• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1255-1260
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• 2004

Decomposition of ozone at room temperature was investigated comparatively with commercial monolithic ozone decomposition catalyst (ODC, $MnO_2$) and monolithic photo catalyst ($TiO_2$). The effects of residence time, UV (ultraviolet) light dependence and ozone concentration on the conversion was presented. UV ray was irradiated using BLB (black light blue) lamp ($315{\sim}400$ nm), supplied with a constant intensity in the reactor. The concentration of ozone in the square-shape reactor can be controlled by combining the DBD (dielectric barrier discharge) reactor with an AC high voltage supply system. The catalytic performance, in presence of UV irradiation did not show significant changes for $MnO_2$ catalyst. $TiO_2$ catalyst was the different case, which showed higher decomposition activity in presence of UV irradiation. Deactivation of catalyst detected by real-time ozone monitor for 120 hours with a constant inlet ozone concentration.

• Journal of environmental and Sanitary engineering
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• v.18 no.4
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• pp.45-51
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• 2003

This study was conducted to remove the color in dyeing wastewater by ozone oxidation process, and the results were summarized as follows ; The 18.3％ of BOD and 56.3％ TOC were removed as decreasing with pH 1 in dyeing wastewater, containing the polyester reducing process. It showed that terephthalic acid was precipitated at low pH. The color of dyeing wastewater was removed by the first order reaction, and the reaction rate constants at pH 3, 7, 12 were investigated $0.234{\;}min^{-1},{\;}0.215{\;}min^{-1}{\;}and{\;}0.201{\;}min^{-1}$ respectively. It showed that color was more effectively removed with direct reaction of ozone than radical reaction(non-direct reaction). As increasing of the water temperature, the reaction rate constants were increased slightly. It indicated that activity of ozone was improved at high water temperature.

• Journal of Surface Science and Engineering
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• v.31 no.2
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• pp.109-116
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• 1998

Highly transparent conductive pure and fluorine-doped tin oxide(FT0, $SnO_2$ : F) films have been prepared by low pressure metal organic chemical vapor deposition (LP-MOCVD) from various mixtures of tetramethyitin(TMT) with oxygen or oxygen containing ozone. The properties of TO films have been changed with the variation of gases, flow rate, and substrate temperature. The nsing of oxygen containing ozone instead of pure oxygen, reduced substrate temperature by 100-$150^{\circ}C$ while maintaining same thickness. The films prepared by using ozone showed the resistivity in the range from $10^~2$ to $10^{~3}\Omega$cm, and the mobiiity from 10 to $14\textrm{cm}^2$/Vs. Fluorine-doped tin oxide films had properties such as the resistivity about $10^{-4}\Omega$cm, and the mobility from 14 to $19\textrm{cm}^2$/Vs.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.5
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• pp.656-665
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• 2004

An Ozone reaction model combined with CFD(Computational Fluid Dynamics) technique was developed in this research, in the simulation of ozonation, hydrodynamic behavior as well as reaction model is important because ozone is supplied to treated water as gas ozone. In order to evaluate hydrodynamic behavior in an ozone contactor, CFD technique was applied. CFD technique elucidated hydrodynamic behavior in the selected ozone contactor, which consisted of three main chambers. Three back-mixing zones were found in the contactor. The higher velocities of water were observed in the second and third compartments than that in the first compartment. The flow of the opposite direction to the main flow was observed near the water surface. Based on the results of CFD simulation, the ozone contactor was divided into small compartments. Mass balance equations were established were established in each compartment with reaction terms. This reaction model was intended to predict dissolved ozone concentration, especially. We concluded that the model could predict favorably the mass balance of ozone, namely absorption efficiency of gaseous ozone, dissolved ozone concentration and ozone consumption. After establishing the model, we discussed the effect of concentration of gaseous ozone at inlet, temperature and organic compounds on dissolved ozone concentration.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.4
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• pp.481-491
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• 2015

The aim of this study was to evaluate the chemical quenching system for residual ozone and to determine the operating condition for the quenching system. Hydrogen peroxide ($H_2O_2$) and sodium thiosulfate ($Na_2S_2O_3$) were investigated as quenching reagents for ozone removal, and the tendency of each chemical was notably different. In the case of $H_2O_2$, the degradation rate of ozone was increased as the concentration of $H_2O_2$ increase, and temperature and pH value have a significant effect on the degradation rate of ozone. On the other hand, the degradation rate of ozone was not affected by the concentration of $Na_2S_2O_3$, temperature and pH value, due to the high reactivity between the ${S_2O_3}^{2-}$ and ozone. This study evaluates the decomposition mechanism of ozone by $H_2O_2$ and $Na_2S_2O_3$ with consideration for the water quality and reaction time. Furthermore, the removal test for the quenching reagents, which can be remained after reaction with ozone, was conducted by GAC process.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.3
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• pp.345-360
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• 2004

The late sea-breeze and its impacts on ozone distributions were investigated during April to September from 1998 to 2002, in the Busan metropolitan area (including surrounding areas) using the surface ozone concentrations (obtained at 9 monitoring sites), local meteorological variables (obtained near the shore), together with synoptic data. The urban scale ozone concentration was also simulated using the MM5/UAM-V to better understand the role of late sea-breeze in Busan. The results from observation study showed that most of the late sea-breeze occurred when weak offshore synoptic flow (northwesterly) suppressed development of sea - breeze, and the ozone concentration level and frequencies exceeding ozone standard increased with the onset time of sea breeze. We also found that the late sea-breeze clearly induces relatively weak wind speed and high temperature during the daytime As a result it enhances the photochemical ozone accumulation and delays the occurrence time of the averaged maximum ozone concentrations. The results of simulation for high ozone episode (24 August, 2001) by MM5/UAM -V revealed that the late sea-breeze interacted with weak offshore synoptic wind can contribute significantly to high ozone concentration in the coastal urban area. The simulated horizontal and vertical distribution of ozone concentration indicated that ozone can be accumulated over the sea under stagnant condition and return to the land in the late afternoon with the sea breeze, suggesting both the relationship between late sea-breeze and recirculation and the importance of late sea -breeze effects influencing severe ozone pollution in Busan.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.52 no.5
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• pp.226-226
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• 2003

When an excessive voltage is applied to the discharge gap in ozone generator, the discharge room temperature becomes higher. As is well own, the efficiency of the ozone generation is deteriorated by the excessively hot temperature because of the decomposition reaction. In this paper, the simple small capacity ozone generating controller has been introduced, which provides effective and stable silent discharge characteristics over wide range input power. The proposed power controller has two important advantages, which imply that the production rate of ozone can be controlled linearly according to the delivered power and the surplus energy is recovered to the source. The experimental results are given to verify the performance of the pre proposed controller.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.52 no.5
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• pp.226-230
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• 2003

When an excessive voltage is applied to the discharge gap in ozone generator, the discharge room temperature becomes higher. As is well own, the efficiency of the ozone generation is deteriorated by the excessively hot temperature because of the decomposition reaction. In this paper, the simple small capacity ozone generating controller has been introduced, which provides effective and stable silent discharge characteristics over wide range input power. The proposed power controller has two important advantages, which imply that the production rate of ozone can be controlled linearly according to the delivered power and the surplus energy is recovered to the source. The experimental results are given to verify the performance of the pre proposed controller.

• Atmosphere
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• v.18 no.4
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• pp.429-439
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• 2008

The lower-stratospheric polar temperature in winter and spring for both hemispheres is investigated based on the NCEP/NCAR 50-year reanalysis data with respect to the strength of the stratospheric eddy heat flux. Both the polar temperature and the eddy heat flux show significant variation on the decadal and year-to-year time scales except during the Southern Hemisphere winter. The year-to-year variation in the polar temperature is mainly determined by the eddy heat flux convergence. The eddy heat flux convergence is compared with the diabatic heating rate obtained from a two-dimensional model. Radiative heating caused by absorption of solar radiation is comparable to the heating caused by the eddy heat flux convergence in the Southern Hemisphere. The effect of ozone depletion on diabatic heating has been found to be secondary in the Northern Hemisphere, even in March 1997 when the record depletion of ozone took place.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.3
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• pp.257-266
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• 1999

In order to analyze the effect of meteorological elements on ozone concentration, we carried out cross-correlation of the elements with ozone concentraton, and time series analysis on them. As a result, it revealed that temperature, wind speed and humidity are not independent variables with ozone concentrations, and also, solar radiation and mixing height are the major elements that affect them. We developed models for ozone with solar radiation and mixing height as dependent variables to verify the effect of major meteorological elements. The predicted ozone concentration has strong correlation coefficients, So, We could conclude that we can predict ozone concentreation only with solar raidation and mixing height as dependents.