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OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Quantitative Visualization of Oxygen Transfer in Micro-channel using Micro-LIF Technique (마이크로 레이저 형광 여기법을 이용한 미세채널 내부에서의 산소 확산에 대한 정량적 가시화)

  • Chen, Juan;Kim, Hyun-Dong;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.10 no.1
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    • pp.34-39
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    • 2012
  • In the present study, oxygen transfer process across gas-liquid interface in a Y-shape micro-channel is quantitatively visualized using the micro laser induced fluorescence (${\mu}$-LIF) technique. Diffusion coefficient of Oxygen ($D_L$) is estimated based on the experimental results and compared to its theoretical value. Tris ruthenium (II) chloride hexahydrate was used as the oxygen quenchable fluorescent dye. A light-emitting diode (LED) with wavelength of 450 nm was used as the light source and phosphorescence images of fluorescent dye were captured by a CMOS high speed camera installed on the microscope system. Water having dissolved oxygen (DO) value of 0% and pure oxygen gas were injected into the Y-shaped microchannel by using a double loading syringe pump. In-situ pixel-by-pixel calibration was carried out to obtain Stern-Volmer plots over whole flow field. Instantaneous DO concentration fields were successfully mapped according to Stern-Volmer plots and DL was calculated as $2.0675{\times}10^{-9}\;m^2/s$.

Cathodic Polarization Measurements on La0.9Sr0.1MnO3 Electrode for Solid Oxide Fuel Cells

  • Lee, H.Y.;Oh, S.M.
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.153-161
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    • 1993
  • Cathodic oxygen reduction kinetics on $La_{0.9}Sr_{0.1}MnO_3$ electrode have been examined at $700-900^{\circ}C$ under various oxygen partial pressures. AC impedance and current interruption techniques were employed for the determination of charge transfer resistances for electrochemical oxygen reduction. The $R_{ct}$ values obtained from two different methods were very close each other for $La_{0.9}Sr_{0.1}MnO_3$ electrode. Activation energy for the electrochemical oxygen reduction was found to be 174kJ/mol under atmospheric oxygen pressure. $R_{ct}$ measurements as a function of oxygen partial pressure indicate that the rate-determining step for the electrochemical oxygen reduction on $La_{0.9}Sr_{0.1}MnO_3$ electrode is the charge transfer process.

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Reduction Characteristics of Mass Produced Particle for Chemical-Looping Combustor with Different Fuels (매체순환식 가스연소기용 대량생산입자의 연료별 환원반응특성)

  • Ryu, Ho-Jung;Kim, Kyung-Su;Lee, Seung-Yong;Park, Yeong-Seong;Park, Moon-Hee
    • Journal of Hydrogen and New Energy
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    • v.19 no.4
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    • pp.348-358
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    • 2008
  • Reduction reactivity and carbon deposition characteristics of mass produced oxygen carrier particle(OCN-650) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all fuels, the maximum conversion and oxygen transfer capacity increased as the temperature increase. The reduction rate and the oxygen transfer rate increased as the temperature increase for methane. However, those values showed maximum at 900$^{\circ}C$ for hydrogen, syngas, and natural gas. To explain consistently the change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels, new parameters such as reactive carbon contents and require oxygen per input gas were adopted.

Effects of Electrolytes, pH, Glucose, Acetic acid and Propionic acid on Oxygen Consumption in Clonorchis Sinensis (배양액(培養液)의 성분(成分) 및 배양시간(培養時間)의 변화(變化)에 따른 간흡충(肝吸?)의 산소소비(酸素消費)에 미치는 영향(影響))

  • Kim, Hwa-Woong;Choi, Hyung-Kon;Yun, Byung-Oh;Ha, Young-Ho
    • The Korean Journal of Pharmacology
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    • v.5 no.1
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    • pp.17-22
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    • 1969
  • Oxygen consumption by Clonorchis sinensis (C.S.) was observed in a medium of valuable pH of KRP, lack of certain electrolytes of KRP and of glucose, acetic acid or propionic acid was added to KRP. The results were as follows. 1. In a different solutions, KRP with or without $0.4%-glucose$, $0.9%-saline$ solution, the variation of oxygen consumption by C.S. was not significant. 2. Oxygen consumption by C.S. was inhibited by the solution of KCI, $CaCl_2$, or $MgSO_4$ in a 0.9% solution of saline. 3. Under the acidity, oxygen consumption was enhanced but under the alkality, it was inhibited. 4. Oxygen consumption by C.S. was inhibited by acetic acid or propionic acid in KRP solution. 5. C.S. keeping in KRP solution for a long duration, oxygen cosumption was reduced in the course of time.

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Influence of Water Temperature and Salinity on Oxygen Consumption and Filtration Rate of on Oxygen Consumption and Filtration Rate of Ark Shell, Anadara granosa bisenensis

  • Kang, Kyoung-Ho;Kim, Jae-Min;Kim, Young-Hun
    • The Korean Journal of Malacology
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    • v.20 no.2
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    • pp.107-110
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    • 2004
  • The filtration rate and oxygen consumption of Anadara granosa bisenensis were measured at 4 different temperature (10$^{\circ}C$, 15$^{\circ}C$, 20$^{\circ}C$, and 25$^{\circ}C$) and 4 different salinity levels (20, 25, 35, and 40 psu), using an direct method under laboratory conditions. The samples were divided into two groups: a large-sized group (shell length: 34.58 ${\pm}$ 2.23 mm, body weight: 12.43 ${\pm}$ 0.44 g) and a small-sized group (shell length: 20.60 ${\pm}$ 0.85 mm, body weight: 4.41 ${\pm}$ 2.30 g). Filtration rate and oxygen consumption increased with the increase of various temperatures and salinity levels. Also, the filtration rate and oxygen consumption of the small-sized group were higher than those of the large-sized group. These results indicate that the filtration rate and oxygen consumption of Anadara granosa bisenensis depends on environmental conditions, especially on water temperature and salinity.

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Damage-Free Treatment of ITO Films using Nitrogen-Oxygen (N2-O2) Molecular DC Plasma

  • Kim, Hong Tak;Nguyen, Thao Phoung Ngoc;Park, Chinho
    • Current Photovoltaic Research
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    • v.3 no.4
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    • pp.112-115
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    • 2015
  • In this study, the surface of ITO films was modified using $N_2-O_2$ molecular plasma, and the effects of oxygen concentration in the plasma on the ITO surface properties were investigated. Upon plasma treatment of ITO films, the surface roughness of ITO films seldom changed up to the oxygen concentration in the range of 0% to 40%, while the roughness of the films slightly changed at or above the oxygen concentration of 60%. The contact angle of water droplet on ITO films dramatically changed with varying oxygen concentration in the plasma, and the minimum value was found to be at the oxygen concentration of 20%. The plasma resistance at this condition exhibited a maximum value, and the change of resistance showed an inverse relationship compared to that of contact angle. From these results, it was conjectured that the chemical reactions in the sheath of the molecular plasma dominated more than the physical actions due to energetic ion bombardment, and also the plasma resistance could be used as an indirect indicator to qualitatively diagnosis the state of plasma during the plasma treatment.

A Study on Analysis of the Hydrogen-Oxygen Gas Generator Using Pulse Power Supply (펄스전원에 의한 수산화가스 발생기에 관한 연구)

  • 이정민;강병희;목형수;최규하
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.5
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    • pp.377-385
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electricity for the Hydrogen-Oxygen gas generator, Firstly chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated through Faraday's laws of electrolysis. After that, pulse power supply is designed for basic experiment which could be applied to the analysis of Hydrogen-Oxygen gas generator. In the basis of above steps, comparison and analysis of Hydrogen-Oxygen gas generator was conducted as variable frequency using pulse Power supply.

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Impact of Lignin Determination Method on Oxygen Delignification Chemistry

  • Shin Soo-Jeong;Lai Yuan-Zong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.50-55
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    • 2005
  • In previous report, we investigated the impact of hexeneuronic acid and some residual extractiveson lignin determination. These non-lignin components severely interfered lignin content determination which also affect on the oxygen delignification comparison between aspen and pine unbleached kraft pulps. Very different pattern was observed whether based on uncorrected conventional kappa number or based on corrected kappa number in oxygen delignification comparison. Lower kappa number aspen pulps showed poor response to oxygen delignification when kappa number was used as lignin determination method but better response with using the acid lignin method. Phenolic hydroxyl group in kraft pulps were also compared based on uncorrected or corrected kappa numberfor lignin content. Based on uncorrected kappa number, lower kappa number oxygen-delignified pulps had lower phenolic hydroxyl group. However, lower kappa number oxygen-delignified pulps showed much higher phenolic hydroxyl group based on the corrected lignin content. For accurate comparison for residual lignin properties from different pulps, lignin determination should be corrected from non-lignin components contribution to lignin.

A study on the determination of a representative location for monitoring the dissolved oxygen concentration in a aeration tank of sewage treatment plant (하수처리장 폭기조의 용존산소농도 모니터링 대표지점 선정에 관한 연구)

  • Bang, Seok-Yong;Bum, Bong-Su;Kim, Jin-Han
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.389-394
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    • 2019
  • In order to determine the location of average concentration and distribution status of dissolved oxygen in the rectangular aeration tank of the sewage treatment plant was analyzed and the difference of dissolved oxygen concentration was remarkable at each location. Compared with the computational fluid dynamics analysis, it was found that the results were consistent with the measurement results by showing the difference of dissolved oxygen concentration between the locations. Based on the measured data, the representative location of dissolved oxygen in aeration tank was selected by using statistical analysis method and the representative location was expressed in three-dimensional coordinates(LWH : 25%, 50%, 33%) from flow direction and left wall. Also the difference between the dissolved oxygen concentration at the actual measurement location and the average concentration value of the entire aeration tank was founded, and the equations for calibrating the automatic measurement data considering the actual measurement location were calculated.