• Title/Summary/Keyword: ozone and temperature

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Molecular Layer Deposition of Organic/Inorganic Nanohybrid Dielectrics for OTFTs

  • Lee, Byeong-Hun;Lee, Gwang-Hyeon;Im, Seong-Il;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.56-56
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    • 2010
  • We report a low-temperature fabrication of organic/inorganic nanohybrid dielectrics for organic thin film transistors. The self-assembled organic layers (SAOLs) were grown by repeated sequential adsorptions of C=C-terminated alkylsilane and metal (Al or Ti) hydroxyl with ozone activation, which was called "molecular layer deposition (MLD)". The $TiO_2$ and $Al_2O_3$ inorganic layers were grown by ALD, which relies on sequential saturated surface reactions resulting in the formation of a monolayer in each sequence and is a potentially powerful method for preparing high quality multicomponent superlattices. The MLD method combined with ALD (MLD-ALD) was applied to fabricate SAOLs-$Al_2O_3$-SAOLs-$TiO_2$ nanohybrid superlattices on polymer substrates at relatively low temperature. The MLD method is an ideal fabrication technique for various flexible electronic devices.

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An Experimental Study on Performance Characteristics of Refrigeration System Using R134a Refrigerating System (R134a를 이용한 냉동장치의 성능특성에 관한 실험적 연구)

  • Kim, Jin-Hyun;Kim, Jong-Kil;Kim, Sung-Bae;Ha, Ok-Nam
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2188-2193
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    • 2007
  • Since the use of CFCs and HCFCs refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the R134a gas to study the performance characteristic from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 1.5 MPa to 1.6 MPa by 0.05 MPa and for superheat temperature from 0$^{\circ}C$ to 5$^{\circ}C$ by 1$^{\circ}C$ at each condensing pressure. As a result of experiment, when the superheat temperature is 1$^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

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Importance of Polar Phytoplankton for the Global Environmental Change (전 지구 환경변화에 대한 극지 식물플랑크톤의 중요성)

  • 강성호;강재신;이상훈;김동선;김동엽
    • Korean Journal of Environmental Biology
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    • v.18 no.1
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    • pp.1-20
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    • 2000
  • There are increasing evidences of climate change in the Antarctic and Arctic Oceans, especially elevated temperature due to the continuous burning of the fossil fuels and ultraviolet B(UV-B) flux within the ozone hole. Light-dependent, temperature-sensitive, and fast-growing organisms respond to these physical and biogeochemical changes. Polar marine phytoplankton, which are pioneer endemic species and important carbon contributors in the polar waters, are therefore highly suitable biological indicators of such changes. By virtue of light requirement, the primary producers are exposed to extreme seasonal fluctuations in temperature, photosynthetically active radiation, and UV radiation. Local environmental warming and increased UV-B radiation during ozone depletion may have profound effects on the primary producers that are primary carbon producers in the polar water. Small changes in climate temperature and solar radiation may have profound effects on the activity threshold of the polar phytoplanktion. To demonstrate biological response to the environmental changes, standardized representative natural and biological parameters are needed so that replicate samples (including controls) can be taken over extended periods of time. In this paper, we review general characteristics of polar phytoplankton, their environment, environmental changes in the polar waters, the effects on the environmental changes to the polar phytoplankton, and the importance of the polar phytoplankton to understand the global environmental changes. [Biological indicators, Global environmental change, Polar phytoplankton, UV].

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A Study on the Relationship of Air Pollution and Meteorologic Factors in a Specific Site (서울 일부지점의 대기오염 농도와 기상인자의 관련성 연구)

  • 신찬기;김윤신
    • Journal of environmental and Sanitary engineering
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    • v.7 no.2
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    • pp.141-152
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    • 1992
  • Simple correlation analysis, factor analysis, and multi-verite analysis have been performed to analyze the relationship between air pollution and meteorological factors for air pollution and meteorological data measured at Kwanghwamun in Seoul during the period of one year (January 1990" December 1990). As a result of simple correlation and factor analysis, $SO_2$, TSP and CO concentrations have shown high negative correlation with temperature and among these indicating that these are related with pollutants emission trend based upon heating fuel usage. Ozone has a good correlation with solar radiation and relative humidity to have a closed relation with $0_3$ generation reaction mechanism. The result of multi-variate correlation analysis shows that the concentration of $SO_2$ and CO are adequate for correlation model with ambient temperature and wind speed and 0$_{3}$ concentrations are adequate for that with solar radiation and wind speed. $SO_2$ and CO levels are considered to be affected first of all by heating fuel usage as a emission source and wind speed as a dispersion effect. The $SO_2$ concentration in the condition that the temperature fall below zero is explained by multiplicative model with wind speed, only one variable.

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A Study on the Relationship of Air Pollution and Meteorological Factors : Focusing at Kwanghwamun in Seoul (대기오염농도와 기상인자의 관련성 연구: 서울 광화문지점을 중심으로)

  • 신찬기;한진석;김윤신
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.4
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    • pp.213-220
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    • 1992
  • Simple correlation analysis, factor analysis, and multi-variate analysis have been performed to analyze the relationship between air pollution and meteorological factors for air pollution and meteorological data measured at Kwanghwamun in Seoul during the period of one year(January 1990 $\sim$ December 1990). As a result of simple correlation and factor analysis, $SO_2$, TSP and CO concentrations have shown high negative correlation with temperature and among these indicating that these are related with pollutant emission trend based upon heating fuel usage. Ozone has a good corrleation with solar radiation and relative humidity to have a closed relation with $O_3$ generation reaction mechanism. The result of multi-variate correlation analysis shows that the concentration of $SO_2$ and CO are adequate for correlation model with ambient temperature and wind speed and $O_3$ concentrations are adequate for that with solar radiation and wind speed. $SO_2$ and CO levels are considered to be affected first of all by heating fuel usage as a emssion source and wind speed as a dispersion effect. The $SO_2$ concentration in the condition that the temperature fall below zero is explained by multilicative model with wind speed, only one variable.

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Facile Preparation of ZnO Nanocatalysts for Ozonation of Phenol and Effects of Calcination Temperatures

  • Dong, Yuming;Zhao, Hui;Wang, Zhiliang;Wang, Guangli;He, Aizhen;Jiang, Pingping
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.215-220
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    • 2012
  • ZnO nanoparticles were synthesized through a facile route and were used as ozonation catalysts. With the increase of calcination temperature ($150-300^{\circ}C$), surface hydroxyl groups and catalytic efficiency of asobtained ZnO decreased remarkably, and the ZnO obtained at $150^{\circ}C$ showed the best catalytic activity. Compared with ozonation alone, the degradation efficiency of phenol increased above 50% due to the catalysis of ZnO-150. In the reaction temperatures range from $5^{\circ}C$ to $35^{\circ}C$, ZnO nanocatalyst revealed remarkable catalytic properties, and the catalytic effect of ZnO was better at lower temperature. Through the effect of tertbutanol on degradation of phenol and the catalytic properties of ZnO on degradation of nitrobenzene, it was proposed that the degradation of phenol was ascribed to the direct oxidation by ozone molecules based on solidliquid interface reaction.

Influence of Wax Molecular Weights on Wax Migration and Evaporation of Rubber Vulcanizates at Room Temperature (상온 노화 후 고무가황물에서 왁스의 이동과 증발에 미치는 왁스의 분자량 분포)

  • Im, Song-Hee;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.397-400
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    • 2009
  • Ozone caused the crack on the surface of a rubber article by oxidation of double bond at room temperature. Wax migrates to the surface of a rubber article and makes a physical barrier to prevent process of ozonation. We investigated change of molecular weight distribution of waxes in unfilled NR, SBR, and BR vulcanizates before and after aging at room temperature for 6 months. Migration and evaporation behaviors of wax in a rubber article at ambient conditions help understand a role of wax as an antidegradant and appearance contamination of a rubber article. The relative intensity distribution of n-alkanes of the NR specimen after the aging was shifted to higher molecular weight compared with the relative intensity distribution before the aging, while those of the SBR specimen before and after the aging did not show a big difference.

The Detection of Yellow Sand with Satellite Infrared bands

  • Ha, Jong-Sung;Kim, Jae-Hwan;Lee, Hyun-Jin
    • Korean Journal of Remote Sensing
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    • v.22 no.5
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    • pp.403-406
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    • 2006
  • An algorithm for detection of yellow sand aerosols has been developed with infrared bands. This algorithm is a hybrid algorithm that has used two methods combined. The first method used the differential absorption in brightness temperature difference between $11{\mu}m\;and\;12{\mu}m\;(BTD1)$. The radiation at $11{\mu}m$ is absorbed more than at $12{\mu}m$ when yellow sand is loaded in the atmosphere, whereas it will be the other way around when cloud is present. The second method uses the brightness temperature difference between $3.7{\mu}m\;and\;11{\mu}m(BTD2)$. This technique is sensitive to dust loading, which the BTD2 is enhanced by reflection of $3.7{\mu}m$ solar radiation. First the Principle Component Analysis (PCA), a form of eigenvector statistical analysis from the two methods, is performed and the aerosol pixel with the lowest 10% of the eigenvalue is eliminated. Then the aerosol index (AI) from the combination of BTD 1 and 2 is derived. We applied this method to Multi-functional Transport Satellite-l Replacement (MTSAT-1R) data and obtained that the derived AI showed remarkably good agreements with Ozone Mapping Instrument (OMI) AI and Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth.

Piggery Waste Treatment using Improved MLE Process in Full-Scale (수정된 MLE 공정을 이용한 Full-Scale에서의 돈사분뇨처리)

  • Hwang, In-Su;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.895-904
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    • 2006
  • The improved MLE (modified Ludzack-Ettinger) process was operated for piggery waste treatment in full-scale public livestock waste treatment plant. The treated waste from bioreactor was suitable for the strict effluent standard of 200 mgCOD/L and 60 mgTN/L as it was dewatered chemically without settling tank and passed through filtration process. Though this treatment method produced a great deal of sludge ($6.4m^3\;per\;m^3$ dewatered piggery waste) it was able to accomplish predominant effluent quality by removing non-biodegradable COD and color without advanced oxidation process as ozone, fenton and etc.. The nitrogen removal efficiency of bioreactor was rapidly declined from March to May (from 0.016 to 0.005 kgN/kgVSS-day) when disinfection is in earnest as well as from warm season when reactor temperature rises higher than $35^{\circ}C$(from 0.016 to 0.008 kgN/kgVSS-day). This study proves that counterplanes for infection residuals, bioreactor temperature and dewatering sludge reduction are necessary for piggery waste treatment.

Analysis of Temperature Change by Forest Growth for Mitigation of the Urban Heat Island (도시열섬 완화를 위한 녹지증가에 따른 온도변화 분석)

  • Yun, Hee Cheon;Kim, Min Gyu;Jung, Kap Yong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.31 no.2
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    • pp.143-150
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    • 2013
  • Recently, environmental issues such as climate warming, ozone layer depletion, reduction of tropical forests and desertification are emerging as global environmental problems beyond national problems. And international attention and effort have been carried out in many ways to solve these problems. In this study, the growth of green was calculated quantitatively using the technique of remote sensing and temperature change was figured out through temperature extraction in the city. The land-cover changes and thermal changes for research areas were analyzed using Landsat TM images on May 2002 and May 2009. Surface temperature distribution was calculated using spectral degree of brightness of Band 6 that was Landsat TM thermal infrared sensor to extract the ground surface temperature in the city. As a result of research, the area of urban green belt was increased by $2.87km^2$ and the ground surface temperature decreased by $0.6^{\circ}C{\sim}0.8^{\circ}C$ before and after tree planting projects. Henceforth, if the additional study about temperature of downtown is performed based on remote sensing and measurement data, it will contribute to solve the problems about the urban environment.