohydrate composition. The results demonstrated that there were no changes in modification sites or the glycan structure under severe conditions; however, the number of dimers and aggregates increased at $40^{\circ}C$ and pH 9, respectively.

Effect of pH on the Cell Wall and Cell Membrane of Bacillus sp. SH-8 Bacillus sp. SH-8M (Bacillus sp. SH-8과 Bacillus sp. SH-8M의 세포벽과 세포막에 미치는 pH의 영향)

  • 심창환;정용준;신원철
    • Microbiology and Biotechnology Letters
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    • v.23 no.1
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    • pp.31-35
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    • 1995
  • Using the alkalophillic Bacillus sp. SH-8 and its mutant Bacillus sp. SH-8M capable of growing at the neutral pH, the amino acid compositions of the cell wall and cell membrane were studied at varying cultivation pH's. The pattem of protein electrophoresis was also tested. It was elucidated that the amino acids consisting of the cell wall were alanine, glutamic acid, lysine, aspartic acid, and meso-diaminopimelic acid. There was not any significant difference in the amino acid compositqon betweeo`two straqns regardless of the culture pH. As the results of HPLC ssay, glutamic acid and aspartic aciu accounted for more than 50% in the amqno acid composytqon of the cell wall. By the isolatqon of the crude cell membrane and the SDS-PAGE analysis, it was found that there was a considerable difference qn the protein pattern when the straqns were cultured at the neutral pH. In addition, by the two dimensional gel electrophoresis, it was confirmed that there was a difference in the protein patterns between two strains cultivated at the neutral pH medium but no difference at the alkaline medium.

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