• Journal of the Korean earth science society
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• v.21 no.6
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• pp.703-718
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• 2000

In order to investigate interannual variation of total ozone and reflectivity over the globe, Nimbus-7/TOMS data were used on the monthly mean and its anomaly for the period of 1979-92. This study also examined MSU channel 4(Ch4; lower-stratosphere) brightness temperature data and two model reanalyses of NCEP and GEOS to compare the ozone variation with atmospheric thermal condition. In addition, the MSU channel 1(Ch1 ; lower-troposphere) brightness temperature was used to compare with the reflectivity. The ozone showed strong annual cycle with downward trend(-6.3${\pm}$0.6 DU/decade) over the globe, and more distinct response to volcanic eruption than El Ni${\tilde{n}$o. The relationship between total ozone and MSU Ch4 observation, and between the ozone and model reanalyses of lower stratosphere temperature showed positive correlation(0.2-0.7) during the period of 1980-92. Reflectivity increased interannually by 0.2${\pm}$0.06%/decade over the globe during the above period and reflected El Ni${\tilde{n}$o(1982-83, 1991-92) well. Its variability in annual cycle was remarkably smaller in tropics than in higher latitudes. This is inferred due to cloud suppression and tropical upwelling regions. Reflectivity correlated negatively(-0.9) to the Ch1 temperature over the globe, but positively(0.2) over tropical ocean. The positive value over the ocean results from the effect of microwave emissivity which increases the Ch1 temperature with enhanced hydrometeor activity. Significant correlations between total ozone and the Ch4 temperature, and between reflectivity and the Ch1 Suggest that the TOMS data may use valuably to better understand the feedback mechanism of climate change.

• Journal of the Korean earth science society
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• v.23 no.8
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• pp.683-696
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• 2002

In this work. we investigated the ozone data sets that exceeded ambient air quality standards from 31 air quality monitoring stations dispersed across the Seoul metropolitan city during the period covering 1990 and 2000. To specifically describe spatial dependency of high level O$_3$ occurrence, we grouped our data into four different geographical ozone exceedance is much longer in SW than the other three sectors. When we compared the exceedance data in terms of occurrence frequency, the month of maximum frequency differed slightly among different sectors. Examination of long-term exceedance trend indicated that its frequency increased continuously from all sectors over the past years, although slightly opposite patterns existed in their absolute values. Most importantly, its peak occurrence frequency seemed to center in very recent years such as 1998 (NE sector) and 2000 (ail pattern sectors except NE). Consequently, we were able to describe the existence of certain patterns of ozone exceedance data sets in terms of both temporal and spatial scales.

• Journal of Animal Environmental Science
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• v.17 no.3
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• pp.181-188
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• 2011

With an increasing livestock population, animal manure production has been steadily increasing in Korea. This trend has forced farmers to spend more money for animal manure treatment in their farm. Therefore, research utilizing animal manure as a renewable resources has become increasingly important. The purpose of this study was to develop a stable advanced wastewater treatment system can be applied to conventional animal wastewater treatment processes and evaluate its contribution to reduce effluent discharge volume by recycling as flushing water. AOP (advanced oxidation process) process improved wastewater treatment efficiency in terms of color, suspended solids (SS) and chemical oxygen demand (COD). Due to the addition of Hydrogen peroxide ($H_2O_2$), pathogens, Salmonella and E. coli, reduction was accomplished. To enhance ozone treatment effect, three levels of ozone test on secondary effluent of pig slurry purification system were conducted. At the level of 5 g/hr, 6.7 g/hr and 8.4 g/hr color of secondary effluent of pig slurry purification system were decreased from 2,433 to 2,199, 2,433 to 1,980 and 2,433 to 243, respectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.132-132
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• 2013

Colloidal synthesis of nanoparticles with well-controlled size, shape, and composition, together with development of in situ surface science characterization tools, such as ambient pressure X-ray photoelectron spectroscopy (APXPS), has brought new opportunities to unravel the surface structure of working catalysts. Recent studies suggest that surface oxides on transition metal nanoparticles play an important role in determining the catalytic activity of CO oxidation. In this talk, I will outline the recent studies on the influence of surface oxides on Rh, Pt, Ru and Co nanoparticles on the catalytic activity of CO oxidation [1-3]. Transition metal nanoparticle model catalysts were synthesized in the presence of poly(vinyl pyrrolidone) polymer capping agent and deposited onto a flat Si support as two-dimensional arrays using the Langmuir-Blodgett deposition technique. APXPS studies exhibited the reversible formation of surface oxides during oxidizing, reducing, and CO oxidation reaction [4]. General trend is that the smaller nanoparticles exhibit the thicker surface oxides, while the bigger ones have the thin oxide layers. Combined with the nature of surface oxides, this trend leads to the different size dependences of catalytic activity. Such in situ observations of metal nanoparticles are useful in identifying the active state of the catalysts during use and, hence, may allow for rational catalyst designs for practical applications. I will also show that the surface oxide can be engineered by using the simple surface treatment such as UV-ozone techniques, which results in changing the catalytic activity [5]. The results suggest an intriguing way to tune catalytic activity via engineering of the nanoscale surface oxide.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1998.11a
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• pp.242-244
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• 1998

Over the years manufactures have become increasingly aware of the importance of water purity and its effect on the quality of the final product. One of the largest problems that confronts pure water system operators is bacterial recontamination shortly after the water purification equipment. There are several recommended methods of either preventing or recommended methods of either preventing or removing such contamination but most have inherent disadvantages. Drinking water has required new treatment techniques such as ozonation and granular activated carbon(GAC) filtration. Ozone is known to be a powerful oxidant and disinfectant. Therefore it has been found to be necessary for the treatment of taste, odor and color as an oxidant of inorganic and organic compounds.

• Proceedings of the SCSK Conference
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• 1992.09a
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• pp.97-114
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• 1992

In these days sun products are developed and produced by the cosmetic scientists in the world. Peoples need strongly to protect themselves from the hazardous UV rays dued to the destruction of ozone layer. Therfore, we, cosmetic scientists must have an effort to produce the more effective goods. In this article the market survey of sun-products as well as the currency of sunscreen agents was investigated. It was found that Benzophenone - 3 and Ocytyl methoxy cinnamate were widely used. The lotions, using Benzophenone - 3 as the chemical agents, and TiO$_2$and micro TiO$_2$ as the physical agents, were measured the UV-Spectrum in the Dilution and Application method. Photoprotective activity of chemical agents can usually be measured in solution state. However, that of the insoluble physical agents such as TiO$_2$is hardly measured in this state. Photoprotective ability of the insoluble physical agents was able to be measured by application of lotions to the surface of UV cells. It was found by this method that micro TiO$_2$showd stronger UV scattering effect than TiO$_2$in this method.

• Fire Science and Engineering
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• v.8 no.1
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• pp.3-8
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• 1994

A new test system was established to measure the flame extinguishing concentration of Halon alternatives. The main characteristic of this system is to use the solid paraffin with a wick instead of liquid fuel, such as n-Heptane. Our results showed that the extinguishing concentration of compounds was lower than that of other existing data, but the trend was consistent with others. The flame extinguishing concentration of all tested compounds were not almost effected by gas flow velocity. The system produces good reliable data with a minimum error for measuring the flame extinguishing concentration. Therefore our new system can be utilized as a standard equipment to evaluate Halon alternatives.

• Atmosphere
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• v.16 no.4
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• pp.333-342
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• 2006

The long-term trends of global solar irradiance, air temperature, specific humidity and cloudiness measured at King Sejong station, Antarctica, during the period of 1988-2004, have been investigated. A statistically insignificant decrease, -0.21 $Wm^{-2}yr^{-1}$ (-0.26 %$yr^{-1}$, P<0.5) in global solar irradiance was found in an analysis from the time series of the monthly mean values, except for the increasing trends only in two months of January and June. The trends in irradiance are directly and inversely associated with the cloudiness trends in annual and monthly means. The trends in surface air temperature show a slight warming, $0.03^{\circ}Cyr^{-1}$ (1.88 %$yr^{-1}$, P<0.5) on the annual average, with cooling trend in the summer months and the warming in the winter. The exact relationship, if any, between the irradiance and temperature trends is not known. No significant tendency was found in specific humidity for the same periods. Recent (1996-2004) erythermal ultraviolet irradiance shows decreasing trend in annual mean, -0.15 $mWm^{-2}yr^{-1}$ (-1.18 %$yr^{-1}$, P<0.1) which is about five times the trends of global solar irradiance. The ratio of erythermal ultraviolet to global solar irradiance shows remarkable seasonal variations with annual mean value of 0.01 % and a peak in October and November, showing the increase of ultraviolet irradiance resulting from the Antarctic ozone hole. The sensitivity of global solar irradiance to the change in cloudiness is roughly $13%oktas^{-1}$ which is about twice of the value at the South Pole due to the difference in the average surface reflectance between the two stations. Much more sensitive values of $59%oktas^{-1}$ was found for erythermal UV irradiance than for the global solar irradiance.

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.4
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• pp.213-220
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• 1992

Simple correlation analysis, factor analysis, and multi-variate analysis have been performed to analyze the relationship between air pollution and meteorological factors for air pollution and meteorological data measured at Kwanghwamun in Seoul during the period of one year(January 1990 $\sim$ December 1990). As a result of simple correlation and factor analysis, $SO_2$, TSP and CO concentrations have shown high negative correlation with temperature and among these indicating that these are related with pollutant emission trend based upon heating fuel usage. Ozone has a good corrleation with solar radiation and relative humidity to have a closed relation with $O_3$ generation reaction mechanism. The result of multi-variate correlation analysis shows that the concentration of $SO_2$ and CO are adequate for correlation model with ambient temperature and wind speed and $O_3$ concentrations are adequate for that with solar radiation and wind speed. $SO_2$ and CO levels are considered to be affected first of all by heating fuel usage as a emssion source and wind speed as a dispersion effect. The $SO_2$ concentration in the condition that the temperature fall below zero is explained by multilicative model with wind speed, only one variable.

• Journal of environmental and Sanitary engineering
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• v.7 no.2
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• pp.141-152
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• 1992

Simple correlation analysis, factor analysis, and multi-verite analysis have been performed to analyze the relationship between air pollution and meteorological factors for air pollution and meteorological data measured at Kwanghwamun in Seoul during the period of one year (January 1990" December 1990). As a result of simple correlation and factor analysis, $SO_2$, TSP and CO concentrations have shown high negative correlation with temperature and among these indicating that these are related with pollutants emission trend based upon heating fuel usage. Ozone has a good correlation with solar radiation and relative humidity to have a closed relation with $0_3$ generation reaction mechanism. The result of multi-variate correlation analysis shows that the concentration of $SO_2$ and CO are adequate for correlation model with ambient temperature and wind speed and 0$_{3}$ concentrations are adequate for that with solar radiation and wind speed. $SO_2$ and CO levels are considered to be affected first of all by heating fuel usage as a emission source and wind speed as a dispersion effect. The $SO_2$ concentration in the condition that the temperature fall below zero is explained by multiplicative model with wind speed, only one variable.