• Title/Summary/Keyword: ozonated pine wood

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Chemical Characteristics of Ozone Treated Pine Wood Meal (오존 처리에 의한 소나무 목분의 화학적 성상 변화)

  • Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.23-28
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    • 2011
  • The pine wood meal was ozonated in acidic water. A 91.3% of lignin and 13% of polysaccharides in pine wood meal were degraded with 180 min ozonation. The phenolic hydroxyl groups of lignin in ozonated wood meals were increased with ozonation time. The vanillin content in nitrobenzene oxidation products of lignin is decreased with 10 min. ozonation and it was slightly increased with ozonation time. The sugar composition of ozonated wood meals showed that the hemicellulose was more susceptible to ozonation than cellulose. The crystallinity of ozonated wood meal was increased.

Enzymatic hydrolysis and micro-structure of ozone treated wood meal (오존 처리에 의한 목재 세포벽의 미세구조변화와 효소가수분해)

  • Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.67-73
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    • 2010
  • Pine (Pinus densiflora) and aspen (Populus euramericana) wood meals were treated with ozone at various time schedule in acidic condition. The lignin contents and surface area of the ozone treated wood meals were determined and the enzymatic hydrolysis rate of ozonated wood meals was evaluated. The feasibility of enzymatic hydrolysis of the ozone treated wood meal was obviously influenced with the degree of delignification. After ozone treatment of wood meal for 10min, total pore volume were slightly increased in the surface of wood meal. When wood meals were treated with ozone longer than 10min, few change in the pore volume was observed. However, the area of over $50{\AA}$ of pore size is increased with ozonation time. As a conclusion, the rate of enzymatic hydrolysis of wood is more effective with the pore size distribution than the total pore volume.